喷气燃料裂解产物中芳烃的全二维气相色谱-质谱分析

采用全二维气相色谱-质谱联用仪(GC×GC-MS),通过优化程序升温和调制周期,建立了喷气燃料裂解产物中芳烃的定性定量分析方法。该方法对多环芳烃(PAH)同分异构体具有良好的分离能力。利用MS检测器谱库检索结果、芳烃标准品及相关的文献报道,对喷气燃料裂解产物中常见的单环芳烃、二环芳烃、三环芳烃及四环芳烃等共27种芳烃进行了准确定性,并利用外标GC×GC-FID法对其进行定量。定量结果表明,芳烃含量均随着裂解产气率的增加而增大,当裂解产气率达到22%时,二环芳烃开始产生,且其含量随着裂解产气率的增加呈指数形式增加。该方法与传统的气相色谱-质谱相比,具有更好的分离及定性能力,可应用于复杂样品的分离及其定性定量分析。     

The low Reynolds number turbulent flow and mixing in a confined impinging jet reactor

Turbulent mixing takes an important role in chemical engineering, especially when the chemical reaction is fast compared to the mixing time. In this context a detailed knowledge of the flow field, the distribution of turbulent kinetic energy (TKE) and its dissipation rate is important, as these quantities are used for many mixing models. For this reason we conduct a direct numerical simulation (DNS) of a confined impinging jet reactor (CIJR) at Re = 500 and Sc = 1. The data is compared with particle image velocimetry (PIV) measurements and the basic flow features match between simulation and experiment. The DNS data is analysed and it is shown that the flow is dominated by a stable vortex in the main mixing duct. High intensities of turbulent kinetic energy and dissipation are found in the impingement zone which decrease rapidly towards the exit of the CIJR. In the whole CIJR the turbulence is not in equilibrium. The strong mixing in the impingement zone leads to a rapid development of a monomodal PDF. Due to the special properties of the flow field, a bimodal PDF is generated in cross-sections downstream the impingement zone, that slowly relaxes under relaminarising conditions. The time required for meso-mixing is dominating the overall mixing performance.     

Effect of acoustic disturbances on a free convective flow

A gas-dynamic flow in an axisymmetric convective jet is studied experimentally. It is demonstrated that the jet flow with Grashof numbers Gr = (0.4–2.0) · 10⁶ is self-similar. Acoustic oscillations directed perpendicular to the axis of symmetry transform the profiles of the gas-flow parameters; two temperature maximums located outside the axis can appear. The results obtained indicate that flow instability is generated in high-gradient regions. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 5, pp. 27–33, September–October, 2006.     

Head-flow and npsh performance of an axial piston pump working with organic fluids at different temperatures

A modified version of the standard axial piston pump, normally used with fuels, has been tested with organic fluids R11 and R113. Head-flow characteristics, volumetric and global efficiency, and npsh curves, have been determined at different speeds and fluid temperatures and the results compared with those obtained with kerosene. Pump efficiencies remain satisfactory with high density, very low viscosity and high vapour pressure fluids. In the absence of cavitation, pump performance seems to be a function of kinematic viscosity, while the npsh curves appear to be a complex function of density, viscosity and vapour pressure     

PLIF技术测量浓度场及其二维数字校正

推导了ＰＬＩＦ技术测量浓度场时液地内荧光强度的分布，提出了ＰＬＩＦ技术的二维数字校正方程和校正方法来消除激光片光的高斯分布和沿光程衰减的影响．在此基础上，对圆形紊动射流的浓度场进行了测量和校正．此外，还将测量结果与前人的半经验理论进行了分析和比较。     

粉喷桩单桩承载力确定方法的比较

粉喷桩在高速公路软土地基处理中得到了广泛的应用,但其承载力的合理确定是工程实际中关心的一个重要问题。通过对工程中常用的几种粉喷桩单桩承载力确定方法的比较,分析了各自存在的问题和适用条件,提出了在实际工程应用中确定水泥搅拌桩单桩承载力的选用建议。     

Effect of particle polydispersity on particle concentration measurement by using laser Doppler anemometry

Measurement of particle concentration by laser Doppler anemometry (LDA) is studied on a vertical air jet seeded by a powder disperser with controlled particle and air flow rates. Particle arrival rate is utilized to retrieve particle number densities from conventional LDA operation. The effect of polydisperse nature of the particles is assessed. Comparisons between measured and estimated particle number densities suggest that only a certain portion of the particle population with a particle size to fringe spacing ratio around unity can be detected. Results indicate that reliable measurement of absolute particle concentration is possible for a particle population of narrow size distribution with an average diameter equivalent to fringe spacing. Present number density measurement technique which is useful for practical purposes with conventional LDA systems is found to yield physically reasonable profiles in both laminar and turbulent regimes.     

Relationship between the recovery factor and the viscous dissipation in a confined, impinging, circular jet of high-Prandtl number liquid

The radial distribution of the recovery factor for a confined impinging jet of high-Prandtl number liquid is investigated by numerical approach with emphasis on its physical mechanism. The recovery factor is determined by the viscous dissipation and Prandtl number. Unlike the case of the gas jet impingement, the recovery factor in the region close to the stagnation point can be much larger than unity, while the recovery factor at the stagnation point approaches zero. The dependence of the recovery factor on the nozzle exit velocity profile, the jet Reynolds number, and the nozzle-to-plate spacing is examined.     

冲击高度对自由冲击射流影响的实验研究

采用热线风速仪测量了雷诺数为 ２３ ０００时四种冲击高度下率流自由冲击射流流场，并给出详细的结果．表明壁面的“阻尼”影响主要集中在近壁面０．５Ｄ以内．小冲击高度时径向速度下降得比大冲击高度时明显要快，量值也较小；在ｒ／Ｄ≤１．５处，小冲击高度时紊动能的数值大小和分布趋势与大冲击高度时不同，特别是在喷管出口距冲击板高度Ｚ与喷管直径Ｄ之比Ｚ／Ｄ为８时分布特殊，在其它测点处，紊动能的分布趋势基本一致，只是大冲击高度下的值较大；流动结构在Ｚ／Ｄ为６～８时发生了较大的变化，这种变化与势流核心区有关，在势流核心区的顶端以及下游的一段距离内紊流度都很高．