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971.
气凝胶纤维因其高外表面积和高柔韧性在能量管理系统中具有潜在应用而引起了广泛关注.但是,目前制备的气凝胶纤维力学强度较低,限制了其实际应用.为提高气凝胶纤维力学性能,在始终保持细菌纤维素(BC)纳米纤维处于湿态下,利用NaOH/尿素/硫脲复合溶剂直接低温溶解原生BC,获得透明的BC纺丝原液;通过湿法纺丝制备了BC水凝胶纤维,经过水洗和冷冻干燥后处理,制得BC气凝胶纤维.采用偏光显微镜(POM)、13C核磁共振(13C-NMR)和高级旋转流变仪研究BC在复合溶剂中的溶解过程与状态;利用全反射傅里叶变换红外吸收光谱(ATR-FTIR)、X射线衍射(XRD)和热失重(TG)研究BC溶解前后结构与性能变化;利用场发射扫描电镜(FESEM)、全自动比表面积和孔径分布分析仪、单丝强力仪对获得的BC气凝胶纤维结构与性能进行表征.结果表明,复合溶剂在?15℃条件下可以直接溶解原生湿态BC,最高溶解浓度为3 wt%;采用湿法纺丝制得高度多孔的连续BC气凝胶纤维,比表面积高达192 m^2/g且具有优异的力学性能,断裂强度和杨氏模量高达(9.36±1.68)MPa和(176±17.55)MPa,如0.4 mg BC气凝胶纤维可以支撑高于其本身质量5×10^4倍的重物. 相似文献
972.
Roger Hagen Lennart Salmn Bengt Stenberg 《Journal of Polymer Science.Polymer Physics》1996,34(12):1997-2006
The viscoelastic properties of various crosslinked natural rubbers, NR, were investigated by mechanical spectroscopy. The glass transition temperature, Tg, was found to be dependent on both the crosslink density and the crosslink type. Higher values of Tg were obtained for sulfur-crosslinked NR than for peroxide-crosslinked NR at the same crosslink density. The greater influence of the sulfur content on Tg may be attributed to polysulfidic crosslinks and cyclic sulfide structures favored at high sulfur contents. Sulfur-vulcanized NRs with monosulfidic crosslinks, favored at relatively high accelerator/sulfur ratios, have properties more similar to the peroxide-cured NR with simple carbon(SINGLE BOND)carbon crosslinks covalent bonds, resulting in only small shifts in Tg. A qualitative analysis of monosulfidic crosslinks and polysulfidic structures was performed with 13C solid-state NMR spectroscopy. The storage modulus, E′, in the rubbery plateau region increased with increasing crosslink density. However, the crosslink type did not influence the moduli values as much as it influenced the Tg values. Different methods of detecting the crosslink density were also discussed. © 1996 John Wiley & Sons, Inc. 相似文献
973.
Paul?LanganEmail author Narayanasami?Sukumar Yoshiharu?Nishiyama Henri?Chanzy 《Cellulose (London, England)》2005,12(6):551-562
Synchrotron X-ray data have been collected to 1.4 Å resolution at the NE-CAT beam-line at the Advanced Photon Source from fibers of cellulose Iβ and regenerated cellulose II (Fortisan) at ambient temperature and at 100 K in order to understand the effects of low temperature on cellulose more thoroughly. Crystal structures have been determined at each temperature. The unit cell of regenerated cellulose II contracted, with decreasing temperature, by 0.25%, 0.22% and 0.1% along the a, b, and c axes, respectively, whereas that of cellulose Iβ contracted only in the direction of the a axis, by 0.9%. The value of 4.6×10?5 K?1 for the thermal expansion coefficient of cellulose Iβ in the a axis direction can be explained by simple harmonic molecular oscillations and the lack of hydrogen-bonding in this direction. The molecular conformations of each allomorph are essential unchanged by cooling to 100 K. The room temperature crystal structure of regenerated cellulose II is essentially identical to the crystal structure of mercerized cellulose II. 相似文献
974.
Grafting polymer glycols onto nano-silica surface through one-step procedure was investigated. The major characteristic of this procedure is that all the materials and reagents (silica, PEG, TDI, DBTDL, solvent) required for grafting were added simultaneously into the reaction vessel. TDI and DBTDL were used as coupling agent and catalyst, respectively.The products were characterized by FTIR, TGA, elemental analyses and TEM, giving evidence for successful grafting of PEG. Possible mechanism of this grafting was studied and two grafting processes were proposed. The process through which the grafting proceeds depends on the reaction temperature. Effect of molecular weight of PEG on grafting was also investigated. 相似文献
975.
Introduction Recent years, chalcopyrite semiconductors have been successfully applied as absorber layers for polycrystalline thin-film solar cells. Among the ternary compound semiconductors, CuInS2 thin films with a direct bandgap of about 1.50 eV and a large absorption coefficient in the range of 104-105cm-1[1] are one kind of the most promising optical absorbers for high efficiency thin film solar cells.To date, CuInS2-based solar cells have shown conversion efficiency of about 12. 5%[2]. They exhibit long-term stability without any signs of degradation. 相似文献
976.
A new method for inductively coupled plasma atomic emission spectrometry (ICP-AES) determination of trace Sc and Y, based on gaseous compound introduction into the plasma as their thenoyltrifluoroacetone (TTA) complexes by electrothermal vaporization was developed. Using the reagent TTA as chemical modifier can not only enhance the analytical signals, but also reduce the vaporization temperature. At a temperature of 1,000 °C the trace Sc and Y can be vaporized completely into ICP. The factors affecting the formation of the chelate and its vaporization behavior, such as drying time, vaporization temperature/time, reaction medium and the amount of TTA, were investigated in detail. Under the optimized conditions (drying temperature/time 100 °C/10 s, vaporization temperature/time 1,000 °C/4 s), the limits of detection for Sc and Y were 19 pg and 34 pg (3), respectively, and the relative standard deviations for Sc and Y were 4.2% (c
Sc=0.2 g mL–1; n=7) and 2.6% (c
Y=0.5 g mL–1; n=7). The linear ranges of the calibration graphs cover three orders of magnitude. The method was applied to the analysis of the biological reference materials (GBW 07602, bush branches and leaves; GBW 07604, poplar leaves), and the results obtained were in good agreement with the certified values. 相似文献
977.
镧改性HL沸石在烃类催化裂化催化剂中的应用 总被引:5,自引:0,他引:5
采用离子交换和浸渍相结合的方法制备了La/HL沸石. 将不同La含量的La/HL沸石与REUSY沸石按不同比例复配后作为催化裂化催化剂的活性组分,用标准轻油微反方法(MAT)对催化剂样品进行了评价,考察了La/HL沸石添加量和La/HL沸石中的La含量对催化剂活性、反应产物分布、汽油产品辛烷值及催化剂上积炭的影响. 结果表明,在裂化催化剂中分子筛总量保持不变的条件下,当La/HL沸石加入量为催化剂总量的1%~5%时,随着La/HL沸石加入量的增加,MAT活性和汽油收率增大,比积炭下降; 当La/HL沸石加入量大于10%时,MAT活性及汽油收率随La/HL沸石加入量的增加而降低,比积炭增加. 当加入5%不同La含量的La/HL沸石时,产物中异丁烷含量增加; La/HL中的La含量低于3.5%时,产物异戊烷含量低于参比样品,但随着La含量的增加,异戊烷含量增大. 当La/HL沸石中的La含量为0.2%~0.5%时,汽油中的芳烃含量显著增加,汽油产品的辛烷值提高了1.24~2.06. 相似文献
978.
Proteins with molecular mass (M(r)) <20 kDa are often poorly separated in 2-D sodium dodecyl sulfate polyacrylamide gel electrophoresis. In addition, low-M(r) proteins may not be readily identified using peptide mass fingerprinting (PMF) owing to the small number of peptides generated in tryptic digestion. In this work, we used a 2-D liquid separation method based on chromatofocusing and non-porous silica reversed-phase high-performance liquid chromatography to purify proteins for matrix-assisted laser desorption/ionization time-of-flight mass spectrometric (MALDI-TOFMS) analysis and protein identification. Several proteins were identified using the PMF method where the result was supported using an accurate M(r) value obtained from electrospray ionization TOFMS. However, many proteins were not identified owing to an insufficient number of peptides observed in the MALDI-TOF experiments. The small number of peptides detected in MALDI-TOFMS can result from internal fragmentation, the few arginines in its sequence and incomplete tryptic digestion. MALDI-QTOFMS/MS can be used to identify many of these proteins. The accurate experimental M(r) and pI confirm identification and aid in identifying post-translational modifications such as truncations and acetylations. In some cases, high-quality MS/MS data obtained from the MALDI-QTOF spectrometer overcome preferential cleavages and result in protein identification. 相似文献
979.
The results detail a novel methodology for the electrochemical determination of ammonia based on its interaction with hydroquinone in DMF. It has been shown that ammonia reversibly removes protons from the hydroquinone molecules, thus facilitating the oxidative process with the emergence of a new wave at less positive potentials. The analytical utility of the proposed methodology has been examined with a linear range from 10 to 95 ppm and corresponding limit-of-detection of 4.2 ppm achievable. Finally, the response of hydroquinone in the presence of ammonia has been examined in the room temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluormethylsulfonyl)imide, [EMIM][N(Tf)2]. Analogous voltammetric waveshapes to that observed in DMF were obtained, thereby confirming the viability of the method in either DMF or [EMIM][N(Tf)2] as solvent. 相似文献
980.
The decay rate of vinyl unsaturation in high-density polyethylenes irradiated at temperatures from about 310 to 450 K, changes significantly in the melting range up to the crystalline melting point as does free radical mobility and the polymer crystallinity. However, orienting the polymer, or slow cooling or quenching from the melt, prior to irradiation, do not alter the decay process or its rate, although they do alter the rate of increase of insoluble gel and of elastic modulus in the molten state. It is suggested that, below 340 K, the marked deviations from a first-order decay result from the limited mobility of polymeric free radicals in the crystalline phase and from scavenging, by vinyl groups, segregated into the amorphous phase, of radiolytic hydrogen atoms (H). In the melting range, the mobility of polymeric free radicals increases as the crystallinity decreases, reducing the importance of scavenging, so vinyl decay approximates more closely to a first-order relation. In the melt, the vinyl decay relation is not changed qualitatively by H atom scavenging, but the effective vinyl concentration is lower, so the decay rate drops sharply. 相似文献