Improving the flame retardancy of polyamide 6 by incorporating hexachlorocyclotriphosphazene modified MWNT

A nitrogen‐, phosphorus‐ and chlorine‐containing flame retardant, hexachlorocyclotriphosphazene (HCTP), has been covalently grafted onto the surface of multi‐wall carbon nanotubes (MWNT) to obtain MWNT‐HCTP. Polyamide 6 (PA6)/MWNT composites were then prepared via melt compounding. The flammability of PA6/MWNT composite was characterized by cone calorimetry, limiting oxygen index (LOI) and UL‐94 tests. The results showed that peak heat release rate of samples containing 3 wt% MWNT‐HCTP was only 460 kW/m², which decreased by 35.2% compared with that of a neat PA6 sample. The LOI value was increased from 22.7% to 26.5%, and UL‐94 test performance was also significantly improved by the presence of MWNT‐HCTP. Scanning electron microscope (SEM) and optical microscope analysis showed that modified MWNT had a better dispersion and compatibility in PA6 than unmodified MWNT. The composition of residue chars and volatile products was investigated by SEM/energy dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy (FTIR) and thermogravimetric‐FTIR, respectively. It was proposed that grafted HCTP was mainly functioned in the condensed phase, where P, N can synergistically promote char formation and Cl element can catch free radicals to terminate the chain reaction during combustion of the PA6 composite. Copyright © 2014 John Wiley & Sons, Ltd.     

基础物理实验网络教学及管理系统的开发研究

本文主要介绍如何利用计算机技术开发《基础物理实验网络教学及管理系统》,用以提高实验教学质量,使实验教学管理工作更加规范化、标准化和高效化.     

利用不确定性提高击中击不中变换的抗畸变能力

对用于目标识别技术的形态学击不中变换进行了分析,引入不确定和模式的概念使得容易受到畸变干扰的像素点对判别结果的作用降低,得到联合排序多值击中击不中变换,从而在不损失图像信息的前提下,提高了目标识别的抗畸变能力,并且具有在输入图像和参考模板之间进行精确匹配的能力。基于非相干相关器,利用新颖的多值互补编码方法,实现了二值图像的联合序多值击中击不中变换,达到了较好的实验结果。     

基于远程控制的六足搜救机器人系统的设计

针对灾后现场环境的危险性与复杂性,设计了一套搜救机器人系统。在基于仿生学的基础上设计机器人六足式移动平台,以Atmega128型单片机为控制核心,通过步态与动作控制,使之具有强大的越障能力和机体灵活性。整个搜救系统分为机器人系统和控制中心系统两大部分。机器人系统配有完备的传感器模块以及高清摄像头,通过无线传输技术,可在0-1000米范围内实现向控制中心系统上位机的数据与图像传输,并接受上位机控制指令,控制中心根据采集到的信息,可以有效指挥现场搜救人员,大大提高了搜救速度与效率。     

Multi‐state multi‐reference Møller–Plesset second‐order perturbation theory for molecular calculations

This work presents multi‐state multi‐reference Møller–Plesset second‐order perturbation theory as a variant of multi‐reference perturbation theory to treat electron correlation in molecules. An effective Hamiltonian is constructed from the first‐order wave operator to treat several strongly interacting electronic states simultaneously. The wave operator is obtained by solving the generalized Bloch equation within the first‐order interaction space using a multi‐partitioning of the Hamiltonian based on multi‐reference Møller–Plesset second‐order perturbation theory. The corresponding zeroth‐order Hamiltonians are nondiagonal. To reduce the computational effort that arises from the nondiagonal generalized Fock operator, a selection procedure is used that divides the configurations of the first‐order interaction space into two sets based on the strength of the interaction with the reference space. In the weaker interacting set, only the projected diagonal part of the zeroth‐order Hamiltonian is taken into account. The justification of the approach is demonstrated in two examples: the mixing of valence Rydberg states in ethylene, and the avoided crossing of neutral and ionic potential curves in LiF. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2006     

M-TIMES SECANT-LIKE MULTI-PROJCTION METHOD FOR SPARSE MINIMIZATION PROBLEM

M-TIMES SECANT-LIKE MULTI-PROJCTION METHOD FOR SPARSE MINIMIZATION PROBLEM@林正华 @宋岱才 @赵立芹~~     

Three bits eight states photochromic recording and nondestructive readout by using IR light

A photochromic polymer film containing three different diarylethene derivatives, that is, 1,2-bis(3,5-dimethyl-2-thienyl)perfluorocyclopentene (1), 1,2-bis(2,5-dimethyl-3-thienyl)perfluorocyclopentene (2), and 1,2-bis(2-methyl-5-phenyl-3-thienyl)perfluorocyclopentene (3) was prepared. Upon UV irradiation, the three derivatives changed to their closed-ring isomers having different colors, yellow, red, and blue. They showed different spectra not only in UV/Vis region but also in the IR spectral region. Upon irradiation with visible light of appropriate wavelengths, each closed-ring isomer was selectively bleached, and three bits eight states recording was performed. The eight states could be read out nondestructively by using IR light of appropriate wavenumbers.     

侧向多喷口干扰复杂流动数值模拟研究

采用具有高分辨率的NND格式,通过数值求解N-S方程对典型外形多喷口侧向喷流复杂干扰流动进行了数值模拟. 为了提高计算效率,采用了LU-SGS隐式算法. 采用分块对接网格技术,生成高质量的贴体计算网格,精确模拟喷口截面. 对比分析了不同计算格式、限制器形式、网格拓扑及流动形态(层流与湍流)对喷流干扰流场结构和压力分布特性的影响,研究和分析了喷口附近流场的涡系结构、波系结构和喷流干扰引起的气动力特性. 在上述研究的基础上,针对典型飞行器外形的侧向喷流干扰特性进行了详细的数值模拟,得到了喷口参数(喷口位置、数目等)及来流条件对喷流干扰流场结构、气动力特性的影响规律,并对其流动机理进行了相应的分析. 研究表明,发展的针对多喷口侧喷干扰的数值计算方法是成功的,可以应用于飞行器侧向喷流干扰的流场结构分析及气动力特性数值预测.      

JAVA多线程技术在图像处理中的应用

使用JAVA多线程技术对复杂图像下载并进行处理和控制,从而达到图像显示的动态性和交互性效果,并给出了一个具体的应用实例。