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Eurydice Arroyo Diana Tentori Alfonso Garcia Ricardo Valdez Miguel A. Armenta Osvaldo J. Nava Roberto Machorro Amelia Olivas 《Particle & Particle Systems Characterization》2023,40(6):2200200
Carbon quantum dots (CQD) have received significant attention in recent years due to their potential applications in optics and sensing. In this study, the authors report on the first characterization of the optical activity and broad absorption spectrum covering from short-wave ultraviolet, at 200 nm, to mid-infrared, at 1600 nm, of CQD synthesized using the “low-molecular-weight alcohols electrochemical carbonization” method. The CQD are analyzed using spectroscopic techniques, optical activity in the infrared, and high-resolution transmission electron microscopy. Results show a CQD size distribution of 5±3 nm and spherical morphology. The absorption spectra show increased absorption at both, high and low frequency. Additionally, the specific rotation of the CQD solution is significantly higher than that of pure ethanol, by three orders of magnitude. These findings suggest that CQD may have potential applications in polarized infrared filters and/or sensors due to their ability to rotate the polarization state of light at 1550 nm. The results of this study provide valuable insights into the optical properties of CQD and their potential for infiltration into hollow core photonic crystal fibers, making them a promising material for future research and development in the field of optics and sensing. 相似文献
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Chun-Dong Xue Zhong-Ping Sun Yong-Jiang Li Jian-Feng Chen Bo Liu Kai-Rong Qin 《Electrophoresis》2020,41(10-11):909-916
In the present study, we numerically demonstrate an approach for separation of micro and sub-micro diamagnetic particles in dual ferrofluid streams based on negative magnetophoresis. The dual streams are constructed by an intermediate sheath flow, after which the negative magnetophoretic force induced by an array of permanent magnets dominates the separation of diamagnetic particles. A simple and efficient numerical model is developed to calculate the motions of particles under the action of magnetic field and flow field. Effects of the average flow velocity, the ratio of sheath fluid flow to sample fluid flow, the number of the magnet pair as well as the position of magnet pair are investigated. The optimal parametric condition for complete separation is obtained through the parametric analysis, and the separation principle is further elucidated by the force analysis. The separation of smaller micro and sub-micro diamagnetic particles is finally demonstrated. This study provides an insight into the negative magnetophoretic phenomenon and guides the fabrication of feasible, low-cost diagnostic devices for sub-micro particle separation. 相似文献
166.
Stilling basin with a negative step is an important structure in hydraulic systems, because it can avoid atomization and decrease scouring problems. Although stilling basins with a negative step have attracted much attention from researchers, few researchers have focused on the wave characteristics. In this research, an experimental study on the wave characteristics of stilling basins with a negative step was carried out. The wave height, average period, wave probability density and power spectrum along the flow direction of different stilling basins with a negative step were described based on the wave theory, and the results indicate discharge and step height have a significant effect on the wave characteristics. The relationships between the different characteristic wave heights, and the empirical formula for the relative characteristic wave height are obtained. Finally, the dimensionless standard deviation at the end of the stilling basin with a negative step is linearly related to the flow-energy ratio and the relative step height under B-jump. 相似文献
167.
Fast gas chromatography/negative-ion chemical ionization mass spectrometric (GC/NICI-MS) assay combined with rapid and nonlaborious sample preparation is presented for the simultaneous determination of benzodiazepines and alpha-hydroxy metabolites, zaleplon and zopiclone in whole blood. The compounds were extracted from 100 microl of whole blood by simultaneous multitube, microscale liquid-liquid extraction (LLE) and derivatized by N-methyl-N-(tert-butyldimethylsilyl)trifluoroacetamide (MTBSTFA), without the need for the time-consuming concentration stage. In the analytical separation, various parameters of fast GC/NICI-MS were applied, e.g. the use of hydrogen as a GC carrier gas, a high carrier gas velocity, a small film thickness of the analytical column, fast MS data acquisition, fast temperature ramping, and high initial and final temperatures of GC column. Sensitive identification, screening and quantitation of 18 compounds of interest were achieved in chromatographic separation in only 4.40 min. Accurate and reproducible results were obtained by using five different and carefully selected deuterated analogues on the basis of the chemical properties of the target analytes. Nevertheless, for alpha-OH-midazolam, and for bromazepam and flunitrazepam at low concentrations, the results can be considered only semiquantitative on the basis of the validation data. The extraction efficiencies ranged from 74.3 to 105.7% and the limits of quantitation (LOQ) from 1 to 100 ng ml(-1). Rapid sample preparation and fast chromatographic separation allowed cost-efficient, reliable and high sample-throughput analyses with a low amount of manual work. The method was fully validated and accredited according to EN ISO/IEC 17025 standards and is applicable for sensitive, reliable and quantitative determination of benzodiazepines, zaleplon and zopiclone, e.g. in clinical and forensic toxicology. 相似文献
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¼ 《Superlattices and Microstructures》2000,28(5-6)
The metal-oxide-semiconductor (MOS) field effect transistor (FET) using ‘oxidized μ c-Si/ultrathin oxide’ gate structure was studied. It was found that this structure shows negative differential resistance behavior, which can be explained by the Coulomb blockade effect of trapped carriers and immediate tunneling into and tunneling out with gate bias variation. The requirements for the device with this structure showing negative differential resistance behavior are based on very weak resistive coupling between floating gate and channel. They are the thinness of the tunnel oxide film, the thickness ratio of the upper oxidized film and the tunnel oxide, and the channel threshold voltage. MOSFET with this gate structure is proposed as a new negative differential resistance device. 相似文献
170.
本文研究高阻恒流源驱动的光发射二极管(LED)的输出光场的振幅噪声压缩与电,光量子效率,漏电流效应,泵浦残余噪声频率的关系,指出高阻恒流技术不仅使任意纵模产生振幅噪声压缩,而且由于仅在高阻恒流下各纵模间存在负量子相关,使得LED总输出光场的振幅噪声压缩加深。 相似文献