考虑最大与最小孔隙半径比的相渗曲线计算模型

相对渗透率对指导油田开发具有十分重要的作用,分形理论的出现为计算相对渗透率曲线提供了一种新的方法,但已有求取相对渗透率曲线的分形模型都将最大与最小孔隙半径比视为无穷大进行简化计算,误差较大.因此建立了考虑最大与最小孔隙半径比求取油水相渗曲线的模型,并分析了最大与最小孔隙半径比对相渗曲线的影响,结果表明最大与最小孔隙半径比的增大对油相渗透率影响微弱,对水相渗透率影响巨大,且水相渗透率曲线随着最大最小半径比的增大渐向右移,两相区面积逐渐减小,当比值为无穷大时两相区面积为零.最后,结合F储层,验证了采用比值变化模型计算的相渗曲线与实验测得曲线误差甚微.说明该方法简单易行,精准度高,值得推广与应用.     

Behaviour of pure water and water mixture with benzene or chloroform adsorbed onto ordered mesoporous silicas

Structural characteristics of synthesized ordered mesoporous silicas MCM-41, MCM-48 and SBA-15 were studied using XRD, nitrogen adsorption and FTIR methods. Pure water and mixtures with water/benzene and water/chloroform-d adsorbed onto silicas were studied by ¹H NMR spectroscopy with layer-by-layer freezing-out of bulk and interfacial liquids. Concentrated aqueous suspensions of MCM-48 and SBA-15 were studied by thermally stimulated depolarization current (TSDC) method. Benzene and chloroform-d can displace a portion of water to broad pores from the pore walls and from narrower pores, especially in the case of a large excess of an organic solvent. This process is accompanied by diminution of both interaction energy of water with an adsorbent surface and freezing temperature depression of adsorbed water. The effect of nonpolar benzene on pore water is much stronger than that of weakly polar chloroform-d. Modifications of the Gibbs-Thomson relation to describe the freezing point depression of mixtures of immiscible liquids confined in pores allow us to determine distribution functions of sizes of structures with unfrozen pore water and benzene. Former address: Pisarzhevskii Institute of Physical Chemistry, 31 Prospect Nauki, Kiev, Ukraine     

Relaxation Oscillation Enhancement and Coherence Collapse in Semiconductor Lasers with Optical Feedback

The dynamic characteristics of a semiconductor laser with optical feedback are strongly dependent on the injection current and the reflectivity and position of the external feedback reflector. We investigated the relaxation oscillation enhancement and coherence collapse state of the laser oscillation based on the laser rate equations. It is well known that laser output power jumps with increase of the injection current due to external mode transition. But here for the first we time demonstrate the existence of a chaotic scenario within successive laser power jumps. The results calculated by numerical simulations based on the rate equations are compared with those of the experiments and good coincidence between them is found.     

New Approximate Model for Nonlinear Adsorption and Concentration Dependent Surface Diffusion in a Single Particle

A new approximate model for nonlinear adsorption (Langmuir model) and concentration dependent surface diffusion (HIO model) in a single particle was derived, based on a parabolic concentration profile assumption for the summation of the gas and adsorbed phases. The surface diffusivity was approximated with the adsorbed phase concentration evaluated at the surface of the particle, as the average of the adsorbed phase concentration, and as the average of the first two approximations. Overall, the approximate model based on the average of the first two approximations compared the best with the exact solution for a wide variety of systems and conditions.     

流体动力润滑油膜破裂的热力学失稳机理

分析了流体动力学润滑过程中的热量传递及对润滑剂流变特性的影响,得出了流体动力润滑油膜发生热力学失稳的条件,建立了描述润滑剂温度非牛顿效应的本构方程数值计算结果表明,由于温度的影响,流体动力润滑油膜存在最大承载能力;在临界状态,微小的扰动将会引起油膜失稳而丧失承载能力。初步揭示了流体动力学力润滑膜破失效的内在力学机制。     

Pore Network Analysis of Resistivity Index for Water-Wet Porous Media

Pore network analysis is used to investigate the effects of microscopic parameters of the pore structure such as pore geometry, pore-size distribution, pore space topology and fractal roughness porosity on resistivity index curves of strongly water-wet porous media. The pore structure is represented by a three-dimensional network of lamellar capillary tubes with fractal roughness features along their pore-walls. Oil-water drainage (conventional porous plate method) is simulated with a bond percolation-and-fractal roughness model without trapping of wetting fluid. The resistivity index, saturation exponent and capillary pressure are expressed as approximate functions of the pore network parameters by adopting some simplifying assumptions and using effective medium approximation, universal scaling laws of percolation theory and fractal geometry. Some new phenomenological models of resistivity index curves of porous media are derived. Finally, the eventual changes of resistivity index caused by the permanent entrapment of wetting fluid in the pore network are also studied.Resistivity index and saturation exponent are decreasing functions of the degree of correlation between pore volume and pore size as well as the width of the pore size distribution, whereas they are independent on the mean pore size. At low water saturations, the saturation exponent decreases or increases for pore systems of low or high fractal roughness porosity respectively, and obtains finite values only when the wetting fluid is not trapped in the pore network. The dependence of saturation exponent on water saturation weakens for strong correlation between pore volume and pore size, high network connectivity, medium pore-wall roughness porosity and medium width of the pore size distribution. The resistivity index can be described succesfully by generalized 3-parameter power functions of water saturation where the parameter values are related closely with the geometrical, topological and fractal properties of the pore structure.     

Development of Composite Adsorbents of Carbon and Intercalated Clay for N2and O2Adsorption: A Preliminary Study

Composite adsorbents of carbon and alumina intercalated montmorillonite were prepared and characterized by adsorption of N₂and O₂at various temperatures. The effects of pyrolysis, temperature, heating rate, subsequent degassing, and doping of cations and anions were investigated. The adsorption capacities of the composite adsorbents developed at higher temperatures (0 and −79°C) are found to be larger than those of normal alumina pillared clays. The experimental results showed that the framework of these adsorbents is made of alumina particles and clay sheets while the pyrolyzed carbon distributes in the space of interlayers and interpillars. The pores between the carbon particles, clay sheets, and alumina pillars are very narrow with very strong adsorption forces, leading to enhanced adsorption capacities at 0 and −79°C. The composite adsorbents exhibit features similar to those of carbonaceous adsorbents. Their pore structures, adsorption capacities, and selectivities to oxygen can be tailored by a controlled degassing procedure. Meanwhile, ions can be doped into the adsorbents to modify their adsorption properties, as usually observed for oxide adsorbents like zeolite and pillared clays. Such flexibility in pore structure tailoring is a potential advantage of the composite adsorbents developed for their adsorption and separation applications.     

Particle scattering factor of pearl necklace chains

The particle scattering behaviour of a pearl necklace chain is derived. The chain is composed of sphere-like pearls, separated by rod-like segments of fixed length, which have no angular restrictions. By calculating several series of model scattering curves, the important structural features are retrieved. The model is believed to be useful in interpreting intermediate structures of collapsing macromolecules or polyelectrolytes. A first application to a shrinking polyelectrolyte coil generated by molecular dynamic simulations (Limbach and Holm, J.Phys.Chem. 2003) is presented and used to discuss the potentials and limits of the model.     

基于整体易损性的猫头型输电塔抗倒塌能力分析

作为输电线路的主要组成部分,输电塔结构对地震作用非常敏感。本文以中国输电线路中常采用的猫头型输电塔结构为例,开展了输电塔结构整体抗地震倒塌能力分析。以某一实际单回路3个不同高度的直线塔为研究对象,基于OpenSees平台建立输电塔结构三维有限元模型,定义4个倒塌极限状态依据,选取20条远场地震动记录,采用增量动力分析(IDA)方法,得到4个倒塌极限状态依据下输电塔结构的倒塌点,进一步获得输电塔结构的倒塌易损性曲线及其潜在失效杆件,并评估其在不同水平设计地震作用下的倒塌裕度比。研究结果表明,猫头型输电塔的地震损伤主要集中在塔头位置;随着塔体高度的增高,猫头型输电塔抗地震倒塌能力减弱;猫头型输电塔在巨震作用下存在一定的倒塌风险。     

Solvent‐ and counterion‐specific swelling behavior of poly(acrylic acid) gels

The collapse of alkali metal poly(acrylate) (PAAM) gels was investigated for various water/organic solvent mixture systems: methanol (MeOH), ethanol (EtOH), 2‐propanol (2PrOH), t‐butanol (tBuOH), dimethyl sulfoxide (DMSO), acetonitrile (AcN), acetone, tetrahydrofuran (THF), and dioxane. In order to ascertain the counterion specificity in the swelling behavior, four kinds of alkali metal counterions were used: Li⁺, Na⁺, K⁺, and Cs⁺. Remarkable solvent and counterion specificities were observed for every counterion species and every solvent system, respectively. For example, in aqueous EtOH the dielectric constants (D_cr) at which collapse occurred were in the order PAACs < PAALi < PAAK < PAANa. On the other hand, the D_cr at which PAALi gel collapsed increased in the order tBuOH < dioxane < THF < MeOH < 2PrOH < EtOH < acetone < AcN < DMSO, where the D_cr ranged from about 39 to about 67. This was in contrast to our previous observation for a partially quaternized poly(4‐vinyl pyridine) (P4VP) gel, which collapsed in a much narrower D_cr region in similar mixed solvents. The present solvent‐ and counterion‐specific collapses are discussed on the basis of solvent properties such as the dielectric constant and Gutmann's donor number and acceptor number of a pure solvent. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 2791–2800, 2000