Risk assessment of inhalation exposure for airborne toxic metals using instrumental neutron activation analysis

In order to study the effects of air pollution, about 1,300 samples of airborne particulate matter (APM) were collected at suburban and industrial sites, in Daejeon, Korea from 1998 to 2006. The concentrations of carcinogenic (As and Cr) and non-carcinogenic metals (Al, Mn, and Zn) were determined by using instrumental neutron activation analysis (INAA). These long-term metal concentration data were applied to a risk assessment of inhalation exposure using Monte Carlo analysis (MCA).     

Analysis of stone column-supported geosynthetic-reinforced embankments

In the present paper, the behavior of stone column-supported geosynthetic-reinforced embankments has been studied. The soil arching effect is incorporated in the study to determine the stresses acting on stone columns as well as soft soil. The effect of stiffness of the stone column is also incorporated in the present study. Based on the stress action in the improved ground, stress concentration ratio, axial strain of geosynthetic reinforcement, tension developed in it and settlement of the improved soft ground are determined by using the developed methodology. Present analytical method is also verified with several current design methods. It is observed from parametric studies that modular ratio or stiffness of the stone columns, spacing to diameter ratio, height of the embankment, depth of the soft soil, stiffness of the geosynthetic reinforcement significantly affect the behavior of geosynthetic-reinforced stone column-supported embankments resting on soft soil.     

大气颗粒物滤膜中极性有机物在线衍生装置的设计与应用

设计制作了一套用于气相色谱-质谱(GC-MS)分析极性有机物的在线衍生装置,并将其应用于大气颗粒物样品中极性有机物的检测.将大气颗粒物滤膜样品置于GC-MS进样口,通过使用套针组件,匀速引入气态衍生试剂N-甲基-Ⅳ-(三甲基硅烷)三氟乙酰胺(MSTFA),使其在衬管内于310℃下与待测物接触,10 min即可完成硅烷化...     

Optimization and validation of a low temperature microwave-assisted extraction method for analysis of polycyclic aromatic hydrocarbons in airborne particulate matter

A low temperature microwave-assisted extraction method (MAE) is reported for the analysis of polycyclic aromatic hydrocarbons (PAHs) in airborne particulate matter (PM). The main parameters affecting the extraction efficiency (choice of extractants, microwave power, and extraction time) were investigated and optimized. The optimized procedure requires a 20 ml mixture of acetone:n-hexane (1:1) for extraction of PAHs in PM at 150 W of microwave energy (20 min extraction time). Clean-up of MAE extracts was not found to be necessary. The optimized method was validated using two different SRM (1648-urban particulate matter and 1649a, urban dust). The results obtained are in good agreement with certified values. PAHs recoveries for both reference materials were between 79 and 122% with relative standard deviation ranging from 3 to 21%. Detection limits were determined based on blank determination using two kinds of quartz filter substrates (n = 10), which ranged from 0.001 (0.03) ng m⁻³ (pg/μg) for B(k)Ft to 1.119 (37.3) for Naph in ng m⁻³ (pg/μg), respectively. The repeatability and day-to-day reproducibility obtained in this study were in the range of 4-16 and 3-25% for spiked standards and SRM 1649, respectively. The optimized and validated MAE technique was applied to the extraction of PAHs from a set of real world PM samples collected in Singapore. The sum of particulate-bound PAHs in outdoor PM ranged from 1.05 to 3.45 ng m⁻³ while that in indoor PM (cooking emissions) ranged from 27.6 to 75.7 ng m⁻³, respectively.     

A Gas Liquid Chromatographic Fluorescent Procedure for the Analysis of Benzo(A)Pyrene in 24 Hour Atmospheric Particulate Samples

Abstract

This paper describes a selective method for the assay of benzo(a)pyrene (BaP) in 24 hour particulate samples. Benzo(a)pyrene is partially separated from the other polynuclear aromatic hydrocarbons via gas chromatography and then is completely resolved optically from traditionally difficult to resolve compounds (benzo(e)pyrene, perylene, benzo(k)fluoranthene) by means of a gas phase fluorescent detector. Ambient air concentrations as low as 20 picograms per cubic meter of air can be assayed with this gas chromatographic - gas phase fluorescent detection system.     

Ceramic Alumina in The HPLC Determination of Benzo(a)Pyrene in Air Particulate Material

Abstract

A fast room-temperature extraction by mechanical shredding of airborne particulate material collected on Hi-Vol filters is described. The polar compounds in the extract are quickly removed by test-tube adsorption. A group separation of polynuclear aromatic hydrocarbons (PAH) is made on Corning controlled pore ceramic alumina in stainless steel columns with methylene chloride in cyclohexane as the solvent. The pentacyclic fraction is taken at the same elution time as BaP and is evaporated to dryness under a stream of nitrogen. BaP is determined fluorometrically in concentrated sulfuric acid at F 538/553. It can also be dissolved in a polar solvent and separated and quantitated by reverse phase HPLC or gas chromatography. Total analysis time is approximately 2 hours, much of which is waiting time.     

Cadmium and Lead Distribution in Marine Soil Sediments,Terrestrial Soil,Terrestrial Rock,and Atmospheric Particulate Matter around Split,Croatia

The distributions of cadmium and lead in marine sediments, surrounding soil, stones, and atmospheric particulate matter were determined at different locations in Split, Croatia. The determination of cadmium and lead was performed by flame atomic absorption spectrometry whereas atmospheric particulate matter samples were analyzed by inductively coupled plasma–optical emission spectrometry. Cadmium concentrations in the stones and soil were between 0.2 to 0.6 µg g^?1 and 0.2 to 0.9 µg g^?1. The concentration in the atmospheric particulate matter were <0.2 µg m^?2 d^?1(detection limit) to 1.4 µg m^?2 d^?1. Lead concentrations in marine sediments, stones, soil, and atmospheric particulate matter ranged from 31.2 to 144.4 µg g^?1, 9.3 to 29.4 µg g^?1, 11.3 to 66.1 µg g^?1, and 0.5 to 241.4 µg m^?2 d^?1, respectively. The relationship between determined parameters was established using principal component analysis and the results are in agreement with the assumption that anthropogenic sources play important roles for lead and cadmium distribution.     

Study on Flow Induced Nano Structures in iPP with Different Molecular Weight and Resulting Strength Behavior

Polypropylene samples in a wide molecular weight range between approx. 100 kg/mol to 1 600 kg/mol were processed by injection molding to thin walled micro specimens with respect to study shear induced crystallization phenomena under high shear rate and subsequently possible self reinforcement effects. The specimens nano structures were investigated and related deformation behavior under tensile studied. Novel morphologies have been detect and their micromechanical mechanism interpret and summarized.     

A mathematical model to study the soil arching effect in stone column-supported embankment resting on soft foundation soil

Soil arching is a common phenomena in pile or columnar (vibroconcrete columns, soil–cement columns by mixing or grouting, stone columns) supported geosynthetic-reinforced or unreinforced embankments resting on soft soil. Due to soil arching, stress acting on soft soil or geosynthetic reinforcement decreases and stress on piles or columns increases. In this paper, using mechanical elements (such as spring, dashpot), a generalized mathematical model has been developed to study the soil arching effect in stone column-supported geosynthetic-reinforced and unreinforced embankments resting on soft soil. Pasternak model concept has been used to model the embankment soil. The soft soil has been idealized by spring-dashpot system to include the time-dependent behavior. The stone columns and geosynthetic reinforcement are idealized by stiffer nonlinear springs and rough elastic membrane, respectively. The consolidation effect of soft soil due to inclusions of stone columns has also been included in the model to study its effect on soil arching. Plane strain condition has been considered in the analysis. A finite difference scheme has been used to solve the governing differential equations and results are presented in non-dimensional form. It has been observed that the height of embankment, degree of consolidation of soft soil, stiffness of the stone column material, spacing between the stone columns, use of geosynthetic reinforcement and properties of soft and embankment soils (such as ultimate bearing capacity of soft soil, shear modulus and ultimate shearing resistance of embankment soil) significantly influence the degree of soil arching.     

Molecular composites made of ionic poly(p‐phenylene terephthalamide) and poly(4‐vinylpyridine): Deformation modes

Deformation modes were examined on strained thin films of a series of molecular composites containing ionically modified rodlike molecules of poly(p‐phenylene terephthalamide) (PPTA) dispersed in a polar polymer matrix. The rigid molecules were a modified form of PPTA in which the H atom of the amide group was replaced, on 30 mol % of the monomer units, by an ionic propane sulfonate group. The polar polymer matrix of these composites was the flexible‐coil polymer, poly(4‐vinylpyridine). Ionic interactions between the two components increased the effective entanglement strand density and produced changes in the deformation modes. The observed changes were dependent on the relative concentration of the two components and on the nature of the counterion. With K⁺ as the counterion, the induced deformation mode changed from pure crazing, as in the matrix polymer, to combined crazing and shear deformation at 5 wt % of the ionic polymer and to essentially pure shear deformation as the concentration increased to 15 wt %. However, when Ca²⁺ was the counterion, pure shear deformation developed at a concentration of only 5 wt %. This effect was attributed to a greater ionic interaction and to a higher effective strand density of the composites, when monovalent K⁺ was replaced by divalent Ca²⁺. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 429–436, 2003