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81.
S. Soriano C. Dufour K. Dumesnil Ph. Mangin 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,63(4):469-478
Below its ordering temperature (T
N
= 90 K), bulk bcc Eu has a helical magnetic state with propagation vectors along the three equivalent 〈100〉 directions. In
contrast, epitaxial (110)Eu films exhibit a unique magnetic ordering: the domain with a magnetic helix propagating along the
in-plane [001] direction vanishes on cooling, at the expense of other domains with helices propagating along [100] and [010].
This paper is devoted to the study of the stability of the magnetic domains in an external magnetic field using neutron scattering
experiments and macroscopic magnetization measurements. The helix propagating along the [001] direction can be restored by
the application of an external field along this direction. On the contrary, when a magnetic field is applied along an intermediate
direction, specifically [10], the domain with a helix propagating along [001] is suppressed. Both effects depend on the film thickness. They are explained
if one considers that, because of the low magnetic anisotropy of Eu, a helix with a propagation vector parallel to (or close
to) the applied magnetic field is energetically more favourable than cycloidal structures with unchanged propagation vectors.
Finally, the amplitudes of the propagation vectors and their directions (that are modified in films compared to bulk) do not
vary under magnetic field. 相似文献
82.
83.
A method for the analysis of alkaloids in Macleaya cordata (Willd.) R. Br. using high-performance liquid chromatography with diode array detection and electrospray ionization mass spectrometry (HPLC-DAD-ESI/MS) was developed. Using protopine (PRO), allocryptopine (ALL), sanguinarine (SA), and chelerythrine (CHE) as the model components, different columns for the separation and different mobile phases for the signal intensities of alkaloids in ESI/MS were investigated, respectively. The results showed that good separation and high signal intensities can be obtained on a high carbon loading (17%) reversed-phase C(18) column with 30 mM formic acid in mobile phase for the analysis of alkaloids. Under the optimal separation condition and UV detection (284 nm), linearity of the six alkaloids was obtained over concentration range from 0.05 to 100.00 microg/ml. The limit of detection (LOD) was 1.62, 1.87, 1.79, 1.76, 1.10, and 0.94 ng/ml for SA, CHE, PRO, ALL, dihydrosanguinarine (DHSA), and dihydrochelerythrine (DHCHE), respectively. The LODs with ESI/MS detection were lower three orders of magnitude than those obtained with UV detection. The proposed method could be used to control quality of the raw materials of the herb more comprehensively. 相似文献
84.
85.
液氘在高压下有丰富的电学光学性质。利用反射率和相对介电函数关系并从广义极化角度出发初步建立了计算低Z材料电导率的简易模型;在神光-Ⅱ装置上利用第九路激光冲击加载液氘材料并测量了其在强激光冲击下的高压状态参数和反射率。结合上述理论模型和实验,研究了高压下液氘的电离度和电导率。结果表明,液氘在约70 GPa时的电导率约为2.87105 (Wm)-1,已呈现出较为明显的金属电导特性。显然,冲击加载下液氘从绝缘分子态开始电离并向金属氘转变发生在更低的压强。 相似文献
86.
Numerical modeling via finite element analyses (FEA) and experimental measurements via moiré interferometry were applied to the investigation of abrasive waterjet (AWJ) drilling. Polycarbonate and alumina blocks with dimensions of 25.4 mm×19.5 mm×6.25 mm were subjected to concentrated static loads experimentally and numerically. The assumptions of the FEA model are verified by comparing the experimental results with the numerical solution. A closed-form solution confirmed the correlation between the two. It was concluded that the assumption of the FEA model (e.g. mesh, boundary conditions, pressure loading, etc.) represented the static conditions. This conclusion allowed the application of a hybrid numerical/experimental technique to understand the complex interaction of the target material and the AWJ slurry column during drilling. 相似文献
87.
Michael F. Zimmer 《Journal of statistical physics》1993,73(3-4):751-764
The fluctuation-dissipation theorem is not expected to hold for systems that either violate detailed balance or have time-dependent or nonpotential forces. Therefore the relation between response and correlation functions should have contributions due to the nonequilibrium nature. An explicit formula for such a contribution is calculated, which in the present derivation appears as a historydependent term. These relations are the Ward-Takahashi identities of a supersymmetric formulation of the Langevin models, and the new term results from a broken supersymmetry. 相似文献
88.
Carmine Coluccini Yoke Mooi Ng Yves Ira A. Reyes Hsin-Yi Tiffany Chen Yit Lung Khung 《Molecules (Basel, Switzerland)》2020,25(22)
In this paper, a modified Cyclotriveratrylene was synthesized and linked to a branched Polyethylenimine, and this unique polymeric material was subsequently examined as a potential supramolecular carrier for Doxorubicin. Spectroscopic analysis in different solvents had shown that Doxorubicin was coordinated within the hollow-shaped unit of the armed Cyclotriveratrylene, and the nature of the host–guest complex revealed intrinsic Van der Waals interactions and hydrogen bonding between the host and guest. The strongest interaction was detected in water because of the hydrophobic effect shared between the aromatic groups of the Doxorubicin and Cyclotriveratrylene unit. Density functional theory calculations had also confirmed that in the most stable coordination of Doxorubicin with the cross-linked polymer, the aromatic rings of the Doxorubicin were localized toward the Cyclotriveratrylene core, while its aliphatic chains aligned closer with amino groups, thus forming a compact supramolecular assembly that may confer a shielding effect on Doxorubicin. These observations had emphasized the importance of supramolecular considerations when designing a novel drug delivery platform. 相似文献
89.
90.
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