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Víctor García‐Herrero Carlos Torrado‐Salmern Juan Jos García‐Rodríguez Guillermo Torrado Santiago Torrado‐Santiago 《Journal of separation science》2019,42(9):1702-1709
Rapid, simple, and sensitive submicellar liquid chromatography with fluorescence detection was developed and validated to quantify naproxen in plasma and brain samples after oral administration of Naproxen formulations. The method used tramadol as an internal standard. Different submicellar mobile phases with organic phases ranging from 40 to 60% were studied to improve the native fluorescence of the Naproxen and decrease retention times. Separation was done in a Zorbax SB C8 column (250 × 4.6 mm, 5 μm) with a mobile phase containing acidic 0.007 M sodium dodecyl sulfate/acetonitrile (50:50, v/v) at a flow rate of 1 mL/min. Detection was performed with an excitation wavelength of 280 nm and emission of 310 nm and 360 nm for internal standard and Naproxen, respectively. The method was validated by International Conference of Harmonization standards. The method is specific, accurate, and precise (relative standard deviation <3%). Limits of detection and quantification were 0.08 and 0.25 μg/mL, respectively, for biological samples. This method was applied to analyze brain/plasma ratios in mice that had received oral administrations of Naproxen micellar formulations containing 10% w/w of sodium dodecyl sulfate, Cremophor RH 40, or Tween 80. The sodium dodecyl sulfate micelles were faster and more widely distributed in the mouse brains. 相似文献
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Thermal Aqueous Liquid Chromatography (TALC) using pure water as a mobile phase should be a very attractive technique promoting the use of liquid chromatography in routine analysis, either in the laboratory or in future on-line process control. This simple form of chromatography, the selectivity of which depends on the fixed phase only, would allow the use of flame ionization as an almost universal, low-cost detector in liquid chromatography. The potential of the TALC technique is illustrated by selected examples. 相似文献
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Based on the relationship defining the dependence of the capacity ratio upon the composition of the mobile phase, a simple numerical procedure is proposed for evaluating the heterogeneity parameter and the ratio of molecular sizes of solute and solvent. This procedure is examined by using HPLC data for pesticides chromatographed in isooctane/dichloromethane eluent on Lichrosorb at 291 K. 相似文献
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Károly Lázár Nicolas Micheaud R. Magdolna Mihályi Gabriella Pál-Borbély Hermann K. Beyer 《Reaction Kinetics and Catalysis Letters》2001,74(2):289-298
Three variants of solid-state ion exchange were studied. Iron exchange was found to proceed in the first case, in theFeCl2+NH4ZSM-5 FeZSM-5 + NH4Cl process, even at low exchange capacity (Si/Al = 25).The second, Fe2O3 (hematite) + HZ direct reaction does not result in any noticeable interaction for eitherZ = Y or ZSM-5. This process can significantly be promoted by introducing CCl4 vapor via forming chlorine-containingmobile species. However, the structure of the Y zeolite largely collapses during this treatment, whereas the crystalline state of ZSM-5is preserved. 相似文献
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语义地图构建对移动机器人导航与规划具有重要意义,而环境分类是语义地图构建的核心问题。目前所采用的环境分类方法匹配率较低,已成为语义地图构建所面临的主要问题。对此笔者提出了一种基于支持向量机的分类方法,该方法利用激光雷达数据提取环境几何特征,训练SVM分类器对机器人工作空间模式进行识别,并将所提算法用于室内环境的语义分类。实验结果表明,该分类方法具有较高的识别率,可有效地实现语义地图构建。 相似文献