全文获取类型
收费全文 | 34399篇 |
免费 | 3091篇 |
国内免费 | 3778篇 |
专业分类
化学 | 27438篇 |
晶体学 | 523篇 |
力学 | 2522篇 |
综合类 | 209篇 |
数学 | 3355篇 |
物理学 | 7221篇 |
出版年
2024年 | 72篇 |
2023年 | 399篇 |
2022年 | 1050篇 |
2021年 | 945篇 |
2020年 | 1205篇 |
2019年 | 1111篇 |
2018年 | 998篇 |
2017年 | 1260篇 |
2016年 | 1398篇 |
2015年 | 1238篇 |
2014年 | 1527篇 |
2013年 | 2415篇 |
2012年 | 1856篇 |
2011年 | 2116篇 |
2010年 | 1765篇 |
2009年 | 2199篇 |
2008年 | 1991篇 |
2007年 | 2017篇 |
2006年 | 1847篇 |
2005年 | 1701篇 |
2004年 | 1734篇 |
2003年 | 1337篇 |
2002年 | 1578篇 |
2001年 | 959篇 |
2000年 | 784篇 |
1999年 | 665篇 |
1998年 | 567篇 |
1997年 | 503篇 |
1996年 | 535篇 |
1995年 | 494篇 |
1994年 | 478篇 |
1993年 | 324篇 |
1992年 | 333篇 |
1991年 | 200篇 |
1990年 | 160篇 |
1989年 | 152篇 |
1988年 | 167篇 |
1987年 | 133篇 |
1986年 | 94篇 |
1985年 | 83篇 |
1984年 | 86篇 |
1983年 | 34篇 |
1982年 | 81篇 |
1981年 | 104篇 |
1980年 | 116篇 |
1979年 | 119篇 |
1978年 | 95篇 |
1977年 | 70篇 |
1976年 | 64篇 |
1973年 | 30篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
31.
Alain Estve Adeline Bail Georges Landa Ahmed Dkhissi Marie Brut Mehdi Djafari Rouhani Jan Sudor Anne-Marie Gu 《Chemical physics》2007,340(1-3):12-16
Possible collapsed forms of poly(N-isopropylacrylamide) molecules are reviewed on the basis of first principle calculations. Various configurations and associated conformations are detailed. The calculated optimized structures exhibit different possibilities of creating networks of intra-molecular bonds of the hydrogen type. We show that the most remarkable one is able to form a local, self-saturated and well ordered helix. We also indicate in which direction the synthesis of the molecule should be oriented to improve its global behavior in term of hydrophobic/hydrophilic behavior. 相似文献
32.
P Rabindra Reddy P R Prasad Reddy M Harilatha Reddy 《Journal of Chemical Sciences》1987,99(5-6):297-303
Studies on interaction of La(III), Pr(III), Nd(III), Sm(III), Gd(III), Dy(III) and Er(III) with inosine and xanthosine in
a 1:1 ratio have been carried out by potentiometric equilibrium measurements at 35±0·1°C and 0·1 M (KNO3) ionic strength. Investigations were also made for the interaction of these metal ions and nucleosides with the biologically
important secondary ligands glycine and histidine. These investigations were undertaken with a view to assess the influence
of charge on the structure and stability of 1:1 metal-inosine/xanthosine systems.
DBT/India overseas Fellow at Harvard University (1986–88). 相似文献
33.
Structural characterisation of such bio-objects as fibrinogen solution, yeast cells, wheat seeds and bone tissues has been done using two versions of cryoporometry based on the integral Gibbs-Thomson (IGT) equation for freezing point depression of pore liquids and the measurements by 1H NMR spectroscopy (180-200 < T < 273 K) and the thermally stimulated depolarisation current (TSDC) method (90 < T < 273 K) of structured water. The IGT equation was solved using a self-consisting regularization procedure including the maximum entropy principle applied to the distribution function of pore size (PSD). Both methods give clear pictures of changes in the structural characteristics caused, e.g., by hydration and swelling of wheat seeds and yeast cells, coagulation and interaction of fibrinogen with solid nanoparticles in the aqueous media, and the human bone tissue disease. 相似文献
34.
We report on a new type of Fano effect, named as Andreev-Fano effect, in a hybrid normal-metal/supeeconductor (N/S) interferometer embedded with a quantum dot. Compared with the conventional Fano effect, AndreevFano effect has some new features related to the characteristics of Andreev reflection. In the Iinear response regime, the line shape is the square of the conventional Fano shape, while in the nonlinear transport, a sharp resonant structure is superposed on an expanded interference pattern, which is qualitatively different from the conventional Fano effect. The phase dependence of the hybrid N/S interferometer is also distinguished from those of all-N or all-S interferometers. 相似文献
35.
Pál Sohár Gábor Bernáth Géza Stájer Angela E. Szabo 《Magnetic resonance in chemistry : MRC》1989,27(9):872-876
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments. 相似文献
36.
Morphological and chemical properties of both the surface and interface of poly(vinylidene fluoride)/poly(methyl methacrylate)-co-poly(ethyl acrylate) (PVDF/PMMA-co-PEA) blend films have been investigated before and after the samples were exposed to ultraviolet (UV) irradiation using a xenon arc lamp at 50 °C and 9% relative humidity (RH) for 7 months. Surface and interfacial morphologies were studied by atomic force microscopy (AFM). Chemical composition information was obtained by confocal Raman microscopy, attenuated total reflection-FTIR spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. Results show an enrichment of the PVDF material at the air surface, while the acrylic copolymer enriches the interface. Blends having greater than 50% mass fraction of PVDF show little change in the surface morphology after UV exposure for 7 months. However, for a lower PVDF content, blends exhibit significant degradation of PMMA-co-PEA copolymer and a much rougher surface after UV exposure. Microstructural changes in the PVDF spherulites are also observed after UV degradation. It is found that the surface and interfacial morphologies are correlated with the chemical properties. 相似文献
37.
38.
1 Introduction Inrecentyears,boththetheoreticalandexperimentalinvestigationsonlasercoolingandtrappinghavebecomeoneofthemajorfieldsinatomic,molecularandoptical physics[1~ 8] .Thedevelopmentoflasercoolingandtrappingtechnologyisimportantfortheapplicationssu… 相似文献
39.
M. I. Pech-Canul F. Ortega-Celaya M. A. Pech-Canul 《Mechanics of Composite Materials》2006,42(3):283-296
The effect of SiO2 in SiCp and the following processing parameters on the microstructure and impact strength of Al/SiCp composites fabricated by pressureless infiltration was investigated: Mg content in the aluminum alloy, SiC particle size,
and holding time. Preforms of SiCp in the form of rectangular bars (10 × 1 × 1 cm) were infiltrated at 1150°C in an argon→nitrogen atmosphere for 45 and 60
min by utilizing two aluminum alloys (Al-6 Mg-11 Si and Al-9 Mg-11 Si, wt.%). The results obtained show that the presence
of SiO2 in SiC affects the microstructure and impact strength of the composites significantly. When Al4C3 is formed, the impact strength decreases. However, a high proportion of SiC to SiO2 limits the formation of the unwanted Al4C3 phase in the composites. Also, a higher content of Mg in the Al alloy lowers the residual porosity and, consequently, increases
the composite strength. The impact strength grows with decrease in SiC particle size and increases considerably when the residual
porosity is less than 1%.
Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 3, pp. 401–418, May–June, 2006. 相似文献
40.
W. Hufenbach R. Böhm A. Langkamp L. Kroll T. Ritschel 《Mechanics of Composite Materials》2006,42(2):151-162
The basic damage and failure models of multiaxially reinforced composites with a thermoplastic matrix are presented and verified.
Within the framework of continuum damage mechanics, a phenomenological model is introduced, where the damage is defined as
a change in the elasticity tensor. For damage identification, a specific ultrasonic device was developed. A combination of
an immersion set-up and a contact coupling device formed a system for an efficient determination of stiffness-tensor components
from convenient sets of velocity measurements. Linked to a tensile machine, it allowed us to measure the anisotropic damage
of the new materials group caused by tensile loading.
Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 2, pp. 221–234, March–April, 2006. 相似文献