Ni(tpt)(NO3)2—A Three-Dimensional Network with the Exceptional (12,3) Topology: A Self-Entangled Single Net

The shortest circuits in the three-dimensional network with (12,3) topology of solvated Ni(tpt)(NO₃)₂ pass through one another (see picture). This network based upon interlinked double helices occupies a unique position in the set of (n,3) nets. tpt=tri-4-pyridyl-1,3,5-triazine.     

页岩气高效开采的力学问题与挑战

页岩气是指赋存于富含有机质泥页岩中以吸附和游离状态为主要存在方式的天然气,中国资源量丰富,地域分布广泛.页岩气开采能缓解我国常规油气产量不足、煤化石燃料引起环境污染等问题,已成为中国绿色能源开发的重要领域.尽管北美页岩气"革命"取得了成功,目前也仅有预期产量5%～15%的采收率.与北美地区相比,中国页岩气埋藏深,赋存条件差,自然丰度低,因此,高效开采面临更多的困难和挑战.近年来,围绕国家重大能源战略需求,瞄准技术发展前沿,学术界和工业界联合对页岩气高效开采的关键科学和技术问题展开研究.本文结合近三年四川、重庆地区的页岩气试验区块遇到的新问题,针对中国未来3 500 m以下深部开采的新挑战,如地质沉积、裂缝发育构造不同、上覆压力增加、水平应力场变化等新问题,介绍和总结了目前中国页岩气高效开采面临的力学科学问题,主要包括多重耦合下的安全优质钻完井力学理论和方法、水力压裂体积改造和多尺度缝网形成机制、多尺度渗流力学特性与解吸附机理等."深部页岩气高效开采"的研究面向国家重大能源需求,科学意义重大,工程背景明确,需要工程力学、石油工程、地球物理、化学工程和环境工程等多学科专家合作,开展理论研究、物理模拟、数值模拟及现场试验等综合应用基础研究,取得高效开采页岩油气理论与技术的突破.学科交叉是研究页岩气高效开采问题、突破技术瓶颈的桥梁,只有力学与石油工程、地球科学等学科实现深度交叉融合,才能更加有效地推动页岩油气等非常规油气资源的开发.     

Halogen-Bond Mediated [2+2] Photodimerizations: À la Carte Access to Unsymmetrical Cyclobutanes in the Solid State

The ditopic halogen-bond (X-bond) donors 1,2-, 1,3-, and 1,4-diiodotetrafluorobenzene (1,2-, 1,3-, and 1,4-di-I-tFb, respectively) form binary cocrystals with the unsymmetrical ditopic X-bond acceptor trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpe). The components of each cocrystal (1,2-di-I-tFb)·(2,4-bpe), (1,3-di-I-tFb)·(2,4-bpe), and (1,4-di-I-tFb)·(2,4-bpe) assemble via N···I X-bonds. For (1,2-di-I-tFb)·(2,4-bpe) and (1,3-di-I-tFb)·(2,4-bpe), the X-bond donor supports the C=C bonds of 2,4-bpe to undergo a topochemical [2+2] photodimerization in the solid state: UV-irradiation of each solid resulted in stereospecific, regiospecific, and quantitative photodimerization of 2,4-bpe to the corresponding head-to-tail (ht) or head-to-head (hh) cyclobutane photoproduct, respectively.     

无胀缝坡道路面板热胀屈曲的摄动解

文中分析了无胀缝坡道路面板在温度场作用下热胀屈曲的力学机制.采用正则摄动法导出了坡道路面板临界铺设温差的渐近表达式,分析了坡道与水平直道路面板临界铺设温差之间的关系,得出了坡道与水平直道路面板热胀屈曲的统一解答,并据此给出了无胀缝坡道路面的合理铺设温差.     

Perturbation solution for thermal expansion buckling of no expansion joint slope pavement plate

In this paper,the mechanical mechanism of thermal expansion buckling of no expansion joint slope pavement undergoing the action of a temperature field is analysed.By using regular perturbation method,the formula of perturbation solution for this problem is derived,the relationship between critical laying temperature difference of slope pavement and of level straight pavement is studied,and the unified solution and its.numerical results are also obtained.In terms of this research,rational laying temperature of no expansion joint slope pavement is given.     

裂纹技术的基本原理与应用研究进展

本文介绍裂纹技术的基本原理及其应用。裂纹技术通过使裂纹沿给定路线扩展去达到切割材料的目的,它由魏庆同和郎福元在文[2]中首次提出。本文还概要讨论了裂纹技术中四个典型的力学问题,特别是断裂力学的逆问题。笔者希望这篇文章能够引起国内外学者对裂纹技术及其问题的关注。      

Surface patterning and biological evaluation of semi-interpenetrated poly(HEMA)/poly(alkyl β-malolactonate)s

Semi-interpenetrating hydrogel networks were prepared by radical polimerization of monomer HEMA, co-monomer EGDMA as cross-linking agent and in the presence of 1 wt % of poly(alkyl β-malolactonate)s. Biological evaluation in terms of cell adhesion and proliferation of the prepared materials showed the ability of HEMA-based hydrogels to sustain a good cell adhesion and proliferation. Moreover, a method based on soft-lithography to obtained surface microstructured semi-interpenetrating hydrogel networks was developed, thus allowing for further investigation of the influence of surface topography on cell behavior.     

工程服务外包中的激励机制和定价策略研究

工程服务外包是制造企业应对竞争、专注核心业务、降低成本的重要途径之一.在服务外包及由此形成的服务供应链的运作中,由于供应商直接向最终客户提供服务以及服务结果难以被衡量等原因,存在着道德风险问题,需要制造商向供应商提供激励.文章研究了工程服务外包中的最优激励机制问题,运用连续工作表现的道德风险模型构建了激励模型,得出最优的激励转移支付,并详细分析了供应商努力的必要性条件和参与性要求、不同激励程度的机制设计以及不同谈判力要求下的激励机制控制等问题,在此基础上提出了工程服务外包的定价模式.认为：1）只有符合特定需求分布条件的服务才需要激励使激励有效;2）最优激励转移支付存在一个震荡间断点;3）可以通过改变参数来调整激励的程度以及成员间的利润分配比例.     

Motional Quantum-State Engineering and Implementation of a Quantum Phase-Gate for Multiple Trapped Ions

We propose a scheme to generate a superposition of motional coherent states with arbitrary coefficients on a line in phase space and implement a quantum controlled phase-gate for multiple trapped ions with a single standing-wave laser pulse whose carrier frequency is tuned to the ions transition. In the scheme each ion does not need to be exactly positioned at the node of the standing wave, which is very important from viewpoint of experiment, Furthermore, our scheme may allow the generation of a superposition of coherent states with large mean phonon number for a large number of trapped ions in a fast way by choosing suitable laser intensity. We show that it can also be used to generate maximally entangled states of multiple trapped ions.