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201.
为了实现对木材水分的无损检测,设计了一种单边核磁共振(unilateral nuclear magnetic resonance,UMR)传感器,该传感器由单边磁体、抗涡流板、射频线圈、阻抗匹配和调谐电路构成.在距离传感器表面上方75 mm处的50 mm×50 mm的平面内,建立了71.1 mT(共振频率为3.027 MHz)的静态磁场.本文详细介绍了该传感器的设计思路和实现方法,并开展了初步的木材水分无损测量实验.对圆柱形树桩的径向水分分布进行了一维扫描测量,观察了水分由树皮向树芯逐步深入过程中横向弛豫时间(T2)的变化规律,还使用UMR仪对木材干燥过程中水分的挥发进行了测量.实验结果表明,随着干燥的加剧,被测样品T2谱的长T2波峰明显左移、积分面积渐减,而且积分面积与木材样品含水率呈正比.本文为木材研究提供了一种便携的NMR测量设备设计方案,且可以实现野外活体树木的无损测量. 相似文献
202.
Dorin Dusciac Jean-Noël Chazalviel François Ozanam Philippe Allongue Catherine Henry de Villeneuve 《Surface science》2007,601(18):3961-3964
Direct grafting of organic monolayers on Si is of prime interest in order to give specific properties to a silicon surface. However, for microelectronics applications, this possibility is hampered by the limited stability of the grafted layers. It has been previously established that alkyl layers attached to Si surfaces through Si-C bonds become unstable at 250-300 °C, by desorption of alkenes. Changing the nature of the bonding to the surface might allow one to circumvent this desorption pathway and increase the layer stability. In our work, decanol and decyl aldehyde are reacted with the Si(1 1 1)-H surface at ∼100 °C during 20 h in order to obtain alkoxy monolayers. FTIR measurements performed in ATR geometry show that the grafted molecule surface coverage is on the order of 33% after reaction with decanol and 50% after reaction with decyl aldehyde. Characterization by AFM essentially reveals that the morphology of the grafted surfaces is unaffected as compared to that of Si-H surfaces. However, the edges of the terraces at alcohol-grafted surfaces exhibit some pitting, probably due to the presence of water in the grafting liquid. Thermal stability studies show that alkoxy chains progressively disappear from the Si surface between 200 and 400 °C. From the CH2/CH3 ratio in the CH region (2760-3070 cm−1), it appears that the chains undergo progressive dissociation by C-C bond breaking before their complete disappearance from the surface. Therefore, the thermal behaviour of alkoxy monolayers appears quite distinct from that of alkyl monolayers that tend to leave the surface in a much narrower temperature range (250-350 °C), essentially via breaking of the Si-C bonds. 相似文献
203.
Z. Barticevic M. Pacheco C. A. Duque L. E. Oliveira 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,56(4):303-309
A theoretical study, within the effective-mass approximation, of the
effects of applied magnetic fields on excitons in disk-shaped
GaAs-Ga1-xAlxAs quantum dots is presented. Magnetic fields
are applied in the growth direction of the semiconductor
heterostructure. The parity of the excitonic envelope function
related to the simultaneous exchange of ze→-ze and
zh→-zh is a good quantum number and the wave
function, both the odd and even parity, can be expanded as
combination of products of the quantum well electron and hole
function that preserves the parity with appropriate Gaussian
functions. We have simultaneously obtained the energies of the
excitonic ground and excited states and discuss the behavior of
these energies as a function of the magnetic field. 相似文献
204.
P. Mason N. Marginean G. Montagnoli S. Beghini F. Scarlassara E. Farnea C. A. Ur A. Meroni A. M. Stefanini L. Corradi E. Fioretto I. V. Pokrovskiy B. Guiot A. Gadea J. J. Valiente-Dobón F. Della Vedova R. Orlandi E. Sahin D. R. Napoli L. Berti N. Toniolo S. Szilner M. Trotta M. Romoli M. La Commara D. Pierroutsakou M. Sandoli G. Pollarolo G. Benzoni 《The European physical journal. Special topics》2007,150(1):359-361
PRISMA is a magnetic
spectrometer installed at Laboratori Nazionali di Legnaro (Italy)
and designed for A=100–200, E=5–10 MeV-per-nucleon beams, and for
possible use with the proposed radioactive beam facility SPES. The
foremost features of the instrument are presented, along with the
outline of two data analyses exemplifying the effectiveness of
PRISMA-CLARA in studies of reaction
dynamics. 相似文献
205.
206.
Interplay between out-of-plane magnetic plasmon and lattice resonance for modified resonance lineshape and near-field enhancement in double nanoparticles array 下载免费PDF全文
Two-dimensional double nanoparticle (DNP) arrays are demonstrated theoretically, supporting the interaction between out-of-plane magnetic plasmons and in-plane lattice resonances, which can be achieved by tuning the nanoparticle height or the array period due to the height-dependent magnetic resonance and the periodicity-dependent lattice resonance. The interplay between the two plasmon modes can lead to a remarkable change in resonance lineshape and an improvement on magnetic field enhancement. Simultaneous electric field and magnetic field enhancement can be obtained in the gap region between neighboring particles at two resonance frequencies as the interplay occurs, which presents “open” cavities as electromagnetic field hot spots for potential applications on detection and sensing. The results not only offer an attractive way to tune the optical responses of plasmonic nanostructure, but also provide further insight into the plasmon interactions in periodic nanostructure or metamaterials comprising multiple elements. 相似文献
207.
208.
Stretching (kr) and bending (kθ) bond force constants appropriate to describe the bond stiffness of graphene and benzene are calculated using density functional theory. The effect of employing different exchange-correlation functionals for the calculation of kr and kθ is discussed using the generalised gradient approximation (GGA) and the local density approximation (LDA). For benzene, kr = 7.93 mdyn Å-1 and kθ = 0.859 mdyn Å rad-2 using LDA, while kr = 7.67 mdyn Å-1 and kθ = 0.875 mdyn Å rad-2 using GGA. For graphene, kr = 7.40 mdyn Å-1 and kθ = 0.769 mdyn Å rad-2 using LDA, while kr = 6.88 mdyn Å-1 and kθ = 0.776 mdyn Å rad-2 using GGA. This means the difference between the bond force constants for benzene and graphene can be as large as ~12%. The comparison between these two systems allows for elucidation of the effect of periodicity and substitution of carbon atoms by hydrogen in the stiffness of C–C bonds. This effect can be explained by a different redistribution of the charge density when the systems are subjected to strain. The parameters kr and kθ computed here can serve as an input to molecular mechanics or finite element codes of larger carbon molecules, which in the past had frequently assumed the same bond force constants for graphene, benzene or carbon nanotubes. 相似文献
209.
The carbon-13 chemical shift of seventeen N-substituted 2,4,6-triphenyl pyridinium salts (TPP) and N-substituted 2,4,6-triaryl pyridinium (TsPP) salts have been determined. 相似文献
210.
A hierarchical approach bridging the atomistic and nanometric scales is used to compute the elastic properties of boron nitride nanosheets and nanoribbons, examining the effect of sheet size, aspect ratio and anisotropy. The approach consists in obtaining the bond force (force field) constants by dedicated computations based on density functional theory (DFT) and using such constants as input for larger scale structural models solved by finite element analysis (FEA). The bond force constants calculated by DFT are 616.9 N/m for stretching, 6.27×10−19 Nm/rad2 for in-plane rotation and 1.32×10−19 Nm/rad2 for dihedral rotation. Using these constants, the elastic properties of boron nitride nanosheets and nanoribbons predicted by FEA are almost independent of the sheet size, but strongly dependent on their aspect ratio. The sheet anisotropy increases with increased aspect ratio, with nanoribbons of aspect ratios of 10 exhibiting a ratio of elastic moduli along both in-plane directions of 1.7. 相似文献