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201.
基于 HL-2M 真空室烘烤保温要求,通过有限元分析和原型件实验确定采用陶瓷纤维与纳米级微孔材
料组合作为 HL-2M 真空室保温材料。在 30℃时,保温层的导热系数小于 0.027W⋅m−1·℃−1;300℃时,导热系数
小于 0.038W⋅m−1·℃−1。在保温层厚度 25mm、热面温度 300℃且达到稳态时,冷面可控制在 85℃以下,线圈侧的
温度低于 60℃,整体热损失小于 12kW,满足 HL-2M 真空室烘烤需求。 相似文献
202.
结合新课标要求,揭示塑料薄膜撕扯实验在聚合物教学中的重要性、必要性。通过教学片段设计,发展学生“宏观辨识与微观探析、证据推理与模型认知”化学学科核心素养,并让学生认识物质的性能不仅取决于结构,也取决于生产工艺。并对人教版初、高中化学教材和教参中相关问题展开讨论和解释,以期更好地服务教学。 相似文献
203.
Kenji Ichimura Hiroyuki Nakano Masanao Takashima 《Molecular Crystals and Liquid Crystals》2013,570(2):111-117
Abstract In the MxPS3 and M1?xM'xPS3 systems, the P2S6 cluster contributes to the poor electrical conductivity for the compounds in which the energy level of the metal 3d orbital is deeper than those of the P, S 3p orbitals. For the compounds in which metal 3d orbital is closed to P and S 3p orbitals and has mixed valency, the induced mixed valency of P2S6, cluster and/or hopping mechanism contribute to the electrical conductivity. In the organic electron donor intercalation into MxPS3 and M1?xM'xPS3 compounds, the new intercalation reaction is discovered, in which formation of tris-complexes of metal ions with guest molecules occurs in the host interlayer. 相似文献
204.
Applied Mathematics and Mechanics - The recently developed hard-magnetic soft (HMS) materials can play a significant role in the actuation and control of medical devices, soft robots, flexible... 相似文献
205.
Efficient sunlight-responsive BiOBr–CoWO4 heterostructured nanocomposite photocatalysts were prepared via a chemical precipitation route at 100°C in 4 hours. The prepared BiOBr–CoWO4 heterostructures were characterized for phase identification, chemical composition, surface morphology, optical properties and surface area using various techniques. The X-ray diffraction pattern of the BiOBr–CoWO4 nanocomposite was composed of diffraction peaks equivalent to both the tetragonal phase of BiOBr and the monoclinic phase of CoWO4 nanoparticles. X-ray photoelectron spectral study of the BiOBr–CoWO4 nanocomposite revealed orbitals of both BiOBr and CoWO4 compounds. Transmission electron microscopy images revealed that spherical particles of CoWO4 (20–25 nm) were dispersed on the surface of BiOBr. UV–visible–near-infrared spectral study of the BiOBr–CoWO4 nanocomposite showed good visible-light absorption. Among the manufactured materials, BiOBr–CoWO4-2 nanocomposite showed better charge carrier separation efficiency, as demonstrated by photoluminescence and time-resolved fluorescence. To study the practical utility of the prepared materials, their photocatalytic capability was examined for the degradation of rhodamine B (RhB) aqueous solution under sunlight irradiation. The photodegradation results showed that BiOBr–CoWO4-2 nanocomposite degraded 98.69% RhB solution and the degradation constant was 0.067 min−1, which was 5.6 and 22.5 times larger than that of pure BiOBr and CoWO4 nanoparticles, respectively, after 60 minutes of sunlight irradiation. The superior photoactivity was facilitated by electron–hole pair separation and transfer driven by the heterostructure interface between BiOBr particles and CoWO4 nanoparticles. The removal of RhB was initiated by photogenerated h+, O2• − and •OH reactive species based on the scavenger effect. 相似文献
206.
Dr. Chao Zhao Dr. Louise Male Dr. Tzu-Yu Chen Joseph A. Barker Dr. Ian J. Shannon Dr. Paul A. Anderson 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(61):13865-13868
(NH4)2[Zn2(O3PCH2CH2COO)2]⋅5 H2O (BIRM-1) is a new metal phosphonate material, synthesized through a simple hydrothermal reaction between zinc nitrate and 3-phosphonopropionic acid, using urea and tetraethylammonium bromide as the reaction medium. In common with other metal–organic framework materials, BIRM-1 has a large three-dimensional porous structure providing potential access to a high internal surface area. Unlike most others, it has the advantage of containing ammonium cations within the pores and has the ability to undergo cation exchange. Additionally, BIRM-1 also exhibits a reversible dehydration behavior involving an amorphization-recrystallization cycle. The ability to undergo ion exchange and dynamic structural behavior are of interest in their own right, but also increase the range of potential applications for this material. Here the crystal structure of this new metal phosphonate and its ion exchange behavior with K+ as an exemplar are studied in detail, and its unusual structure-reviving property reported. 相似文献
207.
Slow evaporation of an aqueous solution containing l-threonine and magnesium sulphate heptahydrate, results in the fractional crystallization of the less soluble l-threonine crystal and not any novel optoelectronic ‘magnesium sulfate admixtured l-threonine’ crystal as reported by Puhal Raj et al. in Optik, 124 (2013) 6887–6891. 相似文献
208.
209.
The new inorganic–organic hybrids based on SO3H‐functionalized ionic liquids (ILs) and Keggin‐type heteropoly acids (H3PW12O40, H3PMo12O40, and H4SiW12O40; HPAs) are prepared and characterized by FT‐IR, NMR, XRD, CV, SEM/EDX, ICP‐OES, BJH and UV. Different molecular structures according to the different inorganic part were also proved. Potentiometric titration showed a good relationship between catalytic activity and acidity of the catalysts. Electrochemical aspects showed electron transfer ability of the compounds. For understanding catalytic activities of the HPA‐IL hybrids in N‐formylation reaction, effect of catalyst composition, substrate, and reaction conditions were studied. The best SO3H‐functionalized ionic liquid catalyst was readily recovered and reused for four runs. Easy preparation of the catalyst, simple and easy work‐up, mild reaction conditions, low cost, excellent yields and short reaction times are the key features of this work. 相似文献
210.