从微观角度分析电磁感应中的动生电动势和感应电流的形成及能量的转化

以“动电动模型”和“电动电模型”为例,从微观的角度出发,对感应电动势、感应电流的形成以及能量的转化进行分析,目的在于将宏观的认知和微观的内在本质统一起来,以期深入浅出地进行有效教学.     

A novel polythiophene – ionic liquid modified clay composite solid phase microextraction fiber: Preparation,characterization and application to pesticide analysis

This report comprises the novel usage of polythiophene – ionic liquid modified clay surfaces for solid phase microextraction (SPME) fiber production to improve the analysis of pesticides in fruit juice samples. Montmorillonite (Mmt) clay intercalated with ionic liquids (IL) was co-deposited with polythiophene (PTh) polymer coated electrochemically on an SPME fiber. The surface of the fibers were characterized by using scanning electron microscopy (SEM). Operational parameters effecting the extraction efficiency namely; the sample volume and pH, adsorption temperature and time, desorption temperature and time, stirring rate and salt amount were optimized. In order to reveal the major effects, these eight factors were selected and Plackett–Burman Design was constructed. The significant parameters detected; adsorption and temperature along with the stirring rate, were further investigated by Box–Behnken design. Under optimized conditions, calibration graphs were plotted and detection limits were calculated in the range of 0.002–0.667 ng mL⁻¹. Relative standard deviations were no higher than 18%. Overall results have indicated that this novel PTh-IL-Mmt SPME surface developed by the aid of electrochemical deposition could offer a selective and sensitive head space analysis for the selected pesticide residues.     

One‐step synthesis of polymer micro‐tubes tethered by polymer nanowire networks via RAFT polymerization of N,N′‐methylene bisacrylamide xerogel fibers in toluene and ethanol mixed solution

In the mixed solution of toluene and ethanol, polymer micro‐tubes (PMTs) tethered by polymer nanowire networks (PTPWNs) were fabricated facilely via one‐step reversible addition fragmentation chain transfer (RAFT) polymerization by taking N,N′‐methylene bisacrylamide (MBA) xerogel fibers as both template and monomer source. The products were analyzed by FTIR, SEM, TEM, surface area and porosity analyzer, and contact angle tester. The results indicated that PTPWNs were obtained as the sole product at ethanol content of 1.0 wt %. As the content of ethanol increases from 0 to 1.0 wt %, the specific surface area of the products became higher, indicating more polymer nanowire networks (PWNs) on the tubes. At ethanol contents of 1.5 wt % and 2.0 wt %, some particles were also obtained besides PTPWNs. The formation process of PTPWNs was studied by analyzing the products obtained at different reaction time. The results revealed that PTPWNs were formed by two steps, PMTs were formed quickly and then PWNs formed in the solution tethered to the tubes. Moreover, the effect of RAFT agent on the morphologies of the products revealed that PTPWNs could be obtained via RAFT polymerization at suitable dosage of RAFT agent, while polymer particles were generated via conventional free radical polymerization. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1862–1868     

微观数据和宏观汇总数据在统计分析上的差异——以C-D生产函数为例

基于2008年经济普查的数据,从描述统计分析和回归分析两方面分别对微观数据和宏观汇总数据在统计分析上的差异进行了实证分析.在描述统计分析中发现,宏观汇总数据比微观数据更接近正态分布,但对数化处理后的数据并非如此;在回归分析中发现,基于微观数据和宏观汇总数据估计的生产函数,在消除异方差和多重共线性之前,无论是在生产函数的规模效应、生产要素的贡献率以及生产要素对产出的解释力度上均存在着差异,但是在消除异方差和多重共线性之后,在要素对产出的解释力度上仍存在很大差异.     

教育“微理念”对物理教育的影响

当今社会,在很多行业都有"微现象"的存在,这不是一个偶然事件,这种现象反映了当代生活方式与思维方式的变革.这种"微现象"同样给教育领域带来了影响,在教育界构筑起了一种新的意识潮流——"教育‘微理念’".究其根本,教育领域的"微理念"是一种形式与意识同时革新的教学方向,它为今后教育事业的发展指导了一条力所能及的、勇往直前的道路.     

Fast solvers for models of ICEO microfluidic flows

We demonstrate the performance of a fast computational algorithm for modeling the design of a microfluidic mixing device. The device uses an electrokinetic process, induced charge electroosmosis (J. Fluid Mech. 2004; 509 ), by which a flow through the device is driven by a set of polarizable obstacles in it. Its design is realized by manipulating the shape and orientation of the obstacles in order to maximize the amount of fluid mixing within the device. The computation entails the solution of a constrained optimization problem in which function evaluations require the numerical solution of a set of partial differential equations: a potential equation, the incompressible Navier–Stokes equations, and a mass‐transport equation. The most expensive component of the function evaluation (which must be performed at every step of an iteration for the optimization) is the solution of the Navier–Stokes equations. We show that by using some new robust algorithms for this task (SIAM J. Sci. Comput. 2002; 24 :237–256; J. Comput. Appl. Math. 2001; 128 :261–279), based on certain preconditioners that take advantage of the structure of the linearized problem, this computation can be done efficiently. Using this computational strategy, in conjunction with a derivative‐free pattern search algorithm for the optimization, applied to a finite element discretization of the problem, we are able to determine optimal configurations of microfluidic devices. Copyright © 2009 John Wiley & Sons, Ltd.     

Electron Moiré method

It is very important to measure local deformations for an in-depth understanding of mechanical properties and fracture mechanism of structural and functional materials. In this paper, different types of model grid fabrication methods and many types of electron Moiré methods using an electron beam drawing system, a scanning electron microscope or a focus ion beam are reported, together with their applications in the measurement of deformations occurring in various engineerings and materials science research.     

Determination of Zinc(II) by the Reactivation of the Apoenzymes of Alkaline Phosphatases from Diverse Sources

ABSTRACT

A sensitive and selective method for the determination of Zn(II) based on the reactivation of the apoenzymes of alkaline phosphatases from diverse sources: chicken intestine, seal slim intestine and Escherichia coli, has been developed. To obtain the apoenzymes, EDTA was selected as an effective inhibitor of alkaline phosphatases. In the presence of EDTA excess in the solution, the pseudo apoenzymes were obtained. Dialysis of the enzymes against the chelating agent resulted in obtaining inactive zinc-free apo-phosphatases (true apoenzymes). The reactivation of the pseudo- and true apoenzymes of alkaline phosphatases from various sources by zinc(II) was applied for its determination. The proposed procedures are highly sensitive (limit detection of Zn(II) = 0.3-0.4 ng ml^?1), selective (no other metals reactivate the apophosphatases from seal slim intestine and Escherichia coli), accurate, simple and rapid. The schemes of the mechanism of the reactivation effects are discussed.     

外加场分离技术与微流控技术联用在微纳尺度物质分离中的研究进展

微纳尺度物质的分离和分选在精准医学、材料科学和单细胞分析等研究中至关重要。精准、高效和快速的分离微纳尺度物质能够为癌症的早期诊断、生物样品检测和细胞筛选提供重要帮助,其中基于外加场分离技术的分离微纳尺度物质因可以对微纳尺度物质高效在线分离和分选,被广泛应用于微纳米颗粒、外泌体以及生物细胞的分离工作中,而目前多数外加场分离技术存在装备繁琐和样品消耗大等问题。微流控技术是一种通过制作微通道和微流控芯片操纵微小流体对微纳尺度样品组分进行分离的技术,因具有快速检测、高通量、在线分离、集成性高、成本低等优势现被应用于微纳尺度物质分离分析中,是一种微纳尺度物质分离的有效方法,通过在微流控芯片上设计不同的通道及外部配件提高主动场对微纳尺度物质分离效率。外加场分离技术与微流控技术联用可以实现微纳尺度物质的无损、高效、在线分离。该综述主要概述了近年来在微流控芯片上依托流动场、电场、磁场及声场等外加场分离技术来提高对微纳尺度物质分离效率的研究现状,并将各个外力场对单细胞、微颗粒等微纳尺度物质的分离进行分类介绍,总结各自的优缺点及发展应用,最后展望了外加场分离技术与微流控技术联用在应用于癌细胞的早期筛查、精确分离微尺度物质领域的未来发展前景,并提出联用技术的优势和未来应用等。