离子推力器束流引出状态对栅极刻蚀的影响

为了研究30 cm离子推力器束流引出状态对栅极刻蚀的影响,建立了束流引出模型,并采用PIC-MCC方法对CEX离子造成的栅极腐蚀速率进行了计算,最后将计算结果与1500 h寿命试验结果进行比对分析。结果显示：束流正常聚焦时,在3 kW和5 kW两种工作模式下,加速栅和减速栅的质量刻蚀速率分别为(1.11～1.72)×10⁻¹⁵ kg/s及(1.22～1.26)×10⁻¹⁷ kg/s。在5 kW工况下,当屏栅上游等离子体密度达到4.03×10¹⁷ m⁻³时,束流出现欠聚焦现象,此时加速栅和减速栅的最大离子刻蚀速率分别为4.33×10⁻¹⁵ kg/s和4.02×10⁻¹⁵ kg/s;在3 kW工况下,当屏栅上游等离子体密度达到0.22×10¹⁷ m⁻³时,束流出现过聚焦现象,此时加速栅和减速栅的最大离子刻蚀速率分别为3.24×10⁻¹⁵ kg/s和5.01×10⁻¹⁵ kg/s。寿命试验结果表明,加速栅孔质量刻蚀速率的计算值与试验值比对误差较小,而由于束流离子对减速栅孔的直接轰击,导致减速栅孔刻蚀速率的计算值和试验值差异极大。经研究认为,对屏栅小孔采用变孔径设计,是降低当束流处于欠聚焦或过聚焦状态下,CEX离子造成加速栅孔和减速栅孔刻蚀速率,并提升推力器工作寿命的有效措施。     

Application of Tikhonov regularization method to wind retrieval from scatterometer data Ⅱ: cyclone wind retrieval with consideration of rain

According to the conclusion of the simulation experiments in paper I, the Tikhonov regularization method is applied to cyclone wind retrieval with a rain-effect-considering geophysical model function (called GMF+Rain). The GMF+Rain model which is based on the NASA scatterometer-2 (NSCAT2) GMF is presented to compensate for the effects of rain on cyclone wind retrieval. With the multiple solution scheme (MSS), the noise of wind retrieval is effectively suppressed, but the influence of the background increases. It will cause a large wind direction error in ambiguity removal when the background error is large. However, this can be mitigated by the new ambiguity removal method of Tikhonov regularization as proved in the simulation experiments. A case study on an extratropical cyclone of hurricane observed with SeaWinds at 25-km resolution shows that the retrieved wind speed for areas with rain is in better agreement with that derived from the best track analysis for the GMF+Rain model, but the wind direction obtained with the two-dimensional variational (2DVAR) ambiguity removal is incorrect. The new method of Tikhonov regularization effectively improves the performance of wind direction ambiguity removal through choosing appropriate regularization parameters and the retrieved wind speed is almost the same as that obtained from the 2DVAR.     

Investigation on ultrasonic cavitation erosion of TiMo and TiNb alloys in sulfuric acid solution

Two kinds of Ti-alloys, i.e., TiMo and TiNb alloys are manufactured in this paper, and their ultrasonic cavitation erosion behaviors in 0.1 M H₂SO₄ solution are evaluated by the mean depth erosion (MDE), SEM and white light photograph. The results show that MDE of TiMo and TiNb alloys obviously increase with increasing the cavitation erosion time, however, they evidently decrease with the increment of Mo or Nb content at each fixed cavitation erosion time, and even some large blank areas (uneroded areas) still exist on the sample surface after ultrasonic cavitation erosion for 2 h in the case of Ti10Mo and Ti20Nb samples, implying the enhanced anti-cavitation erosion property of Ti-alloy by adding Mo or Nb element. The MDE of Ti10Mo or Ti20Nb sample is lower than that of TC4 sample in the case of each cavitation erosion time, indicating the better cavitation erosion resistance of of Ti10Mo or Ti20Nb sample. The influences of Mo and Nb on the passivity of TiMo and TiNb alloys during the ultrasonic cavitation erosion are detected by potentiodynamic curves. The results display that Ti, TC4, TixMo (x = 1, 5, 10) and TixNb (x = 5, 10, 20) samples are all almost in the passive state within the potential region from 0V_SCE to 1.5V_SCE during ultrasonic cavitation erosion, and the passive current density evidently decreases with increasing Mo or Nb content, indicating the enhanced passive characteristic by adding Mo or Nb alloys during the ultrasonic cavitation erosion.     

Computation of the Backscattering Power Density for Rainfall in Millimeter Waves Band

The size distribution and canting angle distribution for non-spherical rain drops are taken into account. Utilizing the Muller matrix, the backscattering power densities are computed at different rain rate and different polarization in millimeter waves band, according the rainfall condition in Xi'an, China. Finally the results obtained are discussed.     

霍尔推力器放电通道溅射腐蚀计算

为了预示霍尔推力器的寿命,建立了推力器粒子束放电通道的2维电磁场模型,模拟的推进剂为氙。利用PIC方法跟踪粒子在电磁场中的运动。磁场的求解采用拉普拉斯方程,电场的求解采用泊松方程。电子由阴极喷入通道,并在电磁场中与原子发生电离碰撞生成离子。在跟踪离子的过程中记录下撞击到内外壁面的离子个数、角度和能量。利用记录下的参数进行腐蚀计算,得到当溅射阈值能量分别为10,20,30,40,50 eV时通道壁面的腐蚀速率。推力器放电通道出口附近的最大腐蚀速率约为1.7×10-9 m/s。     

Electromagnetic wave propagation in rain and polarization effects

This paper summarizes our study on microwave and millimeter-wave propagation in rain with special emphasis on the effects of polarization. Starting from a recount of our past findings, we will discuss developments with these and how they are connected with subsequent research.     

Design of a rate- and time-programming drug release device using a hydrogel: pulsatile drug release from κ-carrageenan hydrogel device by surface erosion of the hydrogel

We have found that a repetitive pulsatile drug release with a certain time interval is observed from a monolithic hydrogel device by surface erosion of the hydrogel. As a model system of pulsatile drug release, dibucaine hydrochloride and κ-carrageenan hydrogel were chosen as a drug and a device, respectively. Electrostatic interactions between dibucaine hydrochloride and κ-carrageenan polymer segments are strong, since dibucaine hydrochloride is positively charged and each disaccharide repeating unit of κ-carrageenan chains has one sulfate group. Dibucaine hydrochloride was loaded into the hydrogel by immersing dry κ-carrageenan hydrogel disks in a dibucaine hydrochloride solution for 24 h. The pulsed release of dibucaine hydrochloride from the device was observed every 50 min between 30 and 250 min after the release starts. The weight of κ-carrageenan hydrogel decreases in an oscillatory manner with time in distilled water. The oscillatory changes observed in the hydrogel weight in distilled water are considered to be caused by influx and efflux of water molecules into and from the surface and core of the hydrogel and by polymer liberation from the hydrogel. This phenomenon was well explained by our kinetic model [Colloids and Surfaces B 8 (1996) 93–100]. The time interval between pulses observed in drug release coincides with that observed in the oscillatory weight change of the hydrogel. From these, it was concluded that the pulsatile release of dibucaine hydrochloride from the device was caused by the pulsatile liberation of swollen κ-carrageenan hydrogel from the surface of the device.     

Investigation on biological properties of tacrolimus-loaded poly(1,3-trimethylene carbonate) in vitro

The drug-eluting stents have been regarded as a milestone in inhibiting the restenosis of coronary arteries. However, adverse reactions caused by bare-metal stents and non-biodegradable polymer coatings may result in some clinical problems. In this study, a new tacrolimus-eluting stent coated with biodegradable poly(1,3-trimethylene carbonate) (PTMC) is developed. The structures are characterized by Fourier transform infrared (FTIR) analysis, and the wettability is measured by contact angle assay. The biological behaviors are evaluated by the in vitro platelets adhesion test, APTT test, the human umbilical cord artery smooth muscle cells (HUCASMCs), 4′,6-diamidine-2-phenylindole (DAPI) and actin immunofluorescence staining, MTT colorimetric assay. These results show that after blending tacrolimus into PTMC, the anticoagulant behavior is improved, and the adhesion and proliferation of HUCASMCs on samples are inhibited. This work aims to find one kind of surface erosion biodegradable polymers that can be applied as drug-eluting stent coatings.     

Supramolecular Control of Ester Hydrolysis in Poly(ethylene glycol)‐Interlocked Hydrogels

Poly(ethylene glycol) (PEG)‐interlocked hydrogels were prepared by linking the PEG with α‐cyclodextrins (α‐CDs) threaded onto a PEG chain having ester linkages at the terminals (hydrolyzable polyrotaxane). These hydrogels were examined to clarify the effect of ionic strength of phosphate buffers, pH, and the addition of ethanol on erosion time in relation to inclusion states of α‐CDs with the ester linkages. The most characteristic phenomenon of the hydrogel erosion was observed in an ethanol/PBS cosolvent system: the time to reach the complete erosion time was shortened with decreasing water content. NMR analysis revealed that the ester linkages were exposed to the aqueous environment due to the aggregation of α‐CDs. These results suggest that the movement of α‐CDs in the polyrotaxanes from the terminal ester region to the another region gives the ester linkages a chance to interact with water.

     

库仑滴定法测定酸雨中总氢离子浓度

本文用库仑滴定法结合Gran图,测定酸雨中的“自由氢离子”和“被束缚的氢离子”的总浓度。并对雨水中常出现的Fe~(3+)、Al~(3+)等离子的干扰影响也进行了探讨。并对10~(-4)～10~(-5)mol·L~(-1)浓度范围内标准硫酸溶液滴定结果进行了考察;以Gran函数((?)及(?)′)对滴定时间(t)作图,得一直线。相对误差在±5%左右。同时用该方法对武汉酸雨样品进行了实际测量。用标准加入法测得其回收率在90.8以上。