全文获取类型
收费全文 | 925篇 |
免费 | 130篇 |
国内免费 | 143篇 |
专业分类
化学 | 531篇 |
晶体学 | 25篇 |
力学 | 178篇 |
综合类 | 7篇 |
数学 | 17篇 |
物理学 | 440篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 39篇 |
2021年 | 26篇 |
2020年 | 32篇 |
2019年 | 30篇 |
2018年 | 36篇 |
2017年 | 47篇 |
2016年 | 69篇 |
2015年 | 61篇 |
2014年 | 46篇 |
2013年 | 83篇 |
2012年 | 69篇 |
2011年 | 58篇 |
2010年 | 45篇 |
2009年 | 69篇 |
2008年 | 41篇 |
2007年 | 61篇 |
2006年 | 48篇 |
2005年 | 36篇 |
2004年 | 50篇 |
2003年 | 30篇 |
2002年 | 33篇 |
2001年 | 43篇 |
2000年 | 21篇 |
1999年 | 22篇 |
1998年 | 20篇 |
1997年 | 20篇 |
1996年 | 14篇 |
1995年 | 10篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1971年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有1198条查询结果,搜索用时 46 毫秒
151.
152.
Z. Buczolich 《Acta Mathematica Hungarica》2008,121(4):371-393
One can define in a natural way irregular 1-sets on the graphs of several fractal functions, like Takagi’s function, Weierstrass-Cellerier type functions and the typical continuous function. These irregular 1-sets can be useful during the investigation of level-sets and occupation measures of these functions. For example, we see that for Takagi’s function and for certain Weierstrass-Cellerier functions the occupation measure is singular with respect to the Lebesgue measure and for almost every level the level set is finite. 相似文献
153.
Rapid analysis of six trace trichlorophenols in seawater by magnetic micro‐solid‐phase extraction and liquid chromatography with tandem mass spectrometry 下载免费PDF全文
Mei‐Lan Chen Jian‐Qing Min Mei‐Qiang Cai Sheng‐Dong Pan Mi‐Cong Jin 《Journal of separation science》2016,39(12):2396-2405
A new facile, rapid, inexpensive, and sensitive method for the analysis of six trace trichlorophenols in seawater samples was developed by magnetic micro‐solid‐phase extraction coupled to liquid chromatography with tandem mass spectrometry. Core–shell covalently functionalized ferroferric oxide coated with aminated silicon dioxide and decorated with multiwalled carbon nanotubes was applied as an adsorbent to perform the extraction process. The effect of factors including solution pH, contact time, adsorbent amount, and ionic strength were investigated in detail. The obtained results revealed that the proposed adsorbent was a highly effective and low‐cost magnetic micro‐solid‐phase extraction material for the enrichment of 2,3,4‐trichlorophenol, 2,3,5‐trichlorophenol, 2,3,6‐trichlorophenol, 2,4,5‐trichlorophenol, 2,4,6‐trichlorophenol, and 3,4,5‐trichlorophenol from seawater. Under the optimized conditions, the recoveries ranged from 88.0 to 99.5% at the three spiking levels, the limits of detection and the limits of quantification were 0.002 and 0.007 μg/L for the six trichlorophenols, respectively. The intra‐ and interday relative standard deviations were 2.0–6.7 and 4.5–8.9%, respectively. The calibration curves showed a good linearity in the range of 0.02–5.0 μg/L. The routine run analyses showed that the developed method was fast, simple, accurate, solvent‐saving and high resolution, and it was suitable for the determination of trace trichlorophenols in seawater. 相似文献
154.
Computational design and fabrication of core–shell magnetic molecularly imprinted polymer for dispersive micro‐solid‐phase extraction coupled with high‐performance liquid chromatography for the determination of rhodamine 6G 下载免费PDF全文
Jin Xie Jie Xie Jian Deng Xiangfang Fang Haiqing Zhao Duo Qian Hongjuan Wang 《Journal of separation science》2016,39(12):2422-2430
A novel core–shell magnetic nano‐adsorbent with surface molecularly imprinted polymer coating was fabricated and then applied to dispersive micro‐solid‐phase extraction followed by determination of rhodamine 6G using high‐performance liquid chromatography. The molecularly imprinted polymer coating was prepared by copolymerization of dopamine and m‐aminophenylboronic acid (functional monomers), in the presence of rhodamine 6G (template). The selection of the suitable functional monomers was based on the interaction between different monomers and the template using the density functional theory. The ratios of the monomers to template were further optimized by an OA9 (34) orthogonal array design. The binding performances of the adsorbent were evaluated by static, kinetic, and selective adsorption experiments. The results reveal that the adsorbent possesses remarkable affinity and binding specificity for rhodamine 6G because of the enhanced Lewis acid‐base interaction between the B(Ш) embedded in the imprinted cavities and the template. The nano‐adsorbent was successfully applied to dispersive micro‐solid‐phase extraction coupled to high‐performance liquid chromatography for the trace determination of rhodamine 6G in samples with a detection limit of 2.7 nmol/L. Spiked recoveries ranged from 93.0–99.1, 89.5–92.7, and 86.9–105% in river water, matrimony vine and paprika samples, respectively, with relative standard deviations of less than 4.3%. 相似文献
155.
A two-step sample preparation technique based on dispersive micro solid-phase extraction combined with coacervative microextraction is presented for preconcentration and determination of tricyclic antidepressant drugs in biological samples. An important feature of the method is the application of hydrophobic magnetic nanoparticles, which in combination with coacervative microextraction method enables development of rapid and efficient extraction procedure in order to achievement of a high extraction efficiency. Simultaneous optimization by experimental design lead to improvement of method with low cost which supply useful information about interaction among variables. Under the optimized conditions, a linear range of 5–1000 ng mL−1 with detection limits from 0.51 to 1.4 ng mL−1 were obtained for target analytes. The method was successfully used for the determination of analytes in biological fluids (plasma and urine) with relative recoveries in the range of 89–105% (RSDs < 3.5%). 相似文献
156.
In this study, ultrasound assisted dispersive solid-phase micro extraction combined with spectrophotometry (USA-DSPME-UV) method based on activated carbon modified with Fe2O3 nanoparticles (Fe2O3-NPs-AC) was developed for pre-concentration and determination of safranin O (SO). It is known that the efficiency of USA-DSPME-UV method may be affected by pH, amount of adsorbent, ultrasound time and eluent volume and the extent and magnitude of their contribution on response (in term of main and interaction part) was studied by using central composite design (CCD) and artificial neural network-genetic algorithms (ANN-GA). Accordingly by adjustment of experimental conditions suggested by ANN-GA at pH 6.5, 1.1 mg of adsorbent, 10 min ultrasound and 150 μL of eluent volume led to achievement of best operation performance like low LOD (6.3 ng mL−1) and LOQ (17.5 ng mL−1) in the range of 25–3500 ng mL−1. In following stage, the SO content in real water and wastewater samples with recoveries between 93.27–99.41% with RSD lower than 3% was successfully determined. 相似文献
157.
An analytical method combining off-line flow-through extraction of a soil micro-sample (mass around 100 mg, packed into a short HPLC glass column) and direct on-column large-volume injection (LVI up to 1.00 mL) of a methanol-water soil extract onto a conventional C18 RP HPLC column enabled fast (within 3.5 minutes) trace micro-analysis of the relatively new chiral pesticides epoxiconazole (E) and novaluron (N), respectively. Linear calibration curves were evaluated from UV detection (230 nm) data in the range from 0.1 to 5 mg/kg in three most abundant Slovak agricultural soils. LOD (confidence band) at the levels 0.08-0.11 mg/kg and LOQ 0.4-0.6 mg/kg and LOD (S/N = 3) at the levels 0.007-0.018 mg/kg and LOQ (S/N = 10) 0.024-0.060 mg/kg, respectively, of dry soil were achieved. Recovery of pesticides in the overall LVI method including flow-through 130-200 mg soil micro-sample extraction was: for epoxiconazole from 74 to 85% and from 56% to 90% for novaluron with reproducibility within +/- 6% RSD. This fast (30 min) and simple method consists of just three steps which are short column filling with a solid micro-sample; flow-through liquid extraction and direct large-volume injection RP HPLC DAD analysis. The method is prepared for automation and further analysis of enantiomers of both investigated pesticides by achiral-chiral column switching techniques. 相似文献
158.
A synthesized graft polymer is used as a biodegradable polymer for an in situ gel-forming injectable implant system. The amphiphilic character of the polymer in the graft structure lowered the viscosity of the polymer solution, which enabled easy injection. A micro-sized gel can be obtained with this system, which has not been found for previous in situ gel-forming systems with poly[(D,L-lactide)-co-glycolide] copolymer. In addition, a protein particle embedded gel exhibits good in vitro drug release performance as a result of the enhanced stability and shorter diffusion length. 相似文献
159.
This paper describes the formation of patterned cell co-cultures using the layer-by-layer deposition of synthetic ionic polymers and without the aid of adhesive proteins/ligands such as collagen or fibronectin. In this study, we used synthetic polymers, namely poly(diallyldimethylammonium chloride) (PDAC) and sulfonated polystyrene (SPS) as the polycation and polyanion, respectively, to build the multilayer films. We formed SPS patterns on polyelectrolyte multilayer (PEM) surfaces either by microcontact printing PDAC onto SPS surfaces or vice-versa. To create patterned co-cultures on PEMs, we capitalize on the preferential attachment and spreading of primary hepatocytes on SPS as opposed to PDAC surfaces. In contrast, fibroblasts readily attached to both PDAC and SPS surfaces, and as a result, we were able to obtain patterned co-cultures of fibroblast and primary hepatocytes on synthetic PEM surfaces. We characterized the morphology and hepatic-specific functions of the patterned cell co-cultures with microscopy and biochemical assays. Our results suggest an alternative approach to fabricating controlled co-cultures with specified cell-cell and cell-surface interactions; this approach provides flexibility in designing cell-specific surfaces for tissue engineering applications. 相似文献
160.