CATALYTIC CONVERSION OF MUNICIPAL WASTE PLASTIC INTO GASOLINE-RANGE PRODUCTS OVER MESOPOROUS MATERIALS

1. Introduction The recycling of polymer waste is important in the con- servation of resources and the protection of environment. Thermal degradation has been studied to characterize and determine the stability of polymers (Garforth et al., 1997). t Unfortunately, the products of thermal degradation from many polymers are distributed over wide ranges of carbon numbers and their commercial value is low, requiring up- grading for effective utilization. On the other hand, catalytic degradation o…     

空间机械的摩擦学设计探讨

本文对空间机械的摩擦学设计进行了探讨,指出要确保空间机械工作的可靠性,就应当根据摩擦学知识在进行空间机械摩擦副结构、强度及动力学设计的同时,合理地选择润滑方式和润滑材料。作者认为,系统地积累空间摩擦学基础知识和各类润滑材科的基本性能数据,以及建立材科的基本性能与实际应用性能之间的数学关系式,都是进行空间机械摩擦学设计所需要具备的条件,并且提出应当根据摩擦副的使用环境和操作条件选择润滑方式利润滑材料,以及根据润滑材科的性能确定摩擦副的结构、强度和动力学设计的摩擦学设计之方法与步骤。 作者在举例说明对空间机械进行摩擦学设计的重要性后强调指出,为了提高我国空间机械的设计水平,应当加强研究部门与设计部门的密切合作,加速建立以材料之基本性能为基础的摩擦学数据库,并逐步建立空间机械摩擦学设计方面的专家系统。     

The effect of temperature on interfacial characteristics of fiber cord/rubber composite in the pull‐out process

The test of fiber pullout from rubber was carried out under different conditions, at three temperatures. Based on the experiment and a nonlinear two‐dimensional finite element (2D FE) modeling, the single fiber cord pullout from the rubber matrix at different temperatures was analyzed. The changes of interfacial shear stresses and failure mode at every stage of interface cracking forthe fiber cord/rubber composite were also investigated. It is shown that the simulation results of the pullout are in good agreement with the experiment. It is concluded that the 2D FE modeling can effectively predict the thermal interface cracking process for an axisymmetric structure of the fiber cord/rubber composite. Copyright © 2010 John Wiley & Sons, Ltd.     

YAlO3∶Ce晶体的生长及性能研究

本文采用中频感应提拉法生长了尺寸为ø35 mm×70 mm的完整的YAlO₃∶Ce(YAP∶Ce)晶体。XRD测试结果表明所生长的YAP∶Ce晶体主相为YAP相,同时存在第二相YAG相;光致激发发射光谱表明晶体发射波长在344 nm和376 nm,激发波长分别为273 nm、290 nm和305 nm;X射线激发发射光谱表明晶体发射波长在377 nm附近;在γ高能射线激发下,晶体衰减时间曲线呈指数衰减,拟合后得到YAP∶Ce晶体的衰减时间为46 ns,通过高斯拟合以后YAP∶Ce晶体的能量分辨率和绝对光产额分别为8.51%和8 530 ph/MeV。本文分析了晶体生长过程中产生开裂和相变的原因,通过优化温场和工艺可以得到完整无开裂的晶体。如何获得更大尺寸的无开裂、无相变晶体,并实现量产是该晶体规模化应用中需要解决的重要技术难题。     

基于声发射矩张量分析混凝土破坏的裂纹运动

从细观上看, 混凝土是一种由骨料、水泥浆基体、裂纹等组成的非均匀复合材料. 单轴准静态加载条件下, 应力应变曲线表现出明显的准脆性特征. 其变形破坏过程实质上是内部微裂纹产生、扩展和汇合的过程, 研究细观尺度的裂纹扩展演化将有助于深入了解混凝土的变形和破坏过程. 声发射作为一种物理检测方法可以获取材料内部细观损伤演化的物理信息. 本文基于声发射技术, 结合改进的时差定位算法和矩张量理论对声发射信号进行分析, 反演了混凝土巴西劈裂破坏中裂纹位置、裂纹类型以及裂纹面运动方向, 揭示了混凝土宏观拉伸破坏的细观裂纹扩展机制. 结果表明: 裂纹运动过程清晰地显示了混凝土内裂纹源首先在试件与载荷接触面附近产生, 之后聚集形成局部损伤区域, 并沿轴线向中心扩展(加载平面)以及裂纹从试件中间向表面扩展的动态过程(厚度方向); 裂纹运动体积可以作为裂纹形成、扩展过程中弹性能释放的度量, 初始裂纹成核时体积参数较小, 峰值载荷时, 裂纹运动体积最大达到$5.93\times10^{-4}$ mm$^{3}$; 混凝土宏观尺度的拉伸破坏在细观尺度上存在有拉伸裂纹、混合裂纹以及剪切裂纹; 拉伸裂纹最多, 占裂纹总数约为60%, 剪切裂纹最少, 约占裂纹总数的10%; 拉伸裂纹运动主导了试件的宏观劈裂破坏.      

The strain energy density ratio criterion for predicting cracking direction in composite materials

The strain energy density ratio criterion for predicting cracking direction incomposite materials is proposed.The Tsai-Hill criterion and Norris criterion ofcomposite materials are extended to predict the cracking direction in composites.Thethree criteria are used to analyse the crack propagation problem of the unidirectionalfibre composite sheet with various fibre directions.The predicted results are comparedwith those of the existing normal stress ratio criterion and strain energy densitycriterion.     

On the Nature of Extra-Framework Aluminum Species and Improved Catalytic Properties in Steamed Zeolites

Steamed zeolites exhibit improved catalytic properties for hydrocarbon activation (alkane cracking and dehydrogenation). The nature of this practically important phenomenon has remained a mystery for the last six decades and was suggested to be related to the increased strength of zeolitic Bronsted acid sites after dealumination. We now utilize state-of-the-art infrared spectroscopy measurements and prove that during steaming, aluminum oxide clusters evolve (due to hydrolysis of Al out of framework positions with the following clustering) in the zeolitic micropores with properties very similar to (nano) facets of hydroxylated transition alumina surfaces. The Bronsted acidity of the zeolite does not increase and the total number of Bronsted acid sites decreases during steaming. O₅Al(VI)-OH surface sites of alumina clusters dehydroxylate at elevated temperatures to form penta-coordinate Al₁O₅ sites that are capable of initiating alkane cracking by breaking the first C-H bond very effectively with much lower barriers (at lower temperatures) than for protolytic C-H bond activation, with the following reaction steps catalyzed by nearby zeolitic Bronsted acid sites. This explains the underlying mechanism behind the improved alkane cracking and alkane dehydrogenation activity of steamed zeolites: heterolytic C-H bond breaking occurs on Al-O sites of aluminum oxide clusters confined in zeolitic pores. Our findings explain the origin of enhanced activity of steamed zeolites at the molecular level and provide the missing understanding of the nature of extra-framework Al species formed in steamed/dealuminated zeolites.     

α-Fe和γ-Fe中氢扩散行为的第一性原理计算

采用基于密度泛函理论的第一性原理方法,研究了α-Fe和γ-Fe中氢扩散行为,建立了两相的H原子扩散系数与温度的关系式,对比了H原子在两相中扩散的难易程度,并结合2205双相不锈钢的氢致开裂试验对计算结果进行了实验验证.研究结果表明:H原子在α-Fe中所需扩散激活能较γ-Fe低,其容易在α-Fe的缺陷处聚集,并最终造成氢致开裂等严重后果;而2205双相不锈钢的HIC实验表明,裂纹在铁素体相中表现为穿晶型开裂,并且在传播过程中由于受到奥氏体相的阻碍,裂纹沿两相界面发展,表现出混合型开裂方式;综上所述,铁素体相更容易产生氢致裂纹,这进一步证实了本文计算结果的可靠性.     

CF-2沸石的表面酸性及催化性能

CF-2是一种新型的高硅沸石。1981年我们实验室首先在二乙醇胺-甘油-Na₂O-SiO₂-Al₂O₃-H₂O体系中制备成功^[1],以后才见到关于Theta-1^[2],ISI-1^[3],KZ-2^[4],NO-10^[5]和ZSM-22^[6]沸石的报道。