TiO2半导体薄膜的制备与特性

ＴｉＯ_２半导体薄膜的制备与特性徐明霞，徐廷献，刘宁（天津大学材料系天津３０００７２）关键词ＴｉＯ_２，半导体薄膜，制备ＴｉＯ２薄膜或涂层，作为优良的色材、氧敏传感器材料和湿式太阳电池的光电阳极材料具有广阔的应用前景［１～３］．传统制膜技术主要采用物理...     

Experimental research on transient heat transfer in sand

In order to examine if the heat conduction in porous material behaves like a wave as claimed by other researchers, experiments on transient heat transfer is conducted in casting sand. The results show that the heat propagation can be described neither by wave nor by diffusion model. The CV-wave concept is discussed and challenged according to the experimental results in the entire transient stage, including the transient response of temperature and the response curve of penetration-depth versus penetration-time.     

Bi_4Ti_3O_(12)薄膜的结构与形貌分析

采用金属与金属氧化物复合靶的射频溅射法,在S_1,Au,Pt和Ti基片上沉积制备Bi_4Ti_3O_(12)(BTO)铁电薄膜,对不同基片沉积的BTO薄膜,以及不同退火温度下的薄膜的相结构、成分及形貌进行了分析。结果表明,BTO薄膜的结构与退火温度和沉积基片有关,不同基片上钙钛矿结构形成的温度按T_t相似文献   

金刚石膜合成条件下的鞘层与等离子体参数分布

本文报导了在用热阴极直流放电等离子体化学气相沉积（通常也称ＥＡＣＶＤ．即电子辅助化学气相沉积）方法合成金刚石的条件下的等离子体密度、电子温度、等离子体空间电位分布及基片附近等离子体鞘结构，并讨论其对成膜的影响．     

一种新型叠层光敏全息记录软片

通过化学反应，在三醋酸纤维素睛基的正反两面同时生成具有感光活性的光敏层的方法，获得了一种具有叠层光敏性的全息记录软片：重铬酸盐－三醋酸纤维素酯。由该软片记录的叠层体积全息光栅，具有迄今为止，最高的一级实验衍射效率（５４％）。     

用于投影显示的分色合色膜系的消偏振设计

由于斜入射时,光学薄膜存在一定的偏振效应,将产生S-和P-偏振光的光谱分离.在Philips棱镜系统中,分色合色膜系通常分色时对S-光应用,合色时则对P-光应用.从提高光能利用率、减少杂散光和增加系统对比度等因素综合考虑,要求分色合色膜系的S-和P-偏振光的分离尽可能小.新设计方法采用宽带法布里－珀罗薄膜干涉滤光片中心波长两侧的干涉带作为长波通或短波通截止滤光片,可实现S-和P-偏振分量的分离几乎为零.     

Large-Scale Production of 3D Bioactive Glass Macroporous Scaffolds for Tissue Engineering

For tissue engineering applications, a scaffold is required that can act as a template and guide for cell proliferation, cell differentiation and tissue growth. Interconnected pores with diameters greater than 100 m are required for tissue ingrowth, vascularisation and nutrient delivery to the centre of the scaffold. 3D bioactive glass scaffolds have been produced, by foaming sol-gel derived bioactive glasses. The method to produce foams with a modal macropore diameter of 100 m, and a handling strength suitable for cell culture, was to foam 50 ml batches of sol with the aid of a surfactant and gelling agent. In vitro and in vivo tests show that the scaffolds have high potential to be used in bone tissue engineering applications. Larger batches are required to produce scaffolds commercially. The aim of this work was to investigate how the process could be up-scaled for commercial use. This study shows that foaming larger aliquots of sol decreased the scaffold porosity and interconnectivity and investigates methods of modifying the process to obtain large quantities of foam scaffolds with pores in excess of 100 m. The optimum method to produce foams of similar pore structure from 200 ml sol to those produced from 50 ml sol comprised of adding 3 ml surfactant and 12 ml dionised water to the sol to start foaming and injecting a gas mixture (70% helium, 30% nitrogen) at 0.2 bar while applying vigorous agitation.     

Capacitive sensors using electropolymerized o-phenylenediamine film doped with ion-pair complex as selective elements for the determination of pentoxyverine

A capacitive sensing method based on electropolymerized o-phenylenediamine film doped with pentoxyverine ion-pair complex as selective element was successfully developed for the determination of pentoxyverine. Ion-pair complex, pentoxyverine-tetraphenylborate or pentoxyverine-picrolonate, was embedded in electropolymerized o-phenylenediamine film by electropolymerizing technique. The effects of working frequency and test solution pH on the detection of pentoxyverine were investigated in detail and optimized. For the sensor modified with pentoxyverine-tetraphenylborate, calibration curve was linear over the concentration range of 5.0×10⁻⁷ to 1.0×10⁻⁴ M with a detection limit of 1.0×10⁻⁷ M at pH 7. The proposed sensor exhibited high selectivity and sensitivity to pentoxyverine. The results in sample analysis confirmed the usefulness of the proposed ISC sensor for quantitative analysis, and also indicated that this method might find applications in the assay of other drugs.     

Organosilica materials with 1,5-bis-(2’-ethyl)-2,4-dimethyl benzene bridging groups

Using 1,5-bis-(2-trichlorosilylethyl)-2,4-dimethyl benzene, we have obtained porous organosilica materials containing 1.5 to 100 mole % 1,5-bis-(2-ethyl)-2,4-dimethyl benzene bridging groups. We have used X-ray phase analysis, adsorption, Fourier transform IR (FTIR) spectroscopy, thermogravimetry, and temperature-programmed desorption mass spectrometry methods to study their structure and composition. We have shown that the materials obtained generally are characterized by a biporous structure and aerosol properties: large pore volume (up to 4 cm³/g) and low density (~70 mg/cm³).Translated from Teoreticheskaya i Éksperimentalnaya Khimiya, Vol. 40, No. 6, pp. 373–379, November–December, 2004.