彩色光弹性干涉影像分析系统

自行开发的“彩色光弹性干涉影像分析系统”首先利用CCD成像和图像采集设备,将光弹图像以数字图像的形式存储到计算机,然后通过对存储的光弹图像进行处理,得到物体边界、等差线、等倾线等数据。最后根据这些数据,绘制出主应力迹线,并进行二维的和三维的应力分析。本文着重介绍了系统整体设计以及系统研制的难点问题(彩色光弹图像处理、主应力迹线的绘制等)。系统可以通过对彩色图像进行分解,应用目前已经比较成熟的灰度光弹图像处理技术,来完成彩色图像的处理;也可以直接应用彩色信息来确定条纹级数,进行相关处理。彩色图像能够比灰度图像提供更精确的图像信息,以满足高精度测量的要求。     

A Gallium‐Substituted Distibene and an Antimony‐Analogue Bicyclo[1.1.0]butane: Synthesis and Solid‐State Structures

RGa {R=HC[C(Me)N(2,6‐iPr₂C₆H₃)]₂} reacts with Sb(NMe₂)₃ with insertion into the Sb? N bond and elimination of RGa(NMe₂)₂ ( 2 ), yielding the Ga‐substituted distibene R(Me₂N)GaSb?SbGa(NMe₂)R ( 1 ). Thermolysis of 1 proceeded with elimination of RGa and 2 and subsequent formation of the bicyclo[1.1.0]butane analogue [R(Me₂N)Ga]₂Sb₄ ( 3 ).     

Six‐Coordinate Group 13 Complexes: The Role of d Orbitals and Electron‐Rich Multi‐Center Bonding

Bonding in six‐coordinate complexes based on Group 13 elements (B, Al, Ga, In, Tl) is usually considered to be identical to that in transition‐metal analogues. We herein demonstrate through sophisticated electronic‐structure analyses that the bonding in these Group 13 element complexes is fundamentally different and better characterized as electron‐rich hypervalent bonding with essentially no role for the d orbitals. This characteristic is carried through to the molecular properties of the complex.     

The Synthesis of B2(SIDip)2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes

A new compound with the formula L‐B₂‐L wherein the stabilizing ligand (L) is 1,3‐bis[diisopropylphenyl]‐4,5‐dihydroimidazol‐2‐ylidene (SIDip) has been synthesized, isolated, and characterized. The π‐acidity of the SIDip ligand, intermediate between the relatively non‐acidic IDip (1,3‐bis[diisopropylphenyl]imidazol‐2‐ylidene) ligand and the much more highly acidic CAAC (1‐[2,6‐diisopropylphenyl]‐3,3,5,5‐tetramethylpyrrolidin‐2‐ylidene) ligand, gives rise to a compound with spectroscopic, electrochemical, and structural properties between those of L‐B₂‐L compounds stabilized by CAAC and IDip. Reactions of all three L‐B₂‐L compounds with CO demonstrate the differences caused by their respective ligands, as the π‐acidities of the CAAC and SIDip carbenes enabled the isolation of bis(boraketene) compounds (L(OC)B‐B(CO)L), which could not be isolated from reactions with B₂(IDip)₂. However, only B₂(IDip)₂ and B₂(SIDip)₂ could be converted into bicyclic bis(boralactone) compounds.     

Taming Tin(IV) Polyazides

The first charge‐neutral Lewis base adducts of tin(IV) tetraazide, [Sn(N₃)₄(bpy)], [Sn(N₃)₄(phen)] and [Sn(N₃)₄(py)₂], and the salt bis{bis(triphenylphosphine)iminium} hexa(azido)stannate [(PPN)₂Sn(N₃)₆] (bpy = 2,2′‐bipyridine; phen = 1,10‐phenanthroline; py = pyridine; PPN = N(PPh₃)₂) have been prepared using covalent or ionic azide‐transfer reagents and ligand‐exchange reactions. The azides were isolated on the 0.3 to 1 g scale and characterized by IR and NMR spectroscopies, microanalytical and thermal methods and their molecular structures determined by single‐crystal XRD. All complexes have a distorted octahedral Sn[N]₆ coordination geometry and possess greater thermal stability than their Si and Ge homologues. The nitrogen content of the adducts of up to 44 % exceed any Sn^IV compound known hitherto.     

Exploring the effect of radiation crosslinking on the physico‐mechanical,dynamic mechanical and dielectric properties of EOC–PDMS blends for cable insulation applications

This work focuses on the effect of electron beam irradiation on the physico‐mechanical, dynamic mechanical and dielectric properties of blends based on ethylene octene copolymer (EOC) and poly dimethyl siloxane (PDMS) rubber. It is found that electron beam irradiation caused considerable improvement in the physico‐mechanical properties; the tensile strength was enhanced by nearly 35% for 70:30 EOC:PDMS blend. Phase morphology of the blends analyzed before irradiation by scanning electron microscopy (SEM) exhibited droplet/matrix morphology with sizes of the PDMS rubber domain varying from 0.55 µm to 0.47 µm as the amount of PDMS rubber decreased from 30 wt% to 10 wt%. This reduction in the PDMS rubber domain has been correlated with the physico‐mechanical properties of the blends. Further, the dynamic mechanical properties and creep behavior of these EOC:PDMS blends before and after irradiation has been studied. It is inferred that the 70:30 blend after radiation crosslinking shows a 17% decrease in the creep compliance, i.e. higher creep resistance compared to neat blends. All the radiation crosslinked blends exhibited lower dielectric constant, lower dielectric loss and higher electrical resistivity as compared to the virgin blends which makes it suitable for cable insulating application. Copyright © 2016 John Wiley & Sons, Ltd.     

Research on mechanical and dielectric properties of XLPE cable under accelerated electrical‐thermal aging

Research into the electrical‐thermal aging properties of cross‐linked polyethylene (XLPE) cable has great significance, because of its wide application. This study conducted accelerated electrical‐thermal aging tests on 10‐kV XLPE cable in order to assess the cable's mechanical and dielectric properties. After being aged by applying 34.8‐kV AC voltage at the four temperatures of 90, 103, 114, and 135°C, the cable samples were taken out in five stages according to the aging time and cut into slices. The slices were conducted experiments to test the breaking elongation, tensile strength, gel content, breakdown voltage, and frequency spectrums of the dielectric constant and dielectric loss. The results demonstrate that the mechanical strength and gel content of XLPE vary greatly under different aging temperatures, a finding that is associated with the crystallization characteristics of the material. The breakdown voltage shows a slight decreasing trend with aging time. The dielectric constant decreases with aging time in high‐frequency areas (10³–10⁶ Hz), while the dielectric loss factor increases with aging time at low frequencies (10^?2–0 Hz). These two parameters can be used to characterize the degree of aging in cable. Copyright © 2016 John Wiley & Sons, Ltd.     

On Cartan's theorem for linear operators

In this paper, we describe a second main theorem of holomorphic curves in , of hyper‐order strictly less than 1, that involves a general linear operator . As an application, we derive a truncated second main theorem of degenerate holomorphic curves of hyper‐order strictly less than 1 using Nochka weights.     

参数灵敏度分析的神经网络方法及其工程应用

在系统分析中，参数灵敏度分析不仅为判断各系统参数的重要性大小提供了依据，量化的灵敏度指标也是后续参数估计的前提。然而，在多效实际系统中，系统参数与系统状态间的显式函数关系不易得到，导致一阶灵敏度指标无法直接求取。简化的单因素分析方法亦存在模型粗糙、精度不高的缺点。本文研究采用人工神经网络的高精度泛化映射，通过少量样本的训练，建立复杂系统中多个系统参数与系统状态间的近似映射关系，继而推导得到统一的灵敏度计算列式。简单结构的神经网络方法和解析方法的对比计算显示了方法的有效性和可靠性。最后，应用该法对某斜拉桥结构的荷载参数和刚度参数进行了考查，得到一般性结论。     

THEORETICAL AND EXPERIMENTALRESEARCH ON DYNAMIC BEHAVIOR OF GUYED MASTS UNDER WIND LOAD

I. INTRODUCTION Wind-induced vibration is the critical factor for the safety of guyed masts. Many dynamic modelshave been proposed in the literature[1 , 2]. However, there are obvious de?ciencies in many of theseprevious works owing to the poor cabl…