PP/CF增强珊瑚砂水泥基复合材料冲击压缩力学性能研究

在人工海水制备珊瑚砂水泥基复合材料中混杂加入碳纤维和聚丙烯纤维,得到4种不同纤维掺量的碳-聚丙烯混杂纤维增强珊瑚砂水泥基复合材料。采用直径100 mm的分离式Hopkinson压杆,对材料进行5种应变率下的冲击压缩试验,采用LS-DYNA进行相应的冲击压缩数值模拟。结果表明：(1) 试验应变率临界值为200 s⁻¹,当试验应变率大于200 s⁻¹时,混杂碳纤维和聚丙烯纤维所形成的纤维网络对试块的增韧效果加强;(2) 碳-聚丙烯混杂纤维增强珊瑚砂水泥基复合材料峰值应力具有明显的应变率效应,且动态增强因子对应变率的敏感程度较高;(3) 使用珊瑚砂细骨料导致试块内微裂纹和微空洞等缺陷较多,在珊瑚砂水泥基复合材料内混杂掺加碳纤维和聚丙烯纤维后,试块冲击抗压强度的提升有限,但珊瑚砂水泥基复合材料的抗冲击韧性显著提升;(4) 通过试验数据和参数调试确定了HJC模型的参数,试块峰值应力的模拟结果与试验结果的误差在5.97 %以内。

     

The physics of Aeolian sand transport

We give a synthetic overview of the state of art of the physics of sand Aeolian transport. We first present the main ideas developed by Bagnold in the middle of the last century. We then review the recent experimental and theoretical advances made in the field and emphasize that the particle flow rate does not exhibit a cubic dependence with the air friction speed, as predicted by Bagnold, but a quadratic one. Finally, we list important open issues that remain.     

沙摆实验误差分析

从实验误差理论角度，分析了沙摆重心变化引起的实验误差，结果表明由重心变化引起的误差相对于其它误差而言在实验中占主要地位．     

Lipids from the sand dollar <Emphasis Type="Italic">Scaphechinus mirabilis</Emphasis>

The composition of lipids and their fatty acids in tissues of scalp, gonads, and internal organs of the sand dollar Scaphechinus mirabilis was determined using one-and two-dimensional TLC and GC-MS. Lipids of S. mirabilis scalp consisting of several neutral and phospholipids were characterized for the first time. A significant quantity of eicosapentaenoic acid (20:5) was found in scalp lipids. __________ Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 320–323, July–August, 2007.     

加拿大油砂沥青减压渣油在CO/H2-H2O作用下的热改质特性研究

以加拿大油砂沥青大于420℃的减压渣油（BVR）为原料,对比研究其在CO/H₂-H₂O和N₂体系中的热改质特性,通过系统分析BVR在H₂-H₂O、CO-H₂O、N₂-H₂O等不同氢源下的热改质特性以揭示CO/H₂-H₂O对渣油热改质的作用机制,最后探讨合成气压力、含水量以及温度对BVR临CO/H₂-H₂O改质生焦倾向的影响。结果表明,与临氮改质相比,相同反应条件下,合成气和水可使BVR热改质的生焦诱导期延长3.5-6.5 min;相同生焦率（约0.1%）时,合成气和水可显著提升BVR热改质降黏率,410℃时相对临氮改质的降黏率为29.1%,而420℃时可达54.6%。比较不同氢源下BVR热改质的生焦诱导期、改质油黏度和安定性、渣油转化率发现,H₂-H₂O、CO-H₂O、N₂-H₂O等均对BVR热改质表现出与CO/H₂-H₂O相同的促进效果,各氢源作用活性的大小顺序为H₂-H₂O > CO/H₂-H₂O > CO-H₂O > N₂-H₂O。由此可知,CO/H₂-H₂O对渣油热改质的促进作用可归因于氢气、CO水热变换新生氢和水热裂解的综合效应,且其中氢气的作用仍最显著。合成气压力、含水量和反应温度可通过影响不同氢源的贡献而调控BVR临CO/H₂-H₂O改质生焦倾向。低成本易获取的合成气可以提供BVR热降黏改质所需氢源,水能够通过CO水热变换反应供出新生活泼氢而协同合成气实现BVR高效改质。     

A semi‐quantitative approach for the rapid screening and mass profiling of naphthenic acids directly in contaminated aqueous samples

We report the use of a direct sampling, online analytical approach for the determination of acid extractable naphthenic acids in complex aqueous samples, known as condensed phase membrane introduction mass spectrometry (CP‐MIMS). The technique employs a capillary hollow fibre semi‐permeable membrane probe configured for immersion into a pH adjusted sample. A continuously flowing methanol acceptor phase transfers naphthenic acids to an electrospray ionization source, operated in negative ion mode, whereupon they are analysed by mass spectrometry as [M–H]^? ions. High‐resolution mass spectrometry is used to characterize the influence of sample pH on membrane transport of multiple components of complex naphthenic acid mixtures. We demonstrate the use of CP‐MIMS for semi‐quantitative analysis of real‐world samples using selected ion monitoring and full scan mass spectra at unit mass resolution. The technique has also been employed to continuously monitor the temporal evolution in the mass profile and concentrations of individual naphthenic acid isomer classes in heterogeneous solutions during adsorption processes. Copyright © 2015 John Wiley & Sons, Ltd.     

砂土场地中直埋热力管道热力学特性试验研究

为研究砂土场地中管道温度变化影响下管体与土体的热力学特性, 设计了一种直埋热力管道温度变化模型试验及测试系统, 较为系统地研究了砂土场地中直埋热力管道运行时的管土热力学特性. 结果表明: 在管道升温过程中, 管道上部土体温度增长速率和幅度均大于管道侧边及底部土体温度; 土体孔压随温度上升而增大, 在温度稳定后逐渐消散; 管体应变在温度上升时因膨胀而变大, 随后回落, 并维持在一定值, 其中环向应变大于轴向应变.     

Fluidization behavior of oil-contaminated sand

Hydrodynamic behavior of oil-polluted particles of sand was investigated in transparent glass column. The onset of fluidization of sand beds increased with the oil content of the bed. An increase of cohesive forces related to the higher content of liquid (oil) caused deterioration of the quality of fluidization. An empirical correlation was developed to predict the dimensionless gas velocity that keeps the bed of sticky particles fluidized. Results of this work can be employed for the design of fluidized-bed remediation units for oil-polluted sands and soils. An erratum to this article is available at .     

蒸养混凝土早期强度影响因素研究

研究了在蒸汽养护条件下,粗细集料对混凝土早期强度的影响.试验结果表明：对C60塑性蒸养混凝土而言,当水灰比一定时,混凝土强度随砂率的增加而增加;混凝土强度一般随细集料细度模数的增加而增加;当砂率一定时,混凝土强度随粗集料最大粒径的减小而增加.     

沙尘大气电磁波多重散射及衰减

为了使干旱沙漠地区的电子系统能够全天候的工作, 必须开展沙尘大气的电磁波多重散射及衰减特性研究. 根据Mie理论、沙尘大气粒子尺寸分布和能见度的关系得到了电磁波沙尘大气传播衰减的计算方法, 计算了不同沙尘大气能见度的37 GHz电磁波的衰减, 与其他经验公式及文献中的实验结果进行比较, 文中方法得到的结果更接近于测量结果. 为了研究较低能见度沙尘暴中电磁波的传播特性, 需研究沙尘大气的多重散射效应. 应用Monte Carlo模拟方法, 在沙尘粒子为干燥和5%水含量时, 模拟了37 GHz和93 GHz电磁波在沙尘大气中传播时考虑多重散射效应的衰减, 并与基于Mie理论的计算结果进行比较, 结果显示, 在37 GHz时, 沙尘大气的多重散射对衰减的影响小, 在93 GHz时多重散射显著, 沙尘大气能见度越低, 多重散射的影响越显著. 粒子水含量增加使电磁波的衰减显著增大, 对多重散射的影响不明显. 因此, 在相同大气能见度下, 沙尘天气越干燥, 多重散射影响越大, 电磁波衰减减小越显著.