Numerical investigation of the partial oxidation process in porous media based reformer

Numerical investigation of the thermal partial oxidation process of Methane in porous media based reformer is performed. A finite volume based CFD code, including radiation modeling, in combination with a detailed chemical kinetics scheme is used to perform the numerical simulation. A heterogeneous approach for the heat transport modeling in porous media (separate coupled energy equations for the gas and solid phases) was used. Validation of the model with experimental data is also performed. The model was able to predict the temperature behavior in the reformer reasonably well. However, the concentrations of H₂ and CO were under predicted while the H₂O concentration was over predicted.     

Scintillation in the White-Noise Paraxial Regime

In this paper the white-noise paraxial wave model is considered. This model describes for instance the propagation of laser beams in the atmosphere in some typical scaling regimes. The closed-form equations for the second- and fourth-order moments of the field are solved in two particular situations. The first situation corresponds to a random medium with a transverse correlation radius smaller than the beam radius. This is the spot-dancing regime: the beam shape spreads out as in a homogeneous medium and its center is randomly shifted according to a Gaussian process whose variance grows like the third power of the propagation distance. The second situation corresponds to a plane-wave initial condition, a small amplitude for the medium fluctuations, and a large propagation distance. This is the scintillation regime: the normalized variance of the intensity converges to one exponentially with the propagation distance, corresponding to strong intensity fluctuations and in agreement with the conjecture that the statistics of the field becomes complex Gaussian.     

Principles of the micromechanics of material damage. 1. Long-term damage

The principles of the theory of long-term damage based on the mechanics of stochastically inhomogeneous media are set out. The process of damage is modeled as randomly dispersed micropores resulting from the destruction of microvolumes. A failure criterion for a single microvolume is associated with its long-term strength dependent on the relationship of the time to brittle failure and the difference between the equivalent stress and the Huber-von Mises failure stress, which is assumed to be a random function of coordinates. The stochastic elasticity equations for porous media are used to determine the effective moduli and the stress-strain state of microdamaged materials. The porosity balance equation is derived in finite-time and differential-time forms for given macrostresses or macrostrains and arbitrary time using the properties of the distribution function and the ergodicity of the random field of short-term strength as well as the dependence of the time to brittle failure on the stress state and the short-term strength. The macrostress-macrostrain relationship and the porosity balance equation describe the coupled processes of deformation and long-term damage __________ Translated from Prikladnaya Mekhanika, Vol. 43, No. 2, pp. 108–121, February 2007. For the centenary of the birth of G. N. Savin.     

Ultrasound promoted aminolysis of epoxides in aqueous media: a rapid procedure with no pH adjustment for additive-free synthesis of beta-aminoalcohols

An efficient and environmentally friendly procedure promoted by ultrasound irradiation is developed for stereoselective ring opening of various epoxides with aromatic and aliphatic amines under aqueous conditions in the presence of no catalyst or additive. Chemoselectivity of the protocol is shown by competition of piperidine and aniline to react with different epoxides resulting in exclusive formation of the respective products of piperidine.     

Synchronization in complex networks by time-varying couplings

Synchronization in networks of complex topologies using couplings of time-varying strength is numerically investigated. The time-dependencies of coupling strengths are coupled to the dynamics of the nodes in a way to enhance synchronization. By time-varying couplings, oscillators are found to take quite a short time to reach synchronization state when the couplings are relatively strong. Even when a nearly regular networks of large-size with few shortcuts is difficult to be synchronized by fixed couplings, the time-varying couplings can easily enhance the emergence of synchronization.     

Cu2O/1-(2-methylhydrazine-1-carbonyl)-isoquinoline 2-oxide catalyzed C-N cross-coupling reaction in aqueous media

An experimentally simple, efficient, and inexpensive catalyst system was developed for the N-arylation of imidazole, indole, pyrrole, alkyl alcohol amines, and alkyl amines with aryl iodides and bromides. The reaction proceeds in water-ethanol media at 120 °C for 12 h with Cu₂O as the catalyst, 1-(2-methylhydrazine-1-carbonyl)-isoquinoline 2-oxide (L2) as the ligand, NaOH as the base to generate a wide range of N-arylated products in moderate to excellent yields. Aqueous medium, ease of operation, and broad substrate scope give the process a benign environmental profile.     

Characteristics of adsorption phase with water/organic mixtures at a surface of activated carbons possessing intraparticle and textural porosities

The behaviour of water and water/organic mixtures adsorbed onto activated microporous carbons or a carbon adsorbent with narrow intraparticle micropores and broad mesopores and macropores between nanoparticles was studied using low-temperature adsorption method and ¹H NMR spectroscopy with layer-by-layer freezing-out of liquids at 190-273 K. These investigations revealed concentration-dependent effects of benzene, DMSO, acetone, chloroform, methane and acetonitrile on the characteristics of adsorbed water and the influence of this water on the interfacial behaviour of adsorbed organics. The influence of organics causes the structural and energetic differentiations of adsorbed water. The latter can be displaced by organics from micropores into broader pores and/or form mixture with polar solvents in meso and macropores. Freezing of adsorbed water can affect the adsorbent structure because ice crystallites have a larger size than that of liquid water droplets that lead to changes in the behaviour of adsorbed water/organic mixtures observed by the ¹H NMR and adsorption methods.     

基于蒙特卡罗随机有限元方法的随机多孔介质内流体自然对流不确定性研究

为分析孔隙率不确定性对多孔介质方腔内自然对流换热的影响,发展了一种基于KL（Karhunen-Loeve展开）-蒙特卡罗随机有限元算法的随机多孔介质内自然对流不确定性分析数理模型及有限元数值模拟程序框架。通过K-L展开及基于拉丁抽样法生成多孔介质孔隙率随机实现,并耦合多孔介质自然对流有限元程序,进行随机多孔介质内自然对流传热数值模拟,得出了多孔介质内流场与温度场平均值与标准偏差,并分析了孔隙率不确定性条件下Da数对Nu数的影响。结果表明,孔隙率不确定性对多孔介质方腔内自然对流有重要影响。随机多孔介质内流场及温度场与确定性条件下的流场及温度场存在一定偏差,Nu数标准偏差随着Da的增大先增大后减小。     

Synchronization in a fractional-order dynamic network with uncertain parameters using an adaptive control strategy

This paper studies synchronization of all nodes in a fractional-order complex dynamic network. An adaptive control strategy for synchronizing a dynamic network is proposed. Based on the Lyapunov stability theory, this paper shows that tracking errors of all nodes in a fractional-order complex network converge to zero. This simple yet practical scheme can be used in many networks such as small-world networks and scale-free networks. Unlike the existing methods which assume the coupling configuration among the nodes of the network with diffusivity, symmetry, balance, or irreducibility, in this case, these assumptions are unnecessary, and the proposed adaptive strategy is more feasible. Two examples are presented to illustrate effectiveness of the proposed method.     

Investigation of Coulomb force effects on ethylene glycol based nanofluid laminar flow in a porous enclosure

Forced convection heat transfer of ethylene glycol based nanofluid with Fe_3O_4 inside a porous medium is studied using the electric field. The control volume based finite element method(CVFEM) is selected for numerical simulation. The impact of the radiation parameter(R_d), the supplied voltage(?φ), the volume fraction of nanofluid(?), the Darcy number(Da), and the Reynolds number(Re) on nanofluid treatment is demonstrated. Results prove that thermal radiation increases the temperature gradient near the positive electrode. Distortion of isotherms increases with the enhance of the Darcy number and the Coulomb force.