重度原油注空气低温氧化过程研究(英文)

低温氧化反应对现场燃烧(ISC)技术点火的成功有十分重要的影响.采用高压氧化管,研究了不同温度压力下,新疆克拉玛依重度原油的低温氧化过程.结果表明,温度和压力的变化对低温氧化反应的放热程度、持续时间以及气体产物有明显影响.适合油样低温氧化反应的温度和压力分别为150℃和10MPa.此外,采用纯组分替代原油族组分进行低温氧化实验,研究低温氧化反应对原油族组分(饱和烃、芳香烃、胶质、沥青质)含量的影响.结果表明,原油所含族组分中,芳香烃组分最易被氧化,其含量由氧化前的19.17%减少到12.38%(150℃)和9.51%(250℃).随着低温氧化过程的进行,结构复杂的族组分(胶质、沥青质)的含量明显增加.实验数据对油藏实施注空气技术,以及该技术现场实施条件的确定有十分重要的指导意义.     

Raman spectroscopy of CaM2+Ge2O6 (M2+ = Mg,Mn, Fe,Co, Ni,Zn) clinopyroxenes

The Raman spectra of Ge‐clinopyroxenes CaM²⁺Ge₂O₆ (M²⁺ = Mg, Mn, Fe, Co, Ni, Zn), general formula M2M1T₂O₆, are reported for the first time. Their spectral features are discussed in comparison with corresponding Si‐pyroxenes. The vibrational wavenumbers of germanates may be roughly obtained by a scale factor of about ~0.8 by those of the corresponding silicates, due to the Ge‐Si mass difference. The main peaks in the germanate Raman spectra at ~850 and ~540 cm⁻¹ may be related to Ge‐O tetrahedral stretching and chain bending, respectively; minor peaks between 200 and 400 cm⁻¹ are ascribed to bending and stretching of the non‐tetrahedral cations. Within Ge‐pyroxenes, possible correlations between crystallographic parameters and the vibrational wavenumbers are investigated. The main stretching mode at ~850 cm⁻¹ shows wavenumber changes with M²⁺ substitutions, but no simple correlation can be found with M²⁺ cation mass or size. On the other hand, the chain bending wavenumber linearly decreases with increasing ionic radius of the M²⁺ cation: the expansion of the M1 polyhedron reduces the chain kinking angle and the Ge‐Ge distances correspondingly increase. Copyright © 2015 John Wiley & Sons, Ltd.     

In Vitro Antiplasmodial and Cytotoxic Activities of Compounds from the Roots of Eriosema montanum Baker f. (Fabaceae)

Malaria remains one of the leading causes of death in sub-Saharan Africa, ranked in the top three infectious diseases in the world. Plants of the Eriosema genus have been reported to be used for the treatment of this disease, but scientific evidence is still missing for some of them. In the present study, the in vitro antiplasmodial activity of the crude extract and compounds from Eriosema montanum Baker f. roots were tested against the 3D7 strain of Plasmodium falciparum and revealed using the SYBR Green, a DNA intercalating compound. The cytotoxicity effect of the compounds on a human cancer cell line (THP-1) was assessed to determine their selectivity index. It was found that the crude extract of the plant displayed a significant antiplasmodial activity with an IC₅₀ (µg/mL) = 17.68 ± 4.030 and a cytotoxic activity with a CC₅₀ (µg/mL) = 101.5 ± 12.6, corresponding to a selective antiplasmodial activity of 5.7. Bioactivity-guided isolation of the major compounds of the roots’ crude extract afforded seven compounds, including genistein, genistin and eucomic acid. Under our experimental conditions, using Artemisinin as a positive control, eucomic acid showed the best inhibitory activity against the P. falciparum 3D7, a well-known chloroquine-sensitive strain. The present results provide a referential basis to support the traditional use of Eriosema species in the treatment of malaria.     

Optimized IR synchrotron beamline design

Synchrotron infrared beamlines are powerful tools on which to perform spectroscopy on microscopic length scales but require working with large bending‐magnet source apertures in order to provide intense photon beams to the experiments. Many infrared beamlines use a single toroidal‐shaped mirror to focus the source emission which generates, for large apertures, beams with significant geometrical aberrations resulting from the shape of the source and the beamline optics. In this paper, an optical layout optimized for synchrotron infrared beamlines, that removes almost totally the geometrical aberrations of the source, is presented and analyzed. This layout is already operational on the IR beamline of the Brazilian synchrotron. An infrared beamline design based on a SOLEIL bending‐magnet source is given as an example, which could be useful for future IR beamline improvements at this facility.     

Investigation of flexural properties and failure behaviour of biaxial braided CFRP

In this research, the experimental tests of quasi-static three-point bending and three-point bending fatigue were carried out for a ±25° biaxial braided carbon fibre reinforced polymer (CFRP) manufactured using vacuum assisted resin transfer moulding (VARTM). A finite element (FE) model was also set up for quasi-static testing and the prediction results revealed that local fibre volume fraction (FVF) is a primary source affecting the mechanical properties of braided CFRP. The fatigue of the braided CFRP was defined as three different stages according to the flexural modulus results. The damage modes of the test specimens were observed via a digital microscope and scanning electron microscope (SEM) and the process-induced defects were summarised. With compiled results and observations, this study provides a better understanding of failure and fatigue behaviour of biaxial braided composites and their flexural properties which offers a good basis for any further research in fibre volume fractions, structure design and manufacturing for braided CFRP.     

Coherence transfer delay optimisation in PSYCOSY experiments

PSYCOSY is an f1 broadband homonuclear decoupled version of the COSY nuclear magnetic resonance pulse sequence. Here, we investigate by a combination of experimental measurements, spatially distributed spin dynamics simulations, and analytical predictions the coherence evolution delay necessary in PSYCOSY experiments to ensure intensity discrimination in favour of the correlations typically arising from short range (ⁿJ, n ≤ 3) ¹H–¹H couplings and show that, in general, a coherence evolution delay of around 35 ms is optimum.     

任意边界条件下双模量矩形薄板的弯曲

将双模量板等效为两个各向同性小矩形板组成的层合板,假定该层合板的中性面即为两个小矩形板的交界面。根据中性面上应力为零且薄板全厚度上应力的代数和为零,推导了双模量矩形薄板的中性面位置。本文采用严宗达提出的带补充项的双重正弦傅里叶级数通解,该通解可以适用于任意边界条件的矩形薄板且不需要叠加或者重新构造。联立边界条件和控制方程,求得通解中的待定系数并代入到通解中,即可得到任意边界条件下双模量矩形薄板的弯曲解析解。与有限元结果比较,本文结果符合工程精度要求。     

Band bending at the conducting polymer/indium tin oxide interfaces with and without ultraviolet treatment

In this study, the effect of ultraviolet treatment on the band bending at the poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate)/indium tin oxide (PEDOT:PSS/ITO) interfaces were researched. The authors suggested that ultraviolet treatment could lead to a reduction in the band bending at the PEDOT:PSS/ITO interface, owing to the removal of carbon contamination at the ITO surfaces and a decrease in the number of the trap-states at the PEDOT:PSS/ITO interface.     

Load’s temporal characteristics for annulling forced vibrations of linear elastic plates

We consider trapezoidal load-time pulses with linearly increasing and affinely decreasing durations equal to integer multiples of the time period of the first bending mode of vibration of a linearly elastic structure. For arbitrary spatial distributions of loads applied to monolithic and laminated orthotropic plates, it is shown through numerical solutions that plates’ vibrations become miniscule after the load is removed. This phenomenon is independent of the dwell time (i.e., the time duration between the rising and the falling portions) during which the load is kept constant. The primary reason for this response is that for such time-dependent loads, nearly all of plate’s strain energy is concentrated in deformations corresponding to the fundamental bending mode of vibration. Thus plate’s deformations can be studied by taking the mode shape of the 1st bending mode as the basis function and reducing the problem to that of solving a single second-order ordinary differential equation. We have verified this postulate by comparing strain energies computed from the 3-dimensional deformations of different plate geometries and boundary conditions with those determined by using the single degree of freedom (DoF) model. Thus for trapezoidal time-dependent loads applied on plates, the 1 DoF model provides reasonably accurate results and saves considerable computational effort.     

LOCAL BENDING OF THIN FILM ON VISCOUS LAYER

Effects of deposition layer position film are systematically investigated. Because the and number/density on local bending of a thin deposition layer interacts with the thin film at the interface and there is an offset between the thin film neutral surface and the interface, the deposition layer generates not only axial stress but also bending moment. The bending moment induces an instant out-of-plane deflection of the thin film, which may or may not cause the socalled local bending. The deposition layer is modeled as a local stressor, whose location and density are demonstrated to be vital to the occurrence of local bending. The thin film rests on a viscous layer, which is governed by the Navier-Stokes equation and behaves like an elastic foundation to exert transverse forces on the thin film. The unknown feature of the axial constraint force makes the governing equation highly nonlinear even for the small deflection chse. The constraint force and film transverse deflection are solved iteratively through the governing equation and the displacement constraint equation of immovable edges. This research shows that in some special cases, the deposition density increase does not necessarily reduce the local bending. By comparing the thin film deflections of different deposition numbers and positions, we also present the guideline of strengthening or suppressing the local bending.