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141.
Stern HA 《Journal of computational chemistry》2004,25(5):749-761
We review principles of non-Hamiltonian statistical mechanics and present a new set of equations and integration algorithm for isothermal-isobaric dynamics. The chief advantage of the present scheme is that it is somewhat simpler than previous methods. We perform numerical simulations to test the accuracy of the algorithm and compare its stability to that of a "gold standard," a symplectic integrator for Hamiltonian dynamics of the same system. The stability of the isothermal-isobaric algorithm is comparable to the stability of the symplectic integrator. 相似文献
142.
建立了气相色谱过程的动态数学模型,给出了模型的实用算法,并据此对各种操作条件下的色谱流出曲线进行了动态模拟计算。模拟计算结果表明该模型是有效的,能够用于各种程序控制的色谱过程,可得到色谱分离的优化条件。 相似文献
143.
144.
D. J. Burlett 《Journal of Thermal Analysis and Calorimetry》2004,75(2):531-544
The transfer of heat through an elastomeric matrix is important for both the processing of the material and its subsequent
lifetime. Thermal conductivity can be used to evaluate the influence of different polymers and fillers on heat transfer. Additionally,
the dispersion of the filler has an effect on heat transfer and thermal conductivity measurements can be used to provide semi-quantitative
estimations of filler dispersion. The degradation of sulfur-crosslinked elastomer systems has been studied for many years.
The degradation of the crosslinks (changes in sulfur rank) and degradation of the polymer backbone by thermal and/or oxidative
processes have been studied extensively using many techniques including thermal analysis (references). However, the degradation
of the crosslinked-polymer 'network' is less well understood. The relationship of the crosslink network to this degradation
process is a key to both the long term and higher temperature performance of the sulfur-crosslinked elastomer. The changes
in physical properties observed upon exposure of sulfur-crosslinked elastomers can be monitored using dynamic mechanical analysis.
Subsequently, other thermal techniques can be used to monitor the chemistry that is occurring during these degradations. Thermal
desorption/mass spectroscopy and dynamic scanning calorimetry are used to complete the picture of the degradation processes
taking place. Examples of these techniques will be provided to illustrate the utility of the analytical approach, the chemistry
involved in these degradation processes and the effect of changes in the polymer, cure package and other ingredients.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
145.
S. Fakirov Z. Sarac T. Anbar B. Boz I. Bahar M. Evstatiev A. A. Apostolov J. E. Mark A. Kloczkowski 《Colloid and polymer science》1997,275(4):307-314
This second part of a systematic study of the properties of crosslinked-oriented gelatin involves the effects of orientation
and water content on the glass transition temperature T
g and on the melting behavior. The samples were the same as those in the preceding study, and their transition temperatures
were determined by both differential scanning calorimetry and dynamic mechanical thermal analysis. The crosslinked gelatin
which had been room-conditioned showed two transition temperatures: the lower one was attributed to T
g of the water-plasticized gelatin, and the higher one was interpreted as T
g of dried gelatin superimposed by melting. A rather unusual situation arose because of the fact that the T
g and melting temperatures T
m (217 and 230 °C, respectively) are so similar. Using water as plasticizer not only decreases T
g but produces imperfect crystallites which melt below the T
g of the system. The presence of the amorphous phase in the glassy state would presumably make it essentially impossible to
define a melting point or crystallization temperature in the normal manner, as an equilibrium between crystalline and amorphous
phases.
Received: 8 October 1996 Accepted: 2 November 1995 相似文献
146.
HeinzD. Roth 《Helvetica chimica acta》2006,89(12):2847-2860
Chemically induced dynamic nuclear polarization (CIDNP) observed during electron transfer (ET) reactions of tertiary amines such as DABCO ( 1 ) or Et3N ( 2 ) with a wide range of electron acceptors support the involvement of amine radical‐cations (e.g., 1. + or 2. + ) as key intermediates. Radical ions such as 2. + may be deprotonated, generating neutral aminoalkyl radicals (e.g., 2. ). When generated by reaction with an electron acceptor of energetically low triplet state such as naphthalene (1Naph*), the resulting pair 2. + /Naph.? reacts mostly by reverse electron transfer (RET) from triplet pairs populating the naphthalene triplet state. 相似文献
147.
HIPS/PP熔融反应共混及其动态力学性质 总被引:2,自引:0,他引:2
研究了高抗冲聚苯乙烯(HIPS)/聚丙烯(PP)共混物在过氧化二异丙苯(DCP)存在下的熔融反应过程及其动态力学性质.HIPS在DCP存在下以聚苯乙烯(PS)的降解为主,伴随着聚丁二烯(PB)的交联和接枝,PP在DCP存在下以降解为主,HIPS/PP在DCP存在下以PP同HIPS的反应接枝为主,这种原位生成的增容剂显著地改善了HIPS/PP两组份间的相容性,其分子运动特征较前两者发生明显变化,PS的Tg下降,PB和PP的Tg升高. 相似文献
148.
A coupling sensitive solid phase spectrophotometric (SPS) procedure for determination of traces of heavy metals (Me-SPS) and multicomponent analysis by multiple linear regressions (MA), a simple methodology for simultaneous determination of metals in mixtures was inaugurated. The Me-SPS procedure is based on sorption of heavy metals on PAN-resin and direct absorbance measurements of colour product Me-PAN sorbed on a solid carrier in a 1-mm cell. This methodology (Me-SPS-MA) was checked by simultaneous determination of metals in synthetic mixtures with different compositions and contents of metals important in pharmaceutical practice: Zn, Pb, Cd, Cu, Co, and Ni. Good agreement between experimental and theoretical amounts of heavy metals is obtained from the recovery test (78.3–110.0%). The proposed method enables determination of particular metal ion at the ng mL−1 level and it was successfully applied to the determination impurities from heavy metal traces in pharmaceutical substances (Cu in ascorbic acid, Pb in glucose, and Zn in insulin). The proposed procedure could be possible contribution to the development of pharmacopoeial methodology for a heavy metals test. 相似文献
149.
微量元素锌在治疗Bell麻痹中的作用 总被引:1,自引:0,他引:1
陈贤雄 《广东微量元素科学》2002,9(3):31-35
为探讨急性早期应用补锌和综合疗法治疗Bell麻痹 ,将 1 5 8例Bell麻痹患者 ,随机分成两组 :(1 )补锌组 (补锌 +综合疗法 ) ;(2 )对照组 (单纯综合疗法 )。对其进行了观察对比治疗 ,同时检测了所有患者治疗前后自身对照发锌值 ,还对所有患者进行了定位诊断、面神经电反应测试、并对面肌功能进行评分。结果表明 ,对定位诊断其病变在D段、面肌功能评分在 1 1分以下、面神经无电反应患者 ,即使给予早期综合治疗 ,效果仍较差 ,而早期给予补锌加综合治疗效果优于对照组 ,其它段内患者治疗次数和治愈天数也均优于对照组。可见微量元素锌在发挥免疫应答、免疫调控中的重要作用 相似文献
150.
Normalized Dynamic Characterization and Application of Multiple Heat Storage Materials Based on Standard Thermal Resistance北大核心CSCD
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基于标准热阻和能量流法,推导出储热材料与换热流体的瞬态换热热阻,通过类比电路分析法,获得了储热-换热过程的瞬态热量流模型及动态响应时间常数。进一步引入节点温度,重新定义换热热阻,获得了储热与换热过程耦合的三阶电路瞬态热量流模型,求解得到了加热、储热和释热三类时间常数,可用于协同表征储热材料中储热与释热的快慢程度,从而实现了多类储热材料的归一化动态表征。通过数值模拟验证与应用对比分析,发现基于多时间常数的归一化动态模型用于表征储热材料的动态特性是可行的,可直接对不同换热、储热材料进行对比分析。案例分析发现与固体储热材料换热时,液态金属的动态换热能力优于熔融盐,而相比于水蒸气和CO2,空气与陶瓷材料换热能更快达到稳态。 相似文献