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911.
An integrated solid-phase spectrophotometry/flow injection analysis (FIA) method is proposed for the determination of the
synthetic colorant matter Ponceau 4R (P4R) in the presence of its unsulfonated derivative 2-hydroxy-1-[(naphthalenyl)azo]
naphthalene (N2N). The procedure is based on the measurement of P4R at λ = 508, followed by retention and preconcentration
of the low level concentration of N2N on a C18 silica gel minicolumn and subsequent measurement of the absorbance of N2N at λ = 508 nm after its elution. The applicable
concentration range, the detection and the relative standard were the following: for P4R, from 0.30 to 20.0 mg/L; 0.052 mg/L
1.1%; and for N2N, between 0.020 to 3.0 mg/L 0.003 mg/L and 1.1%. The method was applied to the determination of small amounts
of N2N present in P4R in food and cosmetic products. Percentages of recovery between 95 and 105% were obtained in all instances.
The method was applied satisfactorily to the determination of the compounds P4R and N2N in samples of sweets and cosmetic
products when compared to results offered by a HPLC reference method.
Received April 5, 2001. Revision July 25, 2001. 相似文献
912.
This paper describes the use of Ag/Ag2S and Ag/AgI ion-selective electrodes by means of chemical pretreatment of a silver wire or tube for the determination of
cysteine (RSH) in batch and flow injection analysis (FIA).
Received December 15, 2000. Revision July 11, 2001. 相似文献
913.
Takumi Yokota 《Geometriae Dedicata》2008,133(1):169-179
In this paper, we consider the behavior of the total absolute and the total curvature under the Ricci flow on complete surfaces
with bounded curvature. It is shown that they are monotone non-increasing and constant in time, respectively, if they exist
and are finite at the initial time. As a related result, we prove that the asymptotic volume ratio is constant under the Ricci
flow with non-negative Ricci curvature, at the end of the paper.
相似文献
914.
Test‐separator units, as traditional methods of well surveillance, mainly suffer from their inherent constraints including the expensive instrumental, mechanical, electrical, piping and safety devices along with technical and protective inspections, repair and operation services, facilities and infrastructures. Other problems are time and cost consuming, uncertainty of well isolation in test separator and need to close the co‐line wells, which are diminished using multivariate thermal well testing. A novel approach was proposed and tested to classify the oil samples taken from individual wells by source and type. The novelties of this work were the use of the applied aspects of 1H NMR spectroscopy in petroleum upstream engineering, the replacement of traditional test methods, the improvement of the confidence of tests and the recognition of multisource streams. The weighed sum method was used to correlate the spectra information, taken from the samples of Iranian offshore oil wells. The experimental results and the field data revealed that the present approach was appropriate for precocious, quick and reliable surveillance of individual oil wells located in an oil field. The model was supported by field experiments and has predicted the accurate productivity of oil wells with respect to the current expensive techniques since 2010. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
915.
AA Yan LI Kai CAO ZhongHua & HU WenRui Key Laboratory of Microgravity 《中国科学:物理学 力学 天文学(英文版)》2011,(2)
The dependency of the critical Marangoni number on the geometrical aspect ratio of the floating half zone is essential to predict the onset of oscillatory thermocapillary convection.The experimental studies in the microgravity conditions on floating half zones of several centimeters in diameter have predicted that the critical Marangoni number increases with the increasing aspect ratio,and the terrestrial experimental studies have predicted the contradictory conclusion for floating half zones of several mil... 相似文献
916.
Most methods of measuring the interfacial tension between two immiscible polymers are based on the analysis of the shape
that a drop of one polymer immersed in the other one exhibits under the action of flow or gravity. In such a situation, the
small, yet nonzero mutual solubility between the two polymers acts toward mass transfer between the drop and the surrounding
fluid. In this work, diffusion effects on the interfacial tension of the pair polyisobutylene/polydimethylsiloxane have been
investigated by drop deformation under shear flow. When the drop was made of polyisobutylene, drop size decreased with time
due to diffusion. Drop shrinkage was associated with a significant increase in interfacial tension, until an apparent plateau
value was reached. The effect was attributed to a selective migration of molecular weights, which would act to enrich the
drop with higher molar mass material. To support such an interpretation, drop viscosity was evaluated by drop shape analysis
and it was actually found to increase with time. In some cases, the ratio between drop and continuous phase viscosity became
higher than the critical value for drop breakup in shear flow. Upon inverting the phases (i.e., when the drop was made of
polydimethylsiloxane), no significant transient effects were observed. In the light of these results, the problem of what
are the correct values of interfacial tension and viscosity ratio for a polymer blend of a certain composition will also be
discussed.
Received: 25 January 1999 Accepted: 24 May 1999 相似文献
917.
The transfer of energy in drag reducing viscoelastic flows is analyzed through a sequence of energetic budgets that include the mean and turbulent kinetic energy, and the mean polymeric energy and mean elastic potential energy. Within the context of single-point statistics, this provides a complete picture of the energy exchange between the mean, turbulent and polymeric fields. The analysis utilizes direct simulation data of a fully developed channel flow at a moderately high friction Reynolds number of 1000 and at medium (30%) and high (58%) drag reduction levels using a FENE-P polymeric model.Results show that the primary effect of the interaction between the turbulent and polymeric fields is to transfer energy from the turbulence to the polymer, and that the magnitude of this transfer does not change between the low and high drag reduction flows. This one-way transfer, with an amplitude independent of the drag reduction regime, comes in contradiction with the purely elastic coupling which is implicit within the elastic theory of the polymer drag reduction phenomenon by Tabor and De Gennes (Europhys. Lett. 2, pp. 519–522, 1986). 相似文献
918.
A new mathematical algorithm is proposed to address the essential details of vertical distributions of horizontal velocity for one‐dimensional steady open‐channel flow. This new algorithm comprises a system of weighted averaged equations developed from corresponding Reynolds equations by performing weighted average operations instead of conventional depth average operations. It is the system of weighted averaged equations, instead of the vertical grids, that allows for more hydraulic coefficients identifiable. It can be thought of as an extension of the St. Venant equations to address the vertical distributions of horizontal velocities, as well as the water surface profiles. To avoid the difficult expansion of governing partial differential equations in high order, an indirect scheme is proposed to solve hydraulic variables through their weighted average values. The governing partial differential equations are generated by using a variety of weight functions, and the weighted averages of relevant hydraulic variables are taken as the unknown independent variables to be solved first. Then, on the basis of the values and polynomial expansions of these weighted averaged velocities, a system of linear algebraic equations is generated and the unknown hydraulic variables or their coefficients are easily solved. Note that the new model is not proposed to compete with any three‐dimensional models in modeling accuracy or accommodation ability to all conditions. It just provides a valuable option to study the vertical structure of flow in open channels where only essential detail and reasonable accuracy of vertical distributions are required, and the data availability and other conditions limit the application of fully three‐dimensional models. The performance of the model is evaluated with experimental data of flows in two different flumes. It is shown that the model well predicted the velocity profiles of sections along the centerlines of these flumes with reasonable accuracy and essential details of vertical distributions of horizontal velocity. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
919.
Kang Zhou Qicheng Sun Lanlei Guo Qingjun Du Yueliang Liu 《Journal of Dispersion Science and Technology》2013,34(10):1523-1530
After being injected into the porous media, the dispersion system of preformed particle gel (PPG) tends to enter high permeability regions and block water channeling passages, which forces the subsequent water to turn to the low permeability regions and thus increases sweep efficiency and enhances oil recovery. However, it is still unclear about the influence factors and the mechanisms how PPG increases water flow resistance, which limits the application of PPG in more oilfields. Therefore, the paper combines the lattice Boltzmann method (LBM), the discrete element method (DEM) and the improved immersed moving boundary (IMB) method to simulate the migration of deformable PPG in porous media. On the basis, the paper quantitatively analyzes the variation law of displacement pressure across the porous media and discusses the influence factors such as the PPG diameter, elasticity modulus and the number concentration. Results indicate that, because of the friction and retention of PPG in pore-throat, the displacement pressure across the porous media during PPG flooding is much higher than that during water flooding. In other words, the existence of PPG increases the flow resistance of injected water. Besides, the displacement pressure is always fluctuant resulting from the continuous process of PPG migration, retention, deformation and remigration. Influence factor analysis shows that the incremental value and fluctuation degree of flow resistance increase with the PPG diameter, elasticity modulus and the number concentration. The study not only provides useful reference for future PPG flooding, but also benefits the development of deformable particle flow theory. 相似文献
920.
This paper develops a posteriori error estimates of residual type for conforming and mixed finite element approximations of the fourth order Cahn-Hilliard equation ut + △(ε△Au-ε^-1f(u)) = 0. It is shown that the a posteriori error bounds depends on ε^-1 only in some low polynomial order, instead of exponential order. Using these a posteriori error estimates, we construct at2 adaptive algorithm for computing the solution of the Cahn- Hilliard equation and its sharp interface limit, the Hele-Shaw flow. Numerical experiments are presented to show the robustness and effectiveness of the new error estimators and the proposed adaptive algorithm. 相似文献