基于连续小波变换下的土壤有害元素砷含量估测

与传统检测方法相比,利用高光谱技术进行土壤有害元素砷含量的估算,具有快速、准确,成本低的特点,可对干旱区绿洲土壤有害元素砷污染进行动态监测。基于新疆渭干河-库车河三角洲绿洲耕层土壤样品的采集,获取土壤光谱数据和有害元素砷含量。通过bior1.3,db4,gaus4和mexh这4种小波基函数对土壤原始光谱反射率进行连续小波变换,并将变换后光谱数据与有害元素砷进行相关分析,以筛选出的敏感小波系数为自变量,采用偏最小二乘回归、支持向量机回归、BP神经网络和随机森林回归方法对有害元素砷含量进行高光谱反演。研究结果显示：（1）4种小波基函数在3~8尺度的光谱分解效果明显优于其他尺度,特别是4~6尺度的连续小波变换有效提升了光谱反射率与土壤有害元素砷之间的相关性,通过显著性检验的小波系数数量有了明显增多（p<0.01）,在可见光的400~700 nm以及近红外的1 100~1 700和2 200~2 400 nm附近具有较强的相关性;（2）通过比较4种小波基函数对光谱数据中有效信息的辨识能力,认为小波基函数bior1.3和mexh要优于db4和gaus4,其中bior1.3的光谱分解效果最好,gaus4相对最弱;通过bior1.3第5尺度的光谱变换,与土壤有害元素砷显著相关的波段数量最多,为507个（p<0.01）;（3）比较4种建模方法的反演结果发现,SVMR,BPNN和RFR模型相较于PLSR模型具有更强的估测能力,模型的估测精度更高。综合分析各模型的稳定性及估测精度后,认为bior1.3-25-RFR模型可作为研究区土壤有害元素砷的最佳估测模型。该模型的训练集和验证集的R2分别为0.893和0.639,RMSE为1.075和1.651 mg·kg-1,RPD分别为2.89和1.64,表明模型估测效果较好,稳定性较强。采用合适的小波基函数进行连续小波变换可减少土壤高光谱数据中的白噪声,挖掘出土壤光谱数据中的有效信息,对土壤有害元素砷含量的准确估测提供有力的技术保障。     

Dual effects of ultrasound on fabrication of anodic aluminum oxide

Ultrasound has been proven to enhance the mass transfer process and impact the fabrication of anodic aluminum oxide (AAO). However, the different effects of ultrasound propagating in different media make the specific target and process of ultrasound in AAO remain unclear, and the effects of ultrasound on AAO reported in previous studies are contradictory. These uncertainties have greatly limited the application of ultrasonic-assisted anodization (UAA) in practice. In this study, the bubble desorption and mass transfer enhancement effects were decoupled based on an anodizing system with focused ultrasound, such that the dual effects of ultrasound on different targets were distinguished. The results showed that ultrasound has the dual effects on AAO fabrication. Specifically, ultrasound focused on the anode has a nanopore-expansion effect on AAO, leading to a 12.24 % improvement in fabrication efficiency. This was attributed to the promotion of interfacial ion migration through ultrasonic-induced high-frequency vibrational bubble desorption. However, AAO nanopores were observed to shrink when ultrasound was focused on the electrolyte, accompanied by a 25.85 % reduction in fabrication efficiency. The effects of ultrasound on mass transfer through jet cavitation appeared to be the reason for this phenomenon. This study resolved the paradoxical phenomena of UAA in previous studies and is expected to guide AAO application in electrochemistry and surface treatments.     

滚子摩擦副弹流润滑特性及其应用──Ⅰ 有限长直母线滚子的弹流数值解

运用改进的数值方法求得了与实验结果相符的等温有限长直母线滚子的弹流数值解，与无限长线接触弹流结果相比较，揭示了润滑状态下滚子摩擦副的边缘效应和端泄对油膜分布的影响，在低速和重载时滚子的两端都几乎不能形成全膜润滑，因而有必要通过修形消除滚子端部的边缘效应．     

Influence of Thermally Induced Chemorheological Changes on the Inflation of Spherical Elastomeric Membranes

When an elastomeric material is deformed and subjected to temperatures above some chemorheological value T _cr (near 100°C for natural rubber), its macromolecular structure undergoes time and temperature dependent chemical changes. The process continues until the temperature decreases below T _cr. Compared to the virgin material, the new material system has modified properties (often a reduced stiffness) and permanent set on removal of the applied load. A recently proposed constitutive theory is used to study the influence of chemorheological changes on the inflation of an initially isotropic spherical rubber membrane. The membrane is inflated while at a temperature below T _cr. We then look at the pressure response assuming the sphere's radius is held fixed while the temperature is increased above T _cr for a period of time and then returned to its original value. The inflation pressure during this process is expressed in terms of the temperature, representing entropic stiffening of the elastomer, and a time dependent property that represents the kinetics of the chemorheological change in the elastomer. When the membrane has been returned to its original temperature, it is shown to have a permanent set and a modified pressure-inflated radius relation. Their dependence on the initial inflated radius, material properties and kinetics of chemorheological change is studied when the underlying elastomeric networks are neo-Hookean or Mooney–Rivlin.     

高阶奇异项及J积分表达式

从４种典型裂纹情况的特征展开式出发，运用其微分性质和伪正交性质得到了含有高阶奇异项的Ｊ积分表达式．它们是通用的显函数表征的．本研究支持了Ｈｕｉ和Ｒｕｉｎａ的杰出研究和重要观点，即高阶奇异项和非奇异项一样在小范围屈服描述中扮演着重要角色．研究表明，常规柔度方法确定的Ｊ积分已隐含了高阶奇异项的贡献．断裂准则有可能由含高阶奇异项和非奇异项的Ｊ积分的临界值来描述     

ANISOTROPIC EFFECTS OF QUASI-ISOTROPIC COMPOSITES(I)──MODELLING

Experimental observations show that quasi-isotropic materials, such as N-axial fibre-reinforced composites and woven materials, exhibit various degrees of anisotropy in elasticity and strength, and the anisotropy in strength is normally stronger than that in elasticity. In view of some available experimental data and based on the general formulation of the constitutive equations and failure criteria of quasi-isotropic materials established by using the theory of representations for tensor functions, we postulate several applicable models of the constitutive equations and strength for 3-and 4-axial quasi-isotropic materials to reveal the anisotropic effects. In a continued work (Part II), the anisotropic effect in strength of an infinitely large plate with a single elliptical hole or crack is studied, and the proposed stiffness and strength models are verified in terms of micro-mechanical analyses.Project supported by the National Natural Science Foundation of China and the State Education Commission Foundation of China     

Coriolis Effect on the Linear Stability of Convection in a Porous Layer Placed Far Away from the Axis of Rotation

The linear stability theory is used to investigate analytically the Coriolis effect on centrifugally driven convection in a rotating porous layer. The problem corresponding to a layer placed far away from the axis of rotation was identified as a distinct case and therefore justifying special attention. The stability of the basic centrifugally driven convection is analysed. The marginal stability criterion is established as a characteristic centrifugal Rayleigh number in terms of the wavenumber and the Taylor number.     

平板网架结构分析的超级有限元法

本文给出一种二维矩形超级单元，用以分析平板网架结构，其做法是将大型平板网架结构离散成一系列矩形超级单元，考虑弯曲、剪切、挤压、拉压、翘曲等多种非经典变形效应，采用构件自由度向超级元自由度的转换把大型多构件问题的求解变为二维问题的求解，可大大减少未知量，又能保证精度，并可方便地与一般有限元软件连接。     

溶质在微极流体中的弥散——考虑无偶应力边界条件

本文研究溶质在作圆管和渠道层流的微极流体中的弥散规律，考虑了化学反应效应。利用Ｅｒｉｎｙｅｎ的微极流体理论，无偶应力边界条件和Ｔａｙｌｏｒ简化假定，导出相对浓度分布Ｃ和等效扩散系数Ｄ＊的解析式，并作数值计算，分析了微极参数λ．ｋ０和化学反应率参数β对上述量的影响。     

Application de l'approximation polytropique à la Simulation Numérique Directe de gaz chaudsApplication of the polytropique approximation to Direct Numerical Simulation of heated gases

As alternative to the usual assumptions of Boussinesq, we propose, for heated gases, a new approximation called polytropic approximation. With this approximation the quantities of corresponding state are related by a polytropic law of exponent χ of which we neglect the variability in space-time derivations in the equations governing the flow considered. As application, we used this new proposition to solve numerically a heated gas flow in an annular cavity of rotor-stator type. We expose here the numerical method and some results of the polytropic approximation with comparison to results of Boussinesq approximations. To cite this article: S. Benjeddou et al., C. R. Mecanique 332 (2003).