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931.
I. E. Filatov G. L. Rusinov O. N. Chupakhin X. Solans M. Font-Bardia M. Font-Altaba 《Russian Chemical Bulletin》1994,43(7):1214-1219
The reaction of 2-chloro-3,5-dinitropyridine with two equivalents of KN3 in the presence of ROH results in stable Meisenheimer-type -adducts of 4,6-dinitrotetra-zolo[1,5-a]pyridine with RO– anions (R = H, Alk, Ph). The mechanism of -complex formation was suggested. The structure of the -adduct with R = Me was established by IR and NMR spectroscopy and by X-ray diffraction analysis.For the preliminary communication, see Ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1278–1283, July, 1994.This work was supported by the Russian Foundation for Basic Research (project code 93-03-5329). 相似文献
932.
In this paper we consider a class of systems described by singular integrodifferential equations. This type of systems appear, for example, in the modeling of certain aeroelastic control problems. We study these systems in frequency domain framework and show the existence of finite-dimensional stabilizing controllers. An algorithmic procedure is outlined for the construction of such controllers. In order to illustrate the numerical aspects of this algorithm, we present an example involving the classical Theodorsen model of an airfoil, which fits in the class of systems considered here.This work was supported in part by the National Science Foundation under Grants DMS-8907019 and MSS-9203418. 相似文献
933.
Yoshinobu Kamishima 《Annals of Global Analysis and Geometry》1994,12(1):261-289
A strictly pseudoconvex pseudo-Hermitian manifoldM admits a canonical Lorentz metric as well as a canonical Riemannian metric. Using these metrics, we can define a curvaturelike function onM. AsM supports a contact form, there exists a characteristic vector field dual to the contact structure. If induces a local one-parameter group ofCR transformations, then a strictly pseudoconvex pseudo-Hermitian manifoldM is said to be a standard pseudo-Hermitian manifold. We study topological and geometric properties of standard pseudo-Hermitian manifolds of positive curvature or of nonpositive curvature . By the definition, standard pseudo-Hermitian manifolds are calledK-contact manifolds by Sasaki. In particular, standard pseudo-Hermitian manifolds of constant curvature turn out to be Sasakian space forms. It is well known that a conformally flat manifold contains a class of Riemannian manifolds of constant curvature. A sphericalCR manifold is aCR manifold whose Chern-Moser curvature form vanishes (equivalently, Weyl pseudo-conformal curvature tensor vanishes). In contrast, it is emphasized that a sphericalCR manifold contains a class of standard pseudo-Hermitian manifolds of constant curvature (i.e., Sasakian space forms). We shall classify those compact Sasakian space forms. When 0, standard pseudo-Hermitian closed aspherical manifolds are shown to be Seifert fiber spaces. We consider a deformation of standard pseudo-Hermitian structure preserving a sphericalCR structure.Dedicated to Professor Sasao Seiya for his sixtieth birthday 相似文献
934.
Aleksandr V. Prichodko Evgenii V. Shatkovski Sergei G. Yastrebov 《International Journal of Infrared and Millimeter Waves》1994,15(3):579-584
Photostimulated changes in thin carbon films deposited onto fused silica substrates by reactive magnetron sputtering and irradiated by the light of the first (1060nm) and the second (530nm) harmonics of a QW-switched Nd3+ AVG laser were investigated. The changes are supposed to be connected with the reordering of chemical bounds. 相似文献
935.
Photoproducts of pyridoxal-5-P, i.e., 4-pyridoxic-5-P and bis-pyridoxal-5-P, have been studied by spectroscopic methods. The spectroscopic properties of bis-pyridoxal-5-P (bis-PLP) resemble those of pyridoxal-5-P (PLP) under similar experimental conditions. The coupling of methylen hydrogens to the phosphorus atom has been shown by NMR spectroscopy. The singlet in the31P-NMR spectra and the triplet in1H-undecoupled experiments confirm the presence of the phosphate group in the 5 position of the structure of the vitamin. The effect of pH and solvent composition on the relative distribution of species of bis-pyridoxine-5-P (bis-PNP) has been investigated by absorption and fluorescence spectroscopy. The acid-base dissociation of the phosphate group is easily detected by emission spectroscopy. Bis-PNP and bis-PLP bind to the enzyme RNase A and they behave as competitive inhibitors with respect to the substrate cytidine-2-3-cyclic phosphate. The natural forms of vitamin B6, pyridoxine, and pyridoxine-5-P have no effect on the catalytic activity of the protein. Experimental evidence derived from fluorescence and inhibition experiments is consistent with the hypothesis that bis-PNP recognizes the catalytic site of RNase A. 相似文献
936.
We consider variational problems involving nonlocal free energy functionals that arise from Gibbs measures with Kac potentials and are related to the characterization of the optimal (i.e., typical) shape of an interface under given constraints on the magnetization profile. 相似文献
937.
G. Alberti G. Bellettini M. Cassandro E. Presutti 《Journal of statistical physics》1996,82(3-4):743-796
We consider an Ising spin system with Kac potentials in a torus of d,d>-2, and fix the temperature below its Lebowitz-Penrose critical value. We prove that when the Kac scaling parameter vanishes, the log of the probability of an interface becomes proportional to its area and the surface tension, related to the proportionality constant, converges to the van der Waals surface tension. The results are based on the analysis of the rate functionals for Gibbsian large deviations and on the proof that they -converge to the perimeter functional of geometric measure theory (which extends the notion of area). Our considerations include nonsmooth interfaces, proving that the Gibbsian probability of an interface depends only on its area and not on its regularity. 相似文献
938.
A. Salam 《Numerical Algorithms》1996,11(1):327-337
The vector -algorithm is obtained from the scalar -algorithm by taking the pseudo-inverse of a vector instead of the inverse of a scalar. Thus the vector -algorithm is known only through its rules contrarily to the scalar -algorithm and some other extrapolation algorithms.The aim of this paper is to provide an algebraic approach to the vector -algorithm. 相似文献
939.
The Modified Barrier Functions (MBF) have elements of both Classical Lagrangians (CL) and Classical Barrier Functions (CBF). The MBF methods find an unconstrained minimizer of some smooth barrier function in primal space and then update the Lagrange multipliers, while the barrier parameter either remains fixed or can be updated at each step. The numerical realization of the MBF method leads to the Newton MBF method, where the primal minimizer is found by using Newton's method. This minimizer is then used to update the Lagrange multipliers. In this paper, we examine the Newton MBF method for the Quadratic Programming (QP) problem. It will be shown that under standard second-order optimality conditions, there is a ball around the primal solution and a cut cone in the dual space such that for a set of Lagrange multipliers in this cut cone, the method converges quadratically to the primal minimizer from any point in the aforementioned ball, and continues, to do so after each Lagrange multiplier update. The Lagrange multipliers remain within the cut cone and converge linearly to their optimal values. Any point in this ball will be called a hot start. Starting at such a hot start, at mostO(In In
-1) Newton steps are sufficient to perform the primal minimization which is necessary for the Lagrange multiplier update. Here, >0 is the desired accuracy. Because of the linear convergence of the Lagrange multipliers, this means that onlyO(In
-1)O(In In
-1) Newton steps are required to reach an -approximation to the solution from any hot start. In order to reach the hot start, one has to perform
Newton steps, wherem characterizes the size of the problem andC>0 is the condition number of the QP problem. This condition number will be characterized explicitly in terms of key parameters of the QP problem, which in turn depend on the input data and the size of the problem.Partially supported by NASA Grant NAG3-1397 and National Science Foundation Grant DMS-9403218. 相似文献
940.
Muhammad El-Taha 《Queueing Systems》1996,22(1-2):47-63
An input-output processZ = {Z(t), t 0} is said to be-rate stable ifZ(t) = o((t)) for some non-negative function(t). We prove that the processZ is -rate stable under weak conditions that include the assumption that input satisfies a linear burstiness condition and Z is asymptotically average stable. In many cases of interest, the conditions for-rate-stability can be verified from input data. For example, using input information, we establish-rate stability of the workload for multiserver queues, an ATM multiplexer, and-rate stability of queue-length processes for infinite server queues. 相似文献