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81.
基于YNS层合板理论,通过对混合能变分原理的修正,建立了层合板问题的Hamilton正则方程。在辛几何数学框架下,采用共轭辛正交归一关系给出精确解。并与经典层板理论进行了比较。 相似文献
82.
在对原表面力仪进行较大改进的基础上 ,以 5 0 0 SN基础油和十六烷为研究对象 ,进行了超薄膜流变特性的实验研究 .结果表明 :在超薄膜润滑条件下 ,5 0 0 SN和十六烷均表现出明显的非牛顿剪切响应 ,即剪切稀释现象 ;摩擦力幅值随剪切速度的增大急剧上升到最大值 ,然后下降至某一固定值附近并产生波动 ;剪切挤压下的临界膜厚小于静态挤压的临界膜厚 ,剪切运动对吸附层有序结构产生破坏作用 相似文献
83.
广义双剪应力准则角隅模型 总被引:7,自引:0,他引:7
本文将广义双剪应力准则变换为π平面和静水应力轴的柱坐标方程,然后将其角隅光滑化,得到了新的光滑、外凸的广义双剪应力准则角隅模型,研究结果表明,近年来作为光滑化Mohr-Coulomb理论提出的各种角隅模型,实际上并不是光滑化的Mohr-Coulomb理论,而是光滑化的广义双剪应力理论。 相似文献
84.
The behavior of a terminally anchored freely-jointed bead-rod chain, subjected to solvent shear flow, was investigated via Brownian dynamics simulations. Previous calculations have been improved by computing the segment density and fluid velocity profiles self-consistently. The segment density distributions, components of the radius of gyration, and chain attachment shear and normal stresses were found to be sensitive to low values of shear rate. Additionally, it was found that the thickness of a model polymer layer was a strong function of the shear rate, and that the functional dependence on shear rate changed dramatically as the chain length increased. For the longest chains studied, the thickness of the model polymer layer first increased as the shear rate increased, passed through a maximum, and then decreased at high shear rates, in accordance with experimental results in theta solvents. These results suggest that a dilute or semi-dilute layer model may explain hydrodynamic behavior previously thought to be due to the entanglements that occur in dense surface bound polymer layers.Nomenclature
a
i
acceleration of bead i
-
b
radius of the beads
-
d
length of the rods connecting the chain beads
-
d
i
vector from bead i to bead i + 1
-
F
i
external force applied to bead i
-
F
i
b
external force on bead i due to Brownian motion of surrounding fluid
-
F
i
h
external force on bead i due to viscous drag
-
F
i
s
external force on bead i due to surface interactions
-
f
Stokes drag coefficient
-
Boltzmann's constant
-
L
h
effective hydrodynamic thickness
-
m
i
mass of bead i
-
N
number of beads on a model chain
-
n
number of chains anchored to the surface per unit surface area
-
P
segment density distribution P pressure
-
Q
flow in a tube with no surface bound polymer layer
-
Q
a
flow in a tube with a surface bound polymer layer
-
R
g
vector representation of the radius of gyration
-
R
tube radius
-
r
radial coordinate in the tube geometry
-
S
ij
pair hydrodynamic interaction tensor for beads i and j
-
T
i
internal chain force in rod i connecting beads i and i + 1
-
T
X
component of the surface attachment force in the direction of the fluid flow
-
T
y
component of the surface attachment force perpendicular to the surface
-
T
temperature
-
v
i
velocity of the center of mass of bead i
-
V
if
average fluid velocity at the location of bead i
-
v
if
0
fluid velocity in the absence of a polymer chain
-
v
if
perturbation to the fluid velocity due to hydrodynamic interactions
-
V
b
bead volume = 4 b
3/3
-
scalar fluid speed in the axial direction down the tube
-
x
axial coordinate in the tube geometry
Greek symbols w
apparent shear rate
-
fluid viscosity
-
polymer layer permeability
-
volume fraction of space occupied by chain beads
- (w)a
chain attachment stress perpendicular to the surface
- (w)a
chain attachment stress in the plane of the surface and in the direction of fluid flow 相似文献
85.
在反平面剪切载荷及侧压力共同作用下引起的裂纹及裂纹扩展导致的层间界面失效,是岩土工程层间界面及砌体结构中界面层上典型的失效方式.运用弹性力学和断裂力学的理论原理,提出了能够反映上述层间界面断裂失效问题力学特性的剪切梁模型.文中采用具有应力软化特性的“粘性裂纹”(内聚力裂纹)模型来表述层间裂纹前方损伤过程区的本构行为.对通过粘性层结合在一起的两个弹性板,在反平面剪切载荷及侧压力共同作用下的力学行为作了解析分析计算,研究了层间界面裂纹扩展规律. 相似文献
86.
87.
88.
Brian Joseph Edwards Mohammad Hadi Nafar Sefiddashti Bamin Khomami 《Entropy (Basel, Switzerland)》2022,24(2)
The challenge of calculating nonequilibrium entropy in polymeric liquids undergoing flow was addressed from the perspective of extending equilibrium thermodynamics to include internal variables that quantify the internal microstructure of chain-like macromolecules and then applying these principles to nonequilibrium conditions under the presumption of an evolution of quasie equilibrium states in which the requisite internal variables relax on different time scales. The nonequilibrium entropy can be determined at various levels of coarse-graining of the polymer chains by statistical expressions involving nonequilibrium distribution functions that depend on the type of flow and the flow strength. Using nonequilibrium molecular dynamics simulations of a linear, monodisperse, entangled C1000H2002 polyethylene melt, nonequilibrium entropy was calculated directly from the nonequilibrium distribution functions, as well as from their second moments, and also using the radial distribution function at various levels of coarse-graining of the constituent macromolecular chains. Surprisingly, all these different methods of calculating the nonequilibrium entropy provide consistent values under both planar Couette and planar elongational flows. Combining the nonequilibrium entropy with the internal energy allows determination of the Helmholtz free energy, which is used as a generating function of flow dynamics in nonequilibrium thermodynamic theory. 相似文献
89.
90.
采用静态拉伸方法在连续升温条件下动态地测量了大块金属玻璃Zr41Ti14Cu12.5Ni10Be22.5(Vit1)的黏度随温度的变化关系.在应变速率与温度的关系曲线中,观测到了与玻璃转变和晶化过程相联系的多个应变速率峰.在玻璃转变温度Tg以上,大块金属玻璃Zr41Ti14Cu12.5Ni10Be22.5的过冷液体呈现Newton流体特征,其黏度与温度的关系符合Vogel Fulcher-Tammann (VFT)关系式,拟合得到脆度D*=36,VFT温度T0=319K,脆度参数m=30,这说明Zr41T
关键词:
大块金属玻璃
应变速率
剪切黏度
自由体积 相似文献