全文获取类型
收费全文 | 63190篇 |
免费 | 6809篇 |
国内免费 | 9449篇 |
专业分类
化学 | 37433篇 |
晶体学 | 1940篇 |
力学 | 4789篇 |
综合类 | 859篇 |
数学 | 16714篇 |
物理学 | 17713篇 |
出版年
2024年 | 110篇 |
2023年 | 529篇 |
2022年 | 1031篇 |
2021年 | 1206篇 |
2020年 | 1605篇 |
2019年 | 1527篇 |
2018年 | 1416篇 |
2017年 | 1770篇 |
2016年 | 2270篇 |
2015年 | 2078篇 |
2014年 | 2974篇 |
2013年 | 4360篇 |
2012年 | 4577篇 |
2011年 | 3746篇 |
2010年 | 3242篇 |
2009年 | 4021篇 |
2008年 | 4187篇 |
2007年 | 4363篇 |
2006年 | 3988篇 |
2005年 | 3760篇 |
2004年 | 3480篇 |
2003年 | 3026篇 |
2002年 | 3029篇 |
2001年 | 2160篇 |
2000年 | 2143篇 |
1999年 | 1784篇 |
1998年 | 1566篇 |
1997年 | 1354篇 |
1996年 | 1221篇 |
1995年 | 1056篇 |
1994年 | 952篇 |
1993年 | 726篇 |
1992年 | 702篇 |
1991年 | 462篇 |
1990年 | 421篇 |
1989年 | 315篇 |
1988年 | 301篇 |
1987年 | 229篇 |
1986年 | 202篇 |
1985年 | 224篇 |
1984年 | 185篇 |
1983年 | 134篇 |
1982年 | 154篇 |
1981年 | 140篇 |
1980年 | 113篇 |
1979年 | 112篇 |
1978年 | 92篇 |
1977年 | 84篇 |
1976年 | 74篇 |
1973年 | 74篇 |
排序方式: 共有10000条查询结果,搜索用时 249 毫秒
121.
Fei Chang Dongheng Zhang Haijian Yang Haibin Song 《Journal of organometallic chemistry》2004,689(5):936-946
The synthesized 1-aryliminomethylenylnaphthalen-2-ol derivatives reacted with nickel chloride to form bis(1-aryliminomethylenylnaphthalen-2-oxy)nickel complexes. All resultant compounds were structurally characterized by elemental analyses, IR and H NMR, and the structures of the formed complexes were elucidated by X-ray crystal structure analysis. The complexes show high catalytic activities for the vinyl polymerization of norbornene in the presence of methylaluminoxane. The catalytic activity variations have been followed by gas chromatography through monitoring the conversion of norbornene. 相似文献
122.
Andrey Pereverzev 《Foundations of Physics Letters》2003,16(5):411-428
We argue that it may be possible to consistently explain the quantum measurement by assuming that the wave function is in one-to-one correspondence with objective physical reality and has no probabilistic interpretation. In the context of such approach we consider the model of a harmonic oscillator linearly coupled to a heat bath and treat the oscillator as the system being measured. Three classes of initial pure states for the bath are considered. Exact expressions for the average values and variances of the oscillator coordinate and momentum as functions of time are considered for each class of pure states. It is shown that these quantities exhibit different asymptotic behavior for different classes of initial states of the bath. In particular, if each mode of the bath is initially in a coherent state, then for an arbitrary initial state of the oscillator the variances of the oscillator coordinate and momentum asymptotically approach the same values as for a coherent state of the free oscillator, while the averages of coordinate and momentum show a Brownian-like behavior. We argue that such behavior shows several features of the quantum measurement and supports our interpretation of the wave function. 相似文献
123.
A 2D HgII coordination polymer containing ligands 1,2,4‐triazole (Htrz) and thiocyanate, [Hg(μ3‐trz)(SCN)]n ( 1 ) has been synthesized and characterized by elemental analysis and IR spectroscopy. The single‐crystal X‐ray data show the coordination number of Hg atoms is four and the ligand trz? acts as a three‐fold donor. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses. The composition and formation of the complex in methanol solution were found to be in support of its solid state structure. 相似文献
124.
125.
The lattice profile analyzes the intrinsic structure of pseudorandom number sequences with applications in Monte Carlo methods and cryptology. In this paper, using the discrete Fourier transform for periodic sequences and the relation between the lattice profile and the linear complexity, we give general formulas for the expected value, variance, and counting function of the lattice profile of periodic sequences with fixed period. Moreover, we determine in a more explicit form the expected value, variance, and counting function of the lattice profile of periodic sequences for special values of the period. 相似文献
126.
The title compound (C2H7NO·C7H4N2O6) has been obtained by the reaction of etha- nolamine with 3,5-dinitrobenzoic acid in deionized water at room temperature. The crystal crystal- lizes in orthorhombic, space group P212121 with a = 6.048(2), b = 9.146(3), c = 21.955(7)(A), C9H11N3O7, Mr = 273.21, Z = 4, V = 1214.3(7)(A)3, Dc = 1.494 g/cm3, F(000) = 568, μ(MoKα) = 0.131 mm-1, R1 = 0.0338 and wR2 = 0.0497. The new organic adduct is composed of one ethanolamine and one 3,5-dinitrobenzoic acid, which are linked up by O-H…O and N-H…O types of hydrogen bonds to form a nine-membered ring and an eleven-membered ring, extending into a one-dimensional network structure. 相似文献
127.
128.
In this paper, we give the following dominated theorem: Let φ(g) ∈ L1(G//K),φε(t)=ε> 0, and the least radical decreasing dominatedfunction φ(t) = sup |φ(y)| ∈L1(G//K). If shtφ(t) is monotonically decreasingon (0, ∞), then for any f∈L1loc(G//K) , the following inequality holds:sup |φε * f(x)| ≤ Cmf(x),where mf(x) is the Hardy-Littlewood maximal function of f, and C = ||φ||1.An application of this dominated theorem is also given. 相似文献
129.
基于MATLAB的异步电动机线性化控制系统的仿真 总被引:1,自引:0,他引:1
从异步电动机在同步旋转坐标系下的状态方程出发,在一定的条件下,对其系数矩阵简化.推出异步电动机的线性化控制模型.并基于该模型得出异步电动机的线性化控制系统.以给定电机为例,对该模型的有效性、响应用MATLAB进行仿真分析.验证的结果说明上述模型具有实用价值. 相似文献
130.
Density functional method (DFT) (B3p86) of Gaussian98 has been used to optimize the structure of the Tc_2 molecule. The result shows that the ground state for Tc_2 molecule is an 11-multiple state and its electronic configuration is {}^{11}Σ_g^-, which shows the spin polarization effect of Tc_2 molecule of a transition metal element for the first time. Meanwhile, we have not found any spin pollution because the wavefunction of the ground state does not mingle with wavefunctions of higher energy states. So, that the ground state for Tc_2 molecule is an 11-multiple state is indicative of the spin polarization effect of Tc_2 molecule of a transition metal element: that is, there exist 10 parallel spin electrons. The non-conjugated electron is greatest in number. These electrons occupy different spacious tracks, so that the energy of Tc_2 molecule is minimized. It can be concluded that the effect of parallel spin of the Tc_2 molecule is larger than the effect of the conjugated molecule, which is obviously related to the effect of electron d delocalization. In addition, the Murrell--Sorbie potential functions with the parameters for the ground state {}^{11}Σ_g^- and other states of Tc_2 molecule are derived. Dissociation energy D_e for the ground state of T_{c2} molecule is 2.266eV, equilibrium bond length R_e is 0.2841nm, vibration frequency ω_e is 178.52cm^{-1}. Its force constants f_2, f_3, and f_4 are 0.9200aJ·nm^{-2}, --3.5700aJ·nm^{-3}, 11.2748aJ·nm^{-4} respectively. The other spectroscopic data for the ground state of Tc_2 molecule ω_eχ_e, B_e, α_e are 0.5523cm^{-1}, 0.0426cm^{-1}, 1.6331×10^{-4}cm^{-1} respectively. 相似文献