取代基效应对三苯甲酸纤维素酯类吸附剂的吸附性能的影响

采用催化合成法制备三苯甲酸纤维素酯（CTB）、三（4-甲基苯甲酸）纤维素酯（CTMB）和三（4-氯苯甲酸）纤维素酯（CTCB），将其分别负载于Gas Chrom Q载体上，用不同类型的探针分子及气相色谱法表征其吸附性能，研究取代基团的电子效应和空间效应对其吸附性能的影响。实验结果表明：在三苯甲酸纤维素酯类吸附剂和苯衍生物吸附质的苯环上的取代基效应（电子效应和立体效应）对吸附质在吸附剂上的吸附热（-Δha）的影响显著，但两者的影响各不相同。     

一种新型吡唑啉衍生物荧光受体的合成及其离子识别性能

以苯环为荧光基团合成了一种新的吡唑啉衍生物荧光受体;采用核磁共振光谱对目标化合物进行了结构表征,并利用荧光光谱法研究了其对常见阳离子的选择性识别.结果表明,合成的吡唑啉衍生物对Na+、H+、Fe3+、Cu2+具有良好的识别络合效果.     

古田山茶湾样地甜槠-木荷林根萌特征分析

根萌是植物营养繁殖的重要策略之一,森林植物的根萌现象影响着植物群落的更新动态和演替方向.在对古田山茶湾1hm2固定样地胸径≥1cm的木本植物调查的基础上,分析了该样地木本植物的根萌现状及根萌与母树的相关性,结果表明:样地内根萌植物共有68种,隶属于48属26科,占群落总物种的67.3%.其中根萌萌生能力较强的物种有林冠层中的石栎(Lithocarpus glaber)、甜槠(Castanopsis eyrei)、木荷(Schima superba),亚乔木层中的灰白蜡瓣花(Corylopsis glandulifera)、隔药柃(Eurya muricata)、浙江红花油茶(Camellia checkiangoleosa),灌木层中的窄基红褐柃(Eurya rubiginosa)、宜昌荚蒾(Vibernum erosum)、映山红(Rhododendron simsii);对优势根萌物种和母树的相关性分析表明:考虑根萌因素后,各物种重要值发生小幅度增减,但各垂直层次的优势种排名次序基本不变;乔冠层物种在母树Ⅰ~Ⅲ级生长阶段、亚乔木层和灌木层物种在母树Ⅰ~Ⅱ级生长阶段均表现出根萌能力逐渐增强的趋势,在其他生长阶段,不同物种表现出不同的变化趋势;优势根萌物种在样地中的分布与样地内相关母树的分布情况基本吻合,多数根萌物种的分布表现出聚集现象.     

改进的特征线方法及过载对水锤效应影响分析

传统特征线方法对过载作用下的水锤计算具有局限性,无法为水锤防护提供可靠性指导。本文在考虑过载效应和动态摩阻的基础上,提出了改进的特征线方法,该方法能准确模拟过载作用下水锤最大压力峰值及水锤波的衰减特性。基于该方法,建立了过载作用下水锤效应数学模型,通过分析结果与CFD数值仿真及实验数据对比,验证了改进特征线方法的正确性。分析结果表明,在恒定过载作用时,阀门位置的流体压力随过载量的增加而增大,且管轴向过载的影响大于横向过载;关阀过程受到瞬时过载作用时,过载效应对水锤最大压力峰值影响显著,而对关阀后水锤波的传播和衰减影响较小;同时,分析了过载效应下关阀特性和流体密度等参数对水锤效应的影响规律。     

Evaluating the lifetime performance index for the exponential lifetime products

Process capability indices (PCIs) are used to measure process potential and performance. Since the lifetime of products generally may possess an exponential, gamma or Weibull distribution, etc., so under a two-parameter exponential distribution, this study constructs a uniformly minimum variance unbiased estimator (UMVUE) of the lifetime performance index based on the right type II censored sample. Then the UMVUE of the lifetime performance index is utilized to develop the new hypothesis testing procedure in the condition of known L. Finally, a practical example is illustrated to employ the testing procedure to determine whether the process is capable.     

LiMn2O4 nanorods as a super-fast cathode material for aqueous rechargeable lithium batteries

LiMn₂O₄ nanorods were prepared by a facile hydrothermal method in combination with traditional solid-state reactions and characterized by X-ray diffraction analysis. Their electrochemical behavior was tested by cyclic voltammetry and repeated charge/discharge cycling. Results show that the reversible intercalation/deintercalation of Li-ions into/from LiMn₂O₄ cathode can yield up to 110 mAh/g at 4.5 C, and still retains 88% at the very large charge rate of 90 C with well-defined charge and discharge plateaus. It presents very high power density, up to 14.5 kW/kg, and very excellent cycling behavior, 94% capacity retention after 1200 cycles. It is thus a competitor for LiFePO₄.     

Integrated design of piezoelectric damping system for flexible structure

This paper aims at developing an integrated design method of the active/passive hybrid type of piezoelectric damping system for reducing the dynamic response of the flexible structures due to external dynamic loads. The design method is based on the numerical optimization technique whose objective function is a control effort of the active damping. A vibration suppression performance, which is evaluated by the maximum value of the gain of the frequency response function of the structure, is constrained. In order to demonstrate the structural damping capability of the hybrid type of piezoelectric damping system designed by proposed method, numerical simulation and laboratory experiment will be done using a three-story flexible structure model equipped with 12 surface bonded PZT tiles pairs. Both numerical and experimental results indicate that the optimally designed hybrid piezoelectric damping system can be successfully achieving excellent performance as compared to a conventional purely active piezoelectric damping system.     

光学分辨本领实验设计

介绍了一种做分辨本领实验的方法，可在白天条件下进行。实验中的衍射属单色的夫琅禾费衍射，误差小效果理想，可作为演示实验，也可作为学生实验。     

Cascading failures of overload behaviors using a new coupled network model between edges

With the development of network science,the coupling between networks has become the focus of complex network research.However,previous studies mainly focused on the coupling between nodes,while ignored the coupling between edges.We propose a novel cascading failure model of two-layer networks.The model considers the different loads and capacities of edges,as well as the elastic and coupling relationship between edges.In addition,a more flexible load-capacity strategy is adopted to verify the model.The simulation results show that the model is feasible.Different networks have different behaviors for the same parameters.By changing the load parameters,capacity parameters,overload parameters,and distribution parameters reasonably,the robustness of the model can be significantly improved.     

γ模拟器与EMP模拟器同步运行可行性研究

 γ-EMP组合模拟器的关键问题是实现γ模拟器与EMP模拟器的准确同步运行。分析了组合模拟器对γ模拟器同步性能的要求,指出γ模拟器动作时间的抖动ΔTγ至少应达到γ脉冲半幅值宽度的1/2的水平。分析研究了选择闪光Ⅰ作为γ模拟器时存在的困难和改进同步性能的途径。讨论了选择闪光ⅠA 作为γ模拟器时的同步性能和可行性。