A Metal–Organic Supramolecular Box as a Universal Reservoir of UV,WL, and NIR Light for Long‐Persistent Luminescence

Long persistent luminescence (LPL) materials have a unique photophysical mechanism to store light radiation energy for subsequent release. However, in comparison to the common UV source, white‐light (WL) and near‐infrared (NIR) excited LPL is scarce. Herein we report a metal–organic supramolecular box based on a D–π–A‐type ligand. Owing to the integrated one‐photon absorption (OPA) and two‐photon absorption (TPA) attributes of the ligand, the heavy‐atom effect of the metal center, as well as π‐stacking and J‐aggregation states in the supramolecular assembly, LPL can be triggered by all wavebands from the UV to the NIR region. This novel designed supramolecular kit to afford LPL by both OPA and TPA pathways provides potential applications in anti‐counterfeiting, camouflaging, decorating, and displaying, among others.     

全二维气相色谱分析持久性有机污染物的应用进展

持久性有机污染物（POPs）组分复杂,在自然界中超痕量存在,其分离分析十分困难。全二维气相色谱（GC×GC）作为一种新型色谱技术,与传统的一维气相色谱相比,具有峰容量大、分辨率和灵敏度高等优势,越来越广泛地应用于环境有机污染物的分析。该文综述了近十年来全二维气相色谱在持久性有机污染物分析中的应用进展,主要包括全二维气相色谱在解决一些复杂POPs定性定量分析难题方面的应用,如二恶英、毒杀芬和短链氯化石蜡等;概述了全二维气相色谱对多种POPs同时定性定量分析的应用进展;讨论了全二维气相色谱在非目标有机污染物筛查分析中的应用,并对发展趋势及相关应用前景进行了总结展望。     

特殊结构的多臂量子环的持续电流

提出了中臂弯曲的多臂量子环模型,且是上臂最短和下臂最长的不等臂量子环.研究发现：总磁通为零时,持续电流随半导体环增大发生非周期性振荡,并与电极的磁矩方向及隧穿电子的自旋方向相关,下臂因为最长而获得最小的平均持续电流.AB磁通增强时,持续电流会发生周期性振荡,各臂之间明显出现相互制约的现象.各臂持续电流之间的差异与臂长和磁通分布相关,Rashba自旋轨道耦合具有改变持续电流相位和相位差的效应.在一定条件下,两种波函数所对应的持续电流是可分离的. 关键词： 多臂量子环 持续电流 Rashba自旋轨道耦合     

Reversible Photoresponsive Molecular Alignment of Liquid Crystals at Fluid Interfaces with Persistent Stability

This work demonstrates a noninvasive approach to control alignment of liquid crystals persistently and reversibly at fluid interfaces by using a photoresponsive azobenzene‐based surfactant dissolved in an ionic liquid (IL), ethylammonium nitrate (EAN). As the first report on the orientational behavior of LCs at the IL/LC interface, our study also expands current understanding of alignment control of LCs at the aqueous/LC interface by adding electrolytes into aqueous solutions. The threshold concentration for switching the optical responses of LCs can be changed just by simply manipulating the ratio of EAN to H₂O. This work will inspire fundamental studies and novel applications of using the LC‐based imaging technique to investigate various chemical and biological events in ILs.     

Relations and deformations of odd Hamiltonian superalgebras

The following (co)homology groups of the Lie superalgebraH(0,n) are calculated: theH ² (H, H) cohomology with coefficients in the adjoint module and theH ₂ (LH) homology of the nitpotent subalgebra. It is shown that dimH ² (H,H) = 1. Translated fromMatematicheskie Zametki, Vol. 63, No. 3, pp. 391–401, March, 1998. This research was supported by the Russian Foundation for Basic Research under grant No. 95-01-01263 and by the International Science Foundation under grant No. RO 4300.     

调制掺杂GaAs/AlGaAs 2DEG材料持久光电导及子带电子特性研究

在掺Si的GaAs/AlGaAs二维电子气(2DEG)结构中，得到μ_2K=1.78×10^{6cm2/(V·s)的高迁移率.在低温(2K)和高磁场(6T)的条件下，对样品进行红 光辐照，观察到持久光电导(PPC)效应，电子浓度在光照后显著增加.通过整数量子霍尔效应 (IQHE)和Shubnikov-de Haas (SdH)振荡的测量，研究了2DEG的子带电子特性.样品在低温光 照后2DEG中第一子带和第二子带的电子浓度同时随电子总浓度的增加而增加；而且电子迁移 率也明显提高.同时，通过整数霍尔平台的宽度对光照前后电子的量子寿命变短现象作了理 论分析. 关键词： 二维电子气 量子霍尔效应 SdH振荡 持久光电导效应}     

Electron correlation effects in the presence of non-symmetry dictated nodes

We numerically study the effect of non-symmetry dictated nodes (NSDN) on electron correlation effects for spinless electrons. We find that repulsive interaction between electrons can enhance the overlap between nearest neighbors in the tight binding Hamiltonian, in the presence of NSDN. Normally, in the absence of NSDN, attractive interaction between electrons give such an effect and repulsive interaction gives the opposite effect.     

Lagrangian non-intersections

No Abstract. . This research was supported by the Israel Science Foundation (grant No. 205/02 *). Received: December 2004 Revision: March 2005 Accepted: March 2005     

关于例外序列自同态代数的Hochschild同调

LetAbeafinitedimensionalassociatealgebrawithidentityoverafieldkandmodAbethecategoryoffinitedimensionalA_modules.LetAe =A k Aop betheenvelopingalgebraofA ,denotebyAithei_foldtensorproductoverkofAwithitself,andby (a1 ,a2 ,… ,ai)theelementa1 a2 … aiinAi,thentheHochschildcomplex (A + 1 ,b)ofAisdefinedviab :An+ 1 →An withb(a1 ,a2 ,… ,an) =∑ni=1( - 1 ) i-1 (a1 ,… ,aiai+ 1 ,… ,an+ 1 ) + ( - 1 ) n(an+ 1 a1 ,… ,an)andH (A) =H(A + 1 ,b)iscalled ththeHochschildhomologygroupofA .Then…