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71.
Polyethers, which are produced by alcoholysis of oxiranes, are often used as solvents in chemical plants. The spectra of the products can be influenced by the choice of the catalyst (acid or base). The results of the base-catalyzed ethanolysis of 1,2-epoxybutane are displayed. The reaction was investigated calorimetrically by varying the molar ratio between ethanol and 1,2-epoxybutane, the starting temperature and the concentration of the catalyst sodium hydroxide. Additionally, the influence of the used alcohol will be shown in one example. To determine the activation parameters, the experiments were evaluated by the nonlinear software package TA-kin v3.3. 相似文献
72.
Erica L. Plambeck Bor-Ruey Fu Stephen M. Robinson Rajan Suri 《Mathematical Programming》1996,75(2):137-176
In this paper we propose a method for optimizing convex performance functions in stochastic systems. These functions can include
expected performance in static systems and steady-state performance in discrete-event dynamic systems; they may be nonsmooth.
The method is closely related to retrospective simulation optimization; it appears to overcome some limitations of stochastic
approximation, which is often applied to such problems. We explain the method and give computational results for two classes
of problems: tandem production lines with up to 50 machines, and stochastic PERT (Program Evaluation and Review Technique)
problems with up to 70 nodes and 110 arcs.
Sponsored by the National Science Foundation under grant number CCR-9109345, by the Air Force Systems Command, USAF, under
grant numbers F49620-93-1-0068 and F49620-95-1-0222, by the U.S. Army Research Office under grant number DAAL03-92-G-0408,
and by the U.S. Army Space and Strategic Defense Command under contract number DASG60-91-C-0144. The U.S. Government has certain
rights in this material, and is authorized to reproduce and distribute reprints for Governmental purposes notwithstanding
any copyright notation thereon.
Sponsored by a Wisconsin/Hilldale Research Award, by the U.S. Army Space and Strategic Defense Command under contract number
DASG60-91-C-0144, and the Air Force Systems Command, USAF, under grant number F49620-93-1-0068.
Sponsored by the National Science Foundation under grant number DDM-9201813. 相似文献
73.
75.
高效液相色谱法测定精对苯二甲酸中微量杂质 总被引:6,自引:0,他引:6
建立了高效液相色谱法(HPLC)同时测定精对-苯二甲酸(PTA)中微量杂质4-羧基苯甲醛(4-CBA)、对-甲基苯甲酸(P-TOL)和苯甲酸(C7H6O2)含量的方法。采用的色谱柱为Shim-PackWAX-1柱,流动相为0.1mol/L NH3H2PO4 6%CH3OH,(pH4.5),检测波长为254nm。PTA中微量杂质4-CBA、P-TOL和C7H6O2的含量分别为0.59-235.20mg/kg、4.52-392.00mg/kg和0.28-24.55mg/kg时线性关系良好,其线性相关系数分别为0.9998、0.9997和0.9999。苯甲酸加样平均回收率99.03%,RSD0.37%。 相似文献
76.
高效液相色谱法测定细胞分裂素的方法研究 总被引:4,自引:0,他引:4
利用高效液相色谱法测定水稻愈伤组织和微生物发酵产品中的玉米素,二氢玉米素,核糖基玉米素和核糖基二氢玉米素。样品用抽提液抽提,经Bio-Rex70弱阳离子交换柱和XAD-7/Sep-pakC18复合柱净化和富集后,直接用HPLC分析,方法回收率达94%~84%,相对标准偏差小于3.3%。最低检测限达2.0ng。 相似文献
77.
In recent years, the synthesis of chiral tetrahedral clusters has been studied extensively and various types are accessible , which are a kind of organometallic compounds with greatly growing interest due to their potential application to asymmetric reaction catalysts. As an efficient 相似文献
78.
环境样品中痕量邻苯二甲酸酯的分离与测定 总被引:11,自引:0,他引:11
本文研究了以小粒径(10-40μ)硅胶柱色谱分离富集、反相高效相色谱分析测定大气颗粒物、土主植物样品中痕量邻苯二甲酸酯的方法,方法操作简单,回收率高,空白值低,利用该方法分析了部分环境样品中邻苯二甲酯酯含量。 相似文献
79.
Fe-Ni-B-O纳米合金的合成及其催化制氢性能的研究 总被引:2,自引:0,他引:2
Preparation and catalytic performance of Fe-Ni-B-O nano-alloy having crystal-palpus structure has been studied. Black powder was synthesized by reducing mixture solution of Fe2+, Ni2+ with KBH4 as reducing agent and polyethylene glycol as dispersant. Fe-Ni-B-O nano-alloy of crystal-palpus structure was obtained after hydrogen reduction of black powder. TEM shows that crystal-palpus length is 200~400 nm, diameter is 2~4 nm. The analytic results indicate that the total content of Fe and Ni is 86.6%, B is 5.08%. The alloy exhibits excellent catalytic performance. Hydrogen generation rate can approach 100% especially when pH is 8. 相似文献
80.
Chao Wang Jing Wang Xiang Xiao Guobin Zhong Shijia Wu Kaiqi Xu Wei Zhao Wei Su Jie Zeng Baojun Wu Weili Zhang Changcheng Wu Zhiqiang Shi 《中国化学快报》2019,30(6):1269-1272
A novel cyclic ammonium salt, N,N-dimethylpyrrolidinium tetrafluoroborate (P11-BF4), was successfully synthesized for the first time. The smallest cyclic structure of P11-BF4 induced high solubility and conductivity in PC, which can easier enter the micropores of activated carbon and occupy more surface area during charge/discharge process. 相似文献