全文获取类型
收费全文 | 2049篇 |
免费 | 51篇 |
国内免费 | 7篇 |
专业分类
化学 | 1129篇 |
晶体学 | 18篇 |
力学 | 299篇 |
综合类 | 1篇 |
数学 | 94篇 |
物理学 | 566篇 |
出版年
2022年 | 11篇 |
2021年 | 11篇 |
2020年 | 16篇 |
2019年 | 8篇 |
2018年 | 9篇 |
2017年 | 21篇 |
2016年 | 53篇 |
2015年 | 53篇 |
2014年 | 47篇 |
2013年 | 116篇 |
2012年 | 61篇 |
2011年 | 68篇 |
2010年 | 51篇 |
2009年 | 86篇 |
2008年 | 87篇 |
2007年 | 75篇 |
2006年 | 76篇 |
2005年 | 33篇 |
2004年 | 45篇 |
2003年 | 50篇 |
2002年 | 342篇 |
2001年 | 80篇 |
2000年 | 69篇 |
1999年 | 80篇 |
1998年 | 84篇 |
1997年 | 53篇 |
1996年 | 46篇 |
1995年 | 37篇 |
1994年 | 27篇 |
1993年 | 28篇 |
1992年 | 21篇 |
1991年 | 18篇 |
1990年 | 14篇 |
1989年 | 17篇 |
1988年 | 10篇 |
1987年 | 11篇 |
1986年 | 12篇 |
1985年 | 10篇 |
1984年 | 15篇 |
1983年 | 8篇 |
1982年 | 9篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1979年 | 8篇 |
1978年 | 19篇 |
1977年 | 30篇 |
1976年 | 21篇 |
1975年 | 10篇 |
1974年 | 8篇 |
1973年 | 18篇 |
排序方式: 共有2107条查询结果,搜索用时 15 毫秒
11.
Relationships have been established between the average conversion degree and the dissociation time for polydisperse granular
material, taking its grain size distribution into account. It has been checked in which cases the kinetic curves obtained
by a numerical solution can be described in terms of KEKAM equation.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
12.
Relationships between average degree of transformation and time of dissociation were derived for polydisperse granular materials
with account to the type of grain size distribution. It has been checked, under what conditions the kinetic curves obtained
by numeric solution of those relationships may be described in terms of equations D1 α2=kt
, F2 [1/(1 - α) - 1 =kt] and F3 [1/(1 - α)2 - 1=kt].
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
13.
Molecular Dynamics Simulations of Energetic Solids 总被引:1,自引:0,他引:1
A continuing objective in the area of energetic materials is to reduce sensitivity toward impact and shock. One approach is to develop a better understanding of how factors related to the crystal lattice, e.g., defects, influence the initiation and propagation of detonation. Molecular dynamics is a useful tool for this purpose. This paper presents an overview of molecular dynamics treatments of energetic solids. Some of these have simulated initiation and propagation in idealized systems; others have focused on developing a satisfactory procedure for describing molecular crystals of practical significance. Our emphasis in this discussion is on the progress that has been made along the second lines. 相似文献
14.
I NQR and spectroscopic investigation of impurity-doped and mixed lithium iodate Li1−xHxIO3 crystals
A. Barabash T. Gavrilko K. Eshimov J. Baran H. Ratajczak 《Journal of Molecular Structure》2004,708(1-3):113-116
The 127I NQR, IR absorption and Raman spectra of impurity-doped and mixed lithium iodate Li1−xHxIO3 crystals grown from water solutions with different LiIO3/HIO3 ratios were investigated depending on the content of the impurity hydrogen x. The NQR results suggested that, at small concentration of doping iodic acid x<0.22, the lattice dynamics of the crystal grown from water solution changes significantly though the crystal retains hexagonal symmetry. Spectroscopic studies are compatible with average hexagonal symmetry of the grown doped crystals. From the results of Raman studies at room temperature and 100 K, the concentration range of hydrogen dopant 0.22<x<0.36 was found where disordered solid solution crystals Li1−xHxIO3 are formed. 相似文献
15.
The boxes contained kiwifruits were irradiated with cobalt-60 γ-rays at different dosages (0.6 , 1.8 and 3.6 KGy) and stored in a room ventilated at night, the natural ambient air being used as cool source.The results showed that the treatment which fruits irradiated with 0.6 KGy was the best after 85 days. It gave the normal-fruit rate of 95.10%, fruit flesh hardness of 4.10 Kg · cm-2, fresh and plump fruits, good quality and less Vc loss. 相似文献
16.
本文扼要地介绍了固体激光质谱学问世20多年来的发展和现状。其中包括有:固体激光质谱的简介和特色;发展过程中有重要贡献科学工作者的主要成就;它的有关基本理论;从仪器和分析实践两个方面介绍其发展概况。文中还就上述几个方面列出带综论性文献,以便读者作进一步了解。最后作者还展望了今后固体激光质谱学的发展前景。 相似文献
17.
Maria?Victoria Roux Paul?J.?Smith Joel?F.?LiebmanEmail author 《Structural chemistry》2005,16(1):73-75
Despite their seeming simplicity, substituted guanidines have not particularly caught the attention of the thermochemical community. The current paper compares the enthalpy of formation of solid substituted guanidines with correspondingly substituted benzenes, also as solids. 相似文献
18.
Agustín Urretabizkaia Gurutze Arzamendi María J. Unzu Jos M. Asua 《Journal of polymer science. Part A, Polymer chemistry》1994,32(9):1779-1788
A method for the calculation of the optimal monomer addition policies for polymer composition control in emulsion terpolymerization is developed. The method is applied to reactors with and without limited heat removal capacity. A mathematical model that incorporates the main features of the vinyl acetate/methyl methacrylate/butyl acrylate high solids content emulsion terpolymerization system allows the calculation of the composition of the initial charge of the reactor and the time-dependent monomer addition rates required. © 1994 John Wiley & Sons, Inc. 相似文献
19.
Anna Kowalska Zygmunt Kowalski Andrzej Kotarba Andrzej Barański 《Mikrochimica acta》1990,100(5-6):349-353
The analytical procedure of determination of Fe(II) in the presence of Fe(III) in milligram samples is proposed. A solid sample is dissolved in hydrochloric acid in argon atmosphere. Subsequently, the pH-value of the solution is fixed and Fe(III) complexed by phosphoric buffer. At the next step Fe(II) is oxidized by -molybdosilicic acid. Finally, the intensity of colouring caused by the reduced form of the acid is measured at the wavelength 770 nm. The proper treatment of the sample during oxidation, and immediately before, is decisive for the accuracy of the analysis. The method was verified by means of the analysis of synthetic magnetite. The theoretical content of Fe(II) was 24.12%, the determined one was 24.02 ± 0.10%. The method was applied to the determination of the homogeneity of an iron catalyst for ammonia synthesis. 相似文献
20.
In the present study was combined the use of high resolution TGA with the isoconversion method, giving us a suitable methodology for determining the stages that occur during a reaction, and providing further insights about the kinetics of the processes involved. As a model reaction was used the thermal dehydration of KNbWO6·H2O. The results shown that the dehydration process is controlled by internal water diffusion (intra-crystallite); with activation energy values between 43 and 36 kJ/mol. This value is consistent with a diffusion mechanism dominated by van der Waals attractions. The estimated kinetic parameters are supported with a structural analysis, that suggest lower dimensionality character for water diffusion due to the specific orientations of 〈1 1 0〉 open channels in the pyrochlore framework. This would explain why the two-dimensional (D2) mechanism appears to be the most probable. 相似文献