Influence of peripheral alkyl chain length on the mesomorphic behaviours of hexasubstituted triphenylene 2,3-dicarboxylic esters

A comparative study of our established synthetic approaches to hexasubsituted triphenylenes 2,3-dicarboxylic esters containing four identical β-alkoxy and two adjacent β-alkoxycarbonyl side chains shows that the phase behaviours of small-sized discotic liquid crystals can be tailored over a wide range by simply varying the length of the peripheral alkyl chains. All the prepared esters in two series were observed to form a single hexagonal columnar phase, except for Tp4-1 having four β-butyloxy and two adjacent β-methoxycarbonyl chains which displays two columnar mesophase behaviours with a transition from the columnar plastic phase to hexagonal columnar phase. A significant difference between the two mesophase was observed in the variable temperature X-ray diffraction studies, and the mesophase assignment was also confirmed by polarising optical microscopy and differential scanning calorimetry. Moreover, the prepared esters in each series display the general trend of decreasing clearing temperature upon increasing alkoxy or alkoxycarbonyl chains length. The intermediate triphenylene 2,3-dicarboxylic acids were also found not only to exhibit columnar hexagonal mesophase over a narrower temperature range by maintaining high melting and clearing points but also to form organogel on mixing with toluene or dichloromethane with the assistance of hydrogen bonding.     

NONLINEAR VIBRATION OF CIRCULAR SANDWICH PLATES UNDER CIRCUMJACENT LOAD

Based on von Karman plate theory, the issue about nonlinear vibration for circular sandwich plates under circumjacent load with the loosely clamped boundary condition was researched. Nonlinear differential eigenvalue equations and boundary conditions of the problem were formulated by variational method and then their exact static solution can be got. The solution was derived by modified iteration method, so the analytic relations between amplitude and nonlinear oscillating frequency for circular sandwich plates were obtained. When circumjacent load makes the lowest natural frequency zero, critical load is obtained.     

弹塑性板壳结构非线性有限元分析

本文根据塑性流动理论的基本公式，由隐式积分导出了与路径无关的变量更新算法和一致切线模量。采用单元广义应力应变直接离散塑性流动定律，构造了杂交应力单元一致切线刚度矩阵的显式表达式，编制了结构有限元程序ＳＡＦＥ，数值算例表明：本文的计算方法和计算程序是正确可靠的，可用于弹塑性板壳结构的非线性分析，计算结果屈曲临界载荷和极限承载能力。     

部分均匀荷载作用下圆板塑性极限统一解

本文采用俞茂宏双剪统一屈服准则求解部分均匀荷载下简支圆板的塑性极限，已有的最大主应力准则、Ｔｒｅｓｃａ准则，Ｍｉｓｅｓ准则的解答均是该解答的特例或线性逼近。该解答可以适合于多种工程材料，具有普遍性和适用性，从得出的解析解和图示中可得出一些新的有益的认识     

THE DYNAMIC BUCKLING OF AN ORTHOTROPIC CYLINDRICAL THIN SHELL UNDER TORSION VARYING AS A POWER FUNCTION OF TIME

The subject of this investigation is to study the buckling of orthotropic cylindricalthin shells under torsion,which is a power function of time.The dynamic stability and compati-bility equations are obtained first.These equations are subsequently reduced to a time dependentdifferential equation with variable coefficient by using Galerkin's method.Finally,the critical dy-namic and static loading,the corresponding wave numbers,the dynamic factors,critical time andcritical impulse are found analytically by applying the Ritz type variational method.Using thoseresults,the effects of the variations of the power of time in the torsion load expression,of theloading parameter,the ratio of the Young's moduli and the ratio of the radius to thickness onthe critical parameters are studied numerically.It is observed that these factors have appreciableeffects on the critical parameters of the problem in the heading.     

A theory of large-strain isotropic thermoplasticity based on metric transformation tensors

Summary A formulation of isotropic thermoplasticity for arbitrary large elastic and plastic strains is presented. The underlying concept is the introduction of a metric transformation tensor which maps a locally defined six-dimensional plastic metric onto the metric of the current configuration. This mixed-variant tensor field provides a basis for the definition of a local isotropic hyperelastic stress response in the thermoplastic solid. Following this fundamental assumption, we derive a consistent internal variable formulation of thermoplasticity in a Lagrangian as well as a Eulerian geometric setting. On the numerical side, we discuss in detail an objective integration algorithm for the mixed-variant plastic flow rule. The special feature here is a new representation of the stress return and the algorithmic elastoplastic moduli in the eigenvalue space of the Eulerian plastic metric for plane problems. Furthermore, an algorithm for the solution of the coupled problem is formulated based on an operator split of the global field equations of thermoplasticity. The paper concludes with two representative numerical simulations of thermoplastic deformation processes.     

复合结构剪切板的屈曲与后屈曲研究

基于Ｒｅｉｓｓｎｅｒ剪切板理论，本文将现有理论模型推进了一步，导出了控制复合材料和构造矩形板平衡的广义Ｋａｒｍａｎ大挠度方程。此外，运用摄动技术，构造了一个单向压缩简支剪切矩形板的后屈曲渐近解，适用于面板和夹心材料都具正交各向异性的夹层板以及计及横向剪切变形对称铺设的层合板。文中给出了典型算例，并将当前结果与其它理论或数值解作了比较，显示出相当好的一致性。     

充满水的金属圆柱壳经受轴向撞击时屈曲过程的实验研究

本文报道了五种规格充满水的圆柱壳经受大质量低速度轴向撞击作用时屈曲过程的实验结果。研究表明由于液体的存在，圆柱壳的屈曲模态呈轴对称型的环带波纹，整个撞击过程可以明显地分为振荡的动力加载、平稳发展的后屈曲和迅速下降的弹性卸载三个阶段。并讨论了试件壁厚和高度等几何参数对其屈曲性能的影响。     

分析薄壳塑性动力响应问题的一种数值方法

探索薄壳塑性动力响应问题的分析与数值方法,是当今力学中的重要课题之一。笔者曾给出联合应用拉普拉斯变换和最小二乘法分析梁、板、壳塑性动力响应的方法。本文分别针对承受中载的短壳和长壳问题,给出只用最小二乘法分析其塑性动力响应的方法。     

铸铁材料在边界润滑条件下形成薄片状磨屑的塑性流动机制

本文在铸铁材料油润滑线接触滑动磨损状态研究的基础上,对边界润滑区典型的薄片状磨屑之形成过程进行了考察。通过对磨损表面的几何形貌、磨屑的形态和内部显微组织变化的分析,提出了薄片状磨屑的塑性流动形成机制。作者认为,薄片状磨屑的形成是磨损表面材料在局部应力和摩擦热的作用下以3种方式发生塑性流动的结果:当摩擦方向垂直于磨削加工条纹时为单侧塑性流动;当摩擦方向平行于磨削加工条纹时为双侧塑性流动;而在峰顶平台(磨削加工粗糙条纹磨合后形成的微平台)较大且载荷较高时,则为平台上的材料沿着摩擦方向向前挤压流动。