可粘贴超疏水薄膜的制备

通过聚二甲基硅氧烷(PDMS)与碳纤维织物复合, 采用模板法在PDMS聚合物表面构筑微阵列结构, 制备了一种具有可重复粘贴性的超疏水薄膜. 研究结果表明, 该薄膜微结构表面的接触角为154°, 滚动角为14°, 具有低黏附的超疏水特性. 而PDMS与碳纤维织物的紧密结合, 赋予了超疏水薄膜较高的黏接力和力学性能, 断裂强度达到116.96 MPa. 所制备的超疏水薄膜可粘贴于多种材料表面, 同时经过30 d的长时间粘贴以及50次的循环粘贴后, 该薄膜依然保持着较高的黏附性能及超疏水特征, 表明超疏水薄膜具有良好的力学稳定性及耐久性, 满足长时间可重复使用的要求, 可应用于对破损超疏水涂层的快速、 大面积粘贴修复.     

Enhanced nucleate boiling on copper micro-porous surfaces

Saturation boiling of PF-5060 dielectric liquid on Cu micro-porous surface layers (95, 139, 171, 197 and 220-μm thick) is investigated. These layers are deposited on 10 × 10 mm Cu substrates using two-stage electrochemical process. The basic micro-structure, obtained in the first stage using current density of 3 A/cm² for 15–44 s, depending on thickness, is strengthened by continuing electrochemical deposition using much lower current density for 10’s of minutes. For conditioned surface layers, after a few successive boiling tests, the pool boiling curves are reproducible and the temperature excursion prior to boiling incipience is either eliminated or reduced <7 K. Present nucleate boiling results are markedly better than those reported for dielectric liquids on micro- and macro-structured surfaces. Present values of CHF (22.7–27.8 W/cm²) and h_MNB (2.05–13.5 W/cm² K) are ∼40–70% higher than and >17 times those reported on plane surfaces (<16 W/cm² and ∼0.8 W/cm² K). Best results are those of the 171-μm thick layer: CHF of 27.8 W/cm² occurs at ΔT_sat of only 2.1 K and h_MNB of 13.5 W/cm² K occurs at ΔT_sat = 2.0 K.     

微结构特性的光学测试平台

微结构是微机电系统的基本元件,其几何尺寸、运动特性、材料及力学特性直接影响微机电系统的整体性能。提出一种将计算机微视觉、米劳显微干涉、频闪成像和激光多普勒测振等技术充分融合的微结构静态和动态特性的光学测试平台,分别对微谐振器的平面和离面周期运动特性和微机械扭转镜的离面瞬时运动特性进行测试研究。实验结果表明,利用计算机微视觉和频闪成像技术能够实观微结构的平面位移、运动相位及喈振频率等周期运动参量的测试．位移的重复精度为30nm;利用显微干涉和频闪成像技术可实现微结构的离面位移及表面扭曲等周期运动参量的测试．位移的重复精度为3nm;激光多普勒测振技术具有在频域上对微结构瞬态运动进行分析的优点．是时域上周期运动测试的重要补充。     

铅基压电薄膜材料的制备、微结构与性能

随着微电子技术的发展和高度集成化的趋势,压电薄膜材料愈来愈受到人们的重视.本文对铅基类压电薄膜材料的研究进展进行了评述,主要讨论了:(1) 两种主要制备方法:脉冲激光熔融法(PLD)和溶胶凝胶法(Sol-Gel); (2) 压电薄膜微观结构的表征,如畴结构,薄膜材料与大块材料的差别等;(3) 压电薄膜材料力学、电学及相互耦合性能的评价参数,薄膜处理过程的相变和残余应力和破坏特征.最后提出了人们可能关注的一些问题.      

新型添加剂对单晶硅表面金字塔形貌的影响

单晶硅表面微结构对晶体硅光电转换性能有非常重要的影响, 晶体硅表面微结构的调节技术一直是半导体、 太阳能电池领域研究的热点之一.利用碱液与单晶硅异向腐蚀特性的刻蚀技术, 在单晶硅表面可以获得布满金字塔的绒面, 但普通碱液刻蚀的绒面, 其金字塔大小、 形貌和分布随机性大, 不利于提高硅太阳电池的转换效率.在普通的碱腐蚀液中加入不同量的特种添加剂, 然后在相同的温度、 时间下刻蚀单晶硅表面, 通过观察样品表面SEM图, 发现在普通碱液中加入适量添加剂后刻蚀的单晶硅表面能形成均匀密集分布金字塔, 金字塔大小在2—4μupm 之间, 棱边圆滑, 表面金字塔覆盖率高; 用积分反射仪测量了样品的反射率曲线, 发现样品平均反射率下降到12.51%.实验结果表明, 在普通碱液中加入特种添加剂, 能控制单晶硅表面金字塔的大小和分布.     

316L不锈钢粉末光纤激光选区熔化特性

采用自行研制的光纤激光选区熔化快速成型设备,研究了选区激光熔化316L不锈钢粉末工艺参数、能量输入与样件致密度、表面形貌之间的关系以及微观组织特征。结果表明:扫描速度对成型效果影响最为显著;样件致密度随着激光能量密度提高有逐渐增大的趋势;能量密度作为选区激光熔化工艺的技术指标具有可操作性;表面形貌由激光功率与扫描速度比值所决定。深入探讨了能量输入、熔化凝固行为、激光功率与扫描速度比值与样件致密度、表面形貌的关系。结果表明:选区激光熔化凝固组织层内、层间熔合处为弧形,且为冶金结合,金相组织主要由柱状晶与等轴晶组成,层内靠近熔合线周围是柱状晶,而层间靠近熔合线附近主要是细小等轴晶,晶粒直径为1μm左右。     

Micro-structure and frictional characteristics of beetle''s joint

Geometric and micro-structure design, tribology properties of beetle joints were experimentally studied, which aimed to enlighten ideas for the joint design of MEMS.The observation by using SEM and microscopy suggested that beetle's joints consist of a concave surface matched with a convex surface. The heads of the beetles, rubbing with flat glass, were tested in fresh and dried statuses and compared with sapphire ball with flat glass. Frictional coefficient of the joint material on glass was significantly lower than that of the sapphire sphere on glass. The material of the joint cuticle for convex surface is rather stiff (the elastic modulus 4.5 Gpa) and smooth. The surface is hydrophobic (the contact angle of distilled water was 88.3° ). It is suggested here that the high stiffness of the joint material and hydrophobicity of the joint surface are parts of the mechanism minimizing friction in insect joints.     

六方晶型MgTiO3温致微结构变化及其原位拉曼光谱研究

采用固相烧结法制备了六方晶型结构的MgTiO₃粉体. 经高温原位X射线衍射分析(293-1473 K)进行了表征与确认,获得了晶胞参数及其随温度的变化,测量了高温原位拉曼光谱(273-1623 K),并运用第一性原理理论计算方法对应核实了拉曼谱峰的归属. 结果表明,随着温度升高,MgTiO₃晶面间距和晶格常数增大,从而反映对于拉曼光谱较为敏感的键长和键角的变化;温致拉曼位移可以反映Ti-O,Mg-O等键长以及Ti-O-Ti,Ti-O-Mg与Mg-O-Mg等键角随温度的细微变化,相关关系则独立于温度,有效提升了原位拉曼光谱微探针诊断技术的分析能力;拉曼谱峰随温度升高而展宽,表明原子瞬间运动振幅加剧,弥散性增加,稳定性有所下降,但仍维持六方晶型. 关键词： 3')" href="#">MgTiO₃ 微结构 拉曼光谱 高温     

Characterizing limit order prices

A computational model of a limit order book is used to study the effect of different limit order distribution offsets. Reference prices such as same side/contra side best market prices and last traded price are considered in combination with different price offset distributions. We show that when characterizing limit order prices, varying the offset distribution only produces different behavior when the reference price is the contra side best price. Irrespective of the underlying mechanisms used in computing the limit order prices, the shape of the price graph and the behavior of the average order book profile distribution are strikingly similar in all the considered reference prices/offset distributions. This implies that existing averaging methods can cancel variabilities in limit order book shape/attributes and may be misleading.     

Adaptive Finite Element Approximations for a Class of Nonlinear Eigenvalue Problems in Quantum Physics

In this paper, we study an adaptive finite element method for a class of nonlinear eigenvalue problems resulting from quantum physics that may have a nonconvex energy functional. We prove the convergence of adaptive finite element approximations and present several numerical examples of micro-structure of matter calculations that support our theory.