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111.
4-Aminobenzoic acid (4-ABA) was covalently grafted on a glassy carbon electrode (GCE) by amine cation radical formation during the electrooxidation process in 0.1 M KCl aqueous solution. X-ray photoelectron spectroscopy (XPS) measurement proves the presence of 4-carboxylphenylamine on the GCE. Electron transfer processes of Fe(CN)63− in solutions of various pHs at the modified electrode are studied by both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Changing the solution pH would result in the variation of the terminal group's charge state, based on which the surface pKa values were estimated. The copper hexacyanoferrate (CuHCF) multilayer films were formed on 4-ABA/GCE prepared in aqueous solution, and which exhibit good electrochemical behavior with high stability. 相似文献
112.
基于对多层衍射元件的衍射效率的理论分析,设计了用于头盔显示器的含有多层衍射元件的60视场折/衍射混合目镜系统。系统在设计波段和整个视场范围内衍射效率均在90 %以上,提高了光能利用率和像面对比度。目镜的出瞳距离为22 mm,出瞳直径为8 mm。调制传递函数(MTF)在25 lp/mm时全视场均在0.38以上,满足VGA分辨率要求。目镜中畸变为4.8%,垂轴色差最大为10 m。整个系统结构紧凑,镜头总长26.8 mm,最大直径16 mm,全系统质量仅8 g,实现了光学系统的轻小型化 相似文献
113.
The mixed covolume method for the regularized long wave equation is developed and studied. By introducing a transfer operator γh , which maps the trial function space into the test function space, and combining the mixed finite element with the finite volume method, the nonlinear and linear Euler fully discrete mixed covolume schemes are constructed, and the existence and uniqueness of the solutions are proved. The optimal error estimates for these schemes are obtained. Finally, a numerical example is provided to examine the efficiency of the proposed schemes. 相似文献
114.
A fractional step scheme with modified characteristic finite differences running in a parallel arithmetic is presented to simulate a nonlinear percolation system of multilayer dynamics of fluids in a porous medium with moving boundary values. With the help of theoretical techniques including the change of regions, piecewise threefold quadratic interpolation, calculus of variations, multiplicative commutation rule of difference operators, multiplicative commutation rule of difference operators, decomposition of high order difference operators, induction hypothesis, and prior estimates, an optimal order in l 2 norm is displayed to complete the convergence analysis of the numerical algorithm. Some numerical results arising in the actual simulation of migration-accumulation of oil resources by this method are listed in the last section. 相似文献
115.
采用脉冲电位法(PPSM)结合聚苯胺(PANI)的层层自组装制备了Pd/PANI交替沉积纳米多层膜, 并用于抗坏血酸(AA)和多巴胺(DA)的检测. 实验发现, 多层膜结构形貌及催化性能受前躯体K2PdCl6浓度、 脉冲条件及膜厚度等影响. 当K2PdCl6浓度为2×10-3 mol/L, 阴极脉冲电位为-0.3 V, 阶跃次数为17时, 5层Pd/PANI修饰玻碳电极对AA和DA的催化性能最佳; 在0.1 mol/L磷酸盐缓冲液中, AA和DA的氧化峰明显分离[ΔEp(AA, DA)=160 mV], 其峰电流与浓度分别在5×10-5~4×10-4和4×10-5~1×10-4 mol/L范围内呈较好线性关系, 实现了对AA和DA的同时测定. 该修饰电极具有良好的抗干扰性和稳定性. 相似文献
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硅基底多层薄膜结构材料残余应力的微拉曼测试与分析 总被引:1,自引:0,他引:1
针对MEMS器件制备中两种典型的硅基底多层薄膜结构的残余应力问题,本文提出了利用微拉曼光谱技术测量其残余应力的方法,分析并给出了硅基底多层薄膜结构中的残余应力分布规律。实验结果表明,在硅基底和薄膜内存在较大的工艺残余应力,残余应力在基底内靠近薄膜两侧部分呈非线性变化,在基底内主要呈线性变化,并引起基底整体翘曲。基于实验结果分析,提出了硅基底多层薄膜结构的分层结构模型。本文工作表明微拉曼光谱技术是测量与研究硅基底多层薄膜结构残余应力的一种有力手段。 相似文献
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120.
Fabrication and characterization of ultra-low noise narrow and wide band Josephson parametric amplifiers
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We have fabricated two types of lumped-element Josephson parameter amplifiers (JPAs) by using a multilayer micro-fabrication process involving wet etching of Al films. The first type is a narrow band JPA which shows typical gain above 14 dB in a bandwidth around 35 MHz. The second type is a wideband JPA which is coupled to an input 50 Ω transmission line via an impedance transformer that changes the impedance from about 15 Ω on the non-linear resonator side to 50 Ω on the input transmission line side. The wideband JPA could operate in a 200 MHz range with a gain higher than 14 dB. The amplifiers were used for superconducting qubit readout. The results showed that the signal to noise ratio and hence the readout fidelity were improved significantly. 相似文献