全文获取类型
收费全文 | 905篇 |
免费 | 74篇 |
国内免费 | 128篇 |
专业分类
化学 | 750篇 |
晶体学 | 10篇 |
力学 | 29篇 |
综合类 | 13篇 |
数学 | 34篇 |
物理学 | 271篇 |
出版年
2024年 | 2篇 |
2023年 | 23篇 |
2022年 | 80篇 |
2021年 | 49篇 |
2020年 | 60篇 |
2019年 | 40篇 |
2018年 | 55篇 |
2017年 | 58篇 |
2016年 | 49篇 |
2015年 | 40篇 |
2014年 | 51篇 |
2013年 | 71篇 |
2012年 | 38篇 |
2011年 | 62篇 |
2010年 | 46篇 |
2009年 | 47篇 |
2008年 | 47篇 |
2007年 | 27篇 |
2006年 | 36篇 |
2005年 | 38篇 |
2004年 | 31篇 |
2003年 | 34篇 |
2002年 | 28篇 |
2001年 | 16篇 |
2000年 | 14篇 |
1999年 | 14篇 |
1998年 | 10篇 |
1997年 | 3篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1981年 | 2篇 |
1979年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有1107条查询结果,搜索用时 15 毫秒
91.
首先制备了α-MnO2纳米花簇、β-MnO2纳米针和δ-MnO2微米颗粒三种不同晶型的MnO2粉末材料,对其结构、形貌及吸附除铵能力进行了表征和测试.结果表明,层间距(7.2Å)大于NH4+直径(2.96Å)和水合NH4+直径(6.62Å)的δ-MnO2相比其他两种晶型的MnO2有更高的NH4+吸附量;接着研究采用KMnO4原位氧化还原法在石墨毡(GF)上直接生长超薄δ-MnO2纳米片(MnO2NPs)阵列构筑了石墨毡载纳米MnO2(MnO2NPs/GF)多级结构材料,制备简单,无须成型造粒就可直接用作除铵净水材料,研究结果表明,MnO2NPs/GF不仅具有较高的吸附量(15 mg·g-1)与良好的选择性,同时还展现了优异的快速吸附和稳定的循环使用性能.MnO2NPs/GF对水中NH4+的吸附符合准二级动力学模型,其吸附等温线符合Langmuir吸附等温式,是吸附-离子交换法除铵的理想材料. 相似文献
92.
93.
Zhi Zeng Marina Hincapie Brian B. Haab Samir Hanash Sharon J. Pitteri Steven Kluck Jason M. Hogan Jacob Kennedy William S. Hancock 《Journal of chromatography. A》2010,1217(19):3307-3315
Protein glycosylation represents one of the major post-translational modifications and can have significant effects on protein function. Moreover, changes in the carbohydrate structure are increasingly being recognized as an important modification associated with cancer etiology. In this report, we describe the development of a proteomics approach to identify breast cancer related changes in either concentration and/or the carbohydrate structures of glycoprotein(s) present in blood samples. Diseased and healthy serum samples were processed by an optimized sample preparation protocol using multiple lectin affinity chromatography (M-LAC) that partitions serum proteins based on glycan characteristics. Subsequently, three separate procedures, 1D SDS-PAGE, isoelectric focusing and an antibody microarray, were applied to identify potential candidate markers for future study. The combination of these three platforms is illustrated in this report with the analysis of control and cancer glycoproteomic fractions. Firstly, a molecular weight based separation of glycoproteins by 1D SDS-PAGE was performed, followed by protein, glycoprotein staining, lectin blotting and LC–MS analysis. To refine or confirm the list of interesting glycoproteins, isoelectric focusing (targeting sialic acid changes) and an antibody microarray (used to detect neutral glycan shifts) were selected as the orthogonal methods. As a result, several glycoproteins including alpha-1B-glycoprotein, complement C3, alpha-1-antitrypsin and transferrin were identified as potential candidates for further study. 相似文献
94.
A magnetically stabilized fluidized bed (MSFB, φ 500mm x 2100mm) was designed to study dust removal from flue gas. Based on the mechanism of dust removal in a fixed bed, the effects on collection efficiency of magnetic field intensity, ratio of flue gas velocity to minimum fluidization velocity, bed height, and particle average diameter, were investigated. Then feasible methods for MSFB to better remove dust were proposed. Over 95% of dust removal with MSFB can be achieved, when stable fluidization is maintained and when magnetic particles are frequently renewed. 相似文献
95.
Moisture removal from a two-layer porous media in which air is circulated through one layer and moisture is removed from the second has not been well studied due to the emphasis given to single-layer systems. This two-layer configuration is common in natural and engineered systems and can be used as a means to create a barrier to downward migrating fluids and to remove liquids and gases that may be present in the finer layer. However, there is little data on moisture removal from a two-layer porous media in which air is circulated through one layer parallel to the interface and moisture is removed from the finer second layer by evaporation. A conceptual model of the moisture removal from a two-layer porous media system was developed and compared to experimental moisture removal rates from laboratory scale dry barriers. The limited experimental data agrees well with the results predicted by the conceptual model, providing an initial validation. 相似文献
96.
陶瓷过滤器高温除尘技术的研究进展 总被引:2,自引:0,他引:2
对陶瓷过滤元件及结构、滤饼的作用和架桥、过滤器故障安全(CPP)系统及陶瓷过滤器高温气体净化一体化技术等几个方面进行了评述,总结了陶瓷过滤器存在着过滤管破裂、清灰效率下降、管板和器壁的连接及脉冲阀的长期稳定性等几个问题,指出新型陶瓷材料的研究和陶瓷过滤器高温气体净化一体化技术是陶瓷过滤器今后的研究方向. 相似文献
97.
Our main results in the chemistry of 1,3-calix[4]-bis-crowns taken from recent literature are reported. 相似文献
98.
Pedro Ilundain Daniel Alvarez Louis Da Cunha Rafael Salazar María J. Barandiaran Jos M. Asua 《Journal of polymer science. Part A, Polymer chemistry》2002,40(23):4245-4249
The mechanisms involved in monomer removal by postpolymerization were investigated to establish a criterion to select the most effective initiator systems. Three redox systems yielding radicals of different hydrophobicities were studied. Efficiency in monomer removal by postpolymerization increased with the hydrophobicity of the radical formed from the initiator system. This result was independent of the water solubility of the residual monomer. The mechanistic reasons for this finding are discussed. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4245–4249, 2002 相似文献
99.
采用氧化钙对高岭土进行改性,并用XRD、SEM和FT-IR对改性高岭土进行了表征。将改性高岭土应用于垃圾渗滤液的处理,考察了改性高岭土投加量、渗滤液初始pH、时间等因素对氨氮去除效果的影响,并对其吸附机理进行了研究。结果表明,氧化钙改性高岭土的产物主要是胶凝材料水化物(硅铝酸钙和含Al的C-S-H凝胶),形貌为蜂窝状;向氨氮含量为3520mg/L、pH为7.53~7.80的垃圾渗滤液中投加160g/L吸附剂,吸附60min,氨氮的去除率达82.66%,吸附量为18.19mg/g。氧化钙改性高岭土对氨氮的吸附符合Langmuir等温模型,动力学上符合准二级动力学方程,其相关系数分别为0.9678,0.9989。同时,该吸附过程包含了膜扩散和颗粒内扩散。 相似文献
100.
Chromium(III) sorption on macroporous strong cation exchanger Amberlyst‐15 (H+) was studied as a function of time and temperature. The rate constant values for chromium(III) sorption were calculated both for film and particle diffusion processes. The temperature was found to have a positive effect on both the diffusional processes. From the rate constant values, the energy of activation was calculated using the well‐known Arrhenius equation. The high values of energy of activation confirmed the film diffusional nature of the process. Equilibrium data were explained with the help of Langmuir equation. Various thermodynamic parameters (ΔH?, ΔS? and ΔG?) from chromium(III) exchange on the resin were calculated. The ΔG? values were found to be negative while both the ΔH? and ΔS? were positive. 相似文献