Polymer adsorption on heterogeneous surfaces

The adsorption of a single ideal polymer chain on energetically heterogeneous and rough surfaces is investigated using a variational procedure introduced by Garel and Orland (Phys. Rev. B 55, 226 (1997)). The mean polymer size is calculated perpendicular and parallel to the surface and is compared to the Gaussian conformation and to the results for polymers at flat and energetically homogeneous surfaces. The disorder-induced enhancement of adsorption is confirmed and is shown to be much more significant for a heterogeneous interaction strength than for spatial roughness. This difference also applies to the localization transition, where the polymer size becomes independent of the chain length. The localization criterion can be quantified, depending on an effective interaction strength and the length of the polymer chain. Received: 29 October 1997 / Revised: 19 December 1997 / Accepted: 6 March 1998     

次序统计量线性函数的随机加权逼近速度

设ｘ１，ｘ２，…ｘｎ（连续未知），Ｆｎ为经验分布函数，Ｈｎ（ｘ）为随机加权经验分布函数，。ｘｎ１≤ｘｎ２≤…≤ｘｎｎ为次序统计量．记以Ｆｎ取代σ２（Ｊ，Ｆ）中的Ｆ即得σ２（Ｊ，Ｆｎ）．     

SOME COMPARISONS BETWEEN GENERALIZED ORDER STATISTICS

Some stochastic comparisons of generalized order statistics under the right spread order,the location independent riskier order and the total time transform order are investigated in this paper.The underlying distributions and parameters on which generalized order statistics are based are also surveyed to obtain the conditions for increasing the expectations of spacings between the first two generalized order statistics and between the last two generalized order statistics.     

中国特大城市自行车到达的统计分布研究

在运用数理统计方法分析实际数据的基础上,结合国内外的已有研究结果,初步认为在自行车流量小的情况下,泊松分布比较适用于描述自行车到达量的统计分布;而当自行车流量很大时,负二项分布比较适合描述一定条件下的自行车到达量的统计分布.考虑到自行车到达分布的复杂性,文中借鉴知识推理的一些概念和方法,非精确地描述了自行车到达分布规律.     

直觉Menger空间中的广义压缩映射原理及其在微分方程中的应用

利用Atanassov的思路,将直觉Menger空间定义为由Menger提出的Menger空间的自然推广.同时也得出一个新广义压缩映射,并运用该压缩映射证明了直觉Menger空间中微分方程解的存在性定理.     

用概率断裂力学方法预测管状接头的疲劳寿命

本文研究了Ｔ型管状接头在面内和面外弯曲循环载荷作用下的疲劳强度问题，通过将材料常数和初始裂纹尺寸作为随机变量，采用ＭｏｎＣａｒｌｏ模拟方法对疲劳寿命进行了统计分析．同时，对计算结果进行了线性回归，并与实验结果作了比较。     

Asymptotic Bound on the Characteristic Function of Signed Linear Serial Rank Statistics

This work establishes an asymptotic bound on the characteristic function of signed linear serial rank statistics. The result is obtained under rather general conditions including the important case of van der Waerden scores. It generalizes the result of Seoh (1983, Ph.D. Thesis, Department of Mathematics, Indiana University) and constitutes an essential step to the elaboration of Berry-Esséen's bounds and the establishment of Edgeworth expansions. These statistics constitute a natural tool for testing the hypothesis of white noise with a symmetrical (unspecified) distribution in comparison to other alternative hypothesis of serial dependence.     

关于随机共轭空间的各种定义及随机线性泛函各种有界性的某些评论

中心目的是详细廉政论在随机共轭空间理论形成过程中所经历的三个阶段的工作，尤其指出了这三个阶段工作之间的联系及本质差别；给出了强有界、拓扑有界及几乎处处有界随机线性泛函之间的关系；亦指出了在概率赋范空间上线性算子理论研究中目前存在的不足．     

Experiments with single atoms in cavities and traps

ＥｘｐｅｒｉｍｅｎｔｓｗｉｔｈｓｉｎｇｌｅａｔｏｍｓｉｎｃａｖｉｔｉｅｓａｎｄｔｒａｐｓＨ．Ｗａｌｔｈｅｒ（ＳｅｋｔｉｏｎＰｈｙｓｉｋｄｅｒＵｎｉｖｅｒｓｉｔａｔＭｕｎｃｈｅｎａｎｄＭａｘ－Ｐｌａｎｃｋ－ＩｎｓｔｉｔｕｔｆｕｒＱｕａｎｔｅｎｏｐｔｉｋ...     

Adsorption and spreading of polymers at plane interfaces; theory and molecular dynamics simulations

Nonequilibrium processes play a key role in the adsorption kinetics of macromolecules. It is expected that the competition between transport of polymer towards an interface and its subsequent spreading has a significant influence on the adsorbed amount. An increase of the transport rate can lead to an increase of the adsorbed amount, especially when the polymer has too little time to spread at the interface. In this study we present both molecular dynamics simulations and analytical calculations to describe some aspects of the adsorption kinetics. From MD simulations on a poly(ethylene oxide) chain in vacuum near a graphite surface, we conclude that the spreading process can, in first approximation, be described by either a simple exponential function or by first-order reaction kinetics. Combining these spreading models with the transport equations for two different geometries (stagnation-point flow and overflowing cylinder) we are able to derive analytical equations for the adsorption kinetics of polymers at solid-liquid and at liquid-fluid interfaces. Received: 18 July 1997 / Received in final form: 27 October 1997 / Accepted: 6 November 1997