全文获取类型
收费全文 | 23573篇 |
免费 | 4699篇 |
国内免费 | 2514篇 |
专业分类
化学 | 12757篇 |
晶体学 | 490篇 |
力学 | 2315篇 |
综合类 | 282篇 |
数学 | 833篇 |
物理学 | 14109篇 |
出版年
2024年 | 39篇 |
2023年 | 148篇 |
2022年 | 562篇 |
2021年 | 639篇 |
2020年 | 756篇 |
2019年 | 701篇 |
2018年 | 740篇 |
2017年 | 1033篇 |
2016年 | 1159篇 |
2015年 | 1009篇 |
2014年 | 1364篇 |
2013年 | 2144篇 |
2012年 | 1646篇 |
2011年 | 1572篇 |
2010年 | 1309篇 |
2009年 | 1398篇 |
2008年 | 1387篇 |
2007年 | 1483篇 |
2006年 | 1337篇 |
2005年 | 1174篇 |
2004年 | 1131篇 |
2003年 | 976篇 |
2002年 | 896篇 |
2001年 | 837篇 |
2000年 | 780篇 |
1999年 | 689篇 |
1998年 | 568篇 |
1997年 | 523篇 |
1996年 | 456篇 |
1995年 | 380篇 |
1994年 | 326篇 |
1993年 | 286篇 |
1992年 | 235篇 |
1991年 | 166篇 |
1990年 | 143篇 |
1989年 | 135篇 |
1988年 | 141篇 |
1987年 | 94篇 |
1986年 | 71篇 |
1985年 | 56篇 |
1984年 | 47篇 |
1983年 | 26篇 |
1982年 | 54篇 |
1981年 | 42篇 |
1980年 | 20篇 |
1979年 | 34篇 |
1978年 | 18篇 |
1977年 | 14篇 |
1976年 | 10篇 |
1974年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
941.
表面结构是影响固体材料物理和化学性质的重要因素,由于高表面能的晶面上存在更多的表面悬挂键等,高表面能晶面裸露的微纳米晶体一般表现出很好的物理和化学活性.近年来,科研工作者针对高能面微纳米晶体材料的制备及性能调控进行了大量的研究工作并取得了一定的进展.本文重点讨论了高能面裸露的金属氧化物半导体微纳米晶体的合成制备方法.主要以本课题组近年在该领域的研究为例,分别从晶体生长过程中的静电作用法、“帽”式试剂保护法、过饱和度调控法、动力学调控法及选择性化学刻蚀法等几个方面对高表面能晶面裸露的金属氧化物微纳米晶体的制备进行了系统的总结. 相似文献
942.
M.C. Menet C.H. Cottart M. Taghi V. Nivet-Antoine D. Dargère F. Vibert O. Laprévote J.-L. Beaudeux 《Analytica chimica acta》2013
Resveratrol is a polyphenol that has numerous interesting biological properties, but, per os, it is quickly metabolized. Some of its metabolites are more concentrated than resveratrol, may have greater biological activities, and may act as a kind of store for resveratrol. Thus, to understand the biological impact of resveratrol on a physiological system, it is crucial to simultaneously analyze resveratrol and its metabolites in plasma. This study presents an analytical method based on UHPLC-Q-TOF mass spectrometry for the quantification of resveratrol and of its most common hydrophilic metabolites. The use of 13C- and D-labeled standards specific to each molecule led to a linear calibration curve on a larger concentration range than described previously. The use of high resolution mass spectrometry in the full scan mode enabled simultaneous identification and quantification of some hydrophilic metabolites not previously described in mice. In addition, UHPLC separation, allowing run times lower than 10 min, can be used in studies that requiring analysis of many samples. 相似文献
943.
Antonio Calvo-López Eva Arasa-Puig Mar Puyol Joan Manel Casalta Julián Alonso-Chamarro 《Analytica chimica acta》2013
The construction and evaluation of a Low Temperature Co-fired Ceramics (LTCC)-based continuous flow potentiometric microanalyzer prototype to simultaneously monitor the presence of two ions (potassium and nitrate) in samples from the water recycling process for future manned space missions is presented. The microsystem integrates microfluidics and the detection system in a single substrate and it is smaller than a credit card. The detection system is based on two ion-selective electrodes (ISEs), which are built using all-solid state nitrate and potassium polymeric membranes, and a screen-printed Ag/AgCl reference electrode. The obtained analytical features after the optimization of the microfluidic design and hydrodynamics are a linear range from 10 to 1000 mg L−1 and from 1.9 to 155 mg L−1 and a detection limit of 9.56 mg L−1 and 0.81 mg L−1 for nitrate and potassium ions respectively. 相似文献
944.
Praneshwar Sethupathy Inas M. Alnashef John R. Monnier Michael A. Matthews John W. Weidner 《合成通讯》2013,43(24):3632-3647
Abstract We show that the superoxide ion (O2 ??) generated electrochemically from oxygen dissolved in room-temperature ionic liquids (RTILs) reacts with primary and secondary alcohols to form the corresponding ketones and carboxylic acids, respectively. Specifically, we study the conversion of benzhydrol to benzophenone and benzyl alcohol to benzaldehyde/benzoic acid. The kinetics (e.g., rate, selectivity, and yield) for these reactions are also determined as functions of the variations in the structure of the ionic liquids. The RTILs used here are imidazolium-based cations where the functional groups on the imidazolium ring are modified. Specifically, 1-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6], 1-butyl-2,3-dimethylimidazolium hexafluorophosphate [bdmim][PF6], and 1-hexyl-3-methylimidazolium hexafluorophosphate [hmim][PF6] are used as the reaction medium. These results are compared to an ammonium-based RTIL (N-butyl-N-trimethylammonium bis(trifluoromethylsulfonyl)imide). The results show that the nucleophilic attack by the O2 ?? of both the RTIL and the alcohol, especially that of the H atom at the R2 position of the [bmim][PF6] and [hmim][PF6], greatly affects the yields. No RTIL degradation products were detected for the reactions in [bdmim][PF6] and N-butyl-N-trimethylammonium bis(trifluoromethylsulfonyl)imide ionic liquids. For the benzyl alcohol oxidation reaction in the RTIL, N-butyl-N-trimethylammonium bis(trifluoromethylsulfonyl)imide, benzaldehyde formed did not undergo further oxidation to form benzoic acid, which may be due to the greater hydrophobicity of this RTIL. The competitive reaction kinetics between the alcohol and RTIL component must be considered in the selection of the RTIL solvent system. 相似文献
945.
The π–π interactions between CO2 and three aromatic molecules, namely benzene (C6H6), pyridine (C5H5N), and pyrrole (C4H5N), which represent common functional groups in metal‐organic/zeoliticimidazolate framework materials, were characterized using high‐level ab initio methods. The coupled‐cluster with single and double excitations and perturbative treatment of triple excitations (CCSD(T)) method with a complete basis set (CBS) was used to calibrate Hartree–Fock, density functional theory, and second‐order M?ller–Plesset (MP2) with resolution of the identity approximation calculations. Results at the MP2/def2‐QZVPP level showed the smallest deviations (only about 1 kJ/mol) compared with those at the CCSD(T)/CBS level of theory. The strength of π–π binding energies (BEs) followed the order C4H5N > C6H6 ~ C5H5N and was roughly correlated with the aromaticity and the charge transfer between CO2 and aromatic molecule in clusters. Compared with hydrogen‐bond or electron donor–acceptor interactions observed during BE calculations at the MP2/def2‐QZVPP level of theory, π–π interactions significantly contribute to the total interactions between CO2 and aromatic molecules. © 2013 Wiley Periodicals, Inc. 相似文献
946.
Abstract SO4 2?/SnO2 was employed for the acylation of a variety of alcohols, phenols, and amines under solvent‐free conditions at room temperature. This method showed preferential selectivity for acetylation of the amino group in the presence of a hydroxyl group. The reported method is simple, mild, and environmentally viable, using several other acid anhydrides at room temperature. 相似文献
947.
Wei Chang Lijuan Liu Jin Zhang Qiwei Pan 《Journal of Dispersion Science and Technology》2013,34(5):639-642
A kind of emulsifier-free latex (FL) was successfully synthesized from styrene (St) and butyl acrylate (BA) with 2-acrylamido-2-methyl propane sulfonic acid (AMPS) as a reactive emulsifier. The particle size of latex particles, stability against electrolytes, minimum film forming temperature (MFT) and water contact angle (CA) were evaluated and compared with a conventional latex (CL). Test results show that FL has larger particle size, better stability against electrolytes and lower MFT value compared with CL; higher AMPS content leads to smaller particle size and smaller water CA. 相似文献
948.
Sally R. Ellingson Jeremy C. Smith Jerome Baudry 《Journal of computational chemistry》2013,34(25):2212-2221
The program VinaMPI has been developed to enable massively large virtual drug screens on leadership‐class computing resources, using a large number of cores to decrease the time‐to‐completion of the screen. VinaMPI is a massively parallel Message Passing Interface (MPI) program based on the multithreaded virtual docking program AutodockVina, and is used to distribute tasks while multithreading is used to speed‐up individual docking tasks. VinaMPI uses a distribution scheme in which tasks are evenly distributed to the workers based on the complexity of each task, as defined by the number of rotatable bonds in each chemical compound investigated. VinaMPI efficiently handles multiple proteins in a ligand screen, allowing for high‐throughput inverse docking that presents new opportunities for improving the efficiency of the drug discovery pipeline. VinaMPI successfully ran on 84,672 cores with a continual decrease in job completion time with increasing core count. The ratio of the number of tasks in a screening to the number of workers should be at least around 100 in order to have a good load balance and an optimal job completion time. The code is freely available and downloadable. Instructions for downloading and using the code are provided in the Supporting Information. © 2013 Wiley Periodicals, Inc. 相似文献
949.
Masashi Daido Yukio Kawashima Masanori Tachikawa 《Journal of computational chemistry》2013,34(28):2403-2411
The structure of Watson–Crick‐type adenine‐thymine and guanine‐cytosine pairs has been studied by hybrid Monte Carlo (HMC) and path integral hybrid Monte Carlo (PIHMC) simulations with the use of semiempirical PM6‐DH+ method in the gas phase. We elucidated the nuclear quantum effect and temperature dependency on the hydrogen‐bonded moiety of base pairs. It was shown that the contribution of nuclear quantum effect on the hydrogen‐bonded structure is significant not only at low temperature 150 K but also at temperature as high as 450 K. The relative position of hydrogen‐bonded proton between two heavy atoms and the nuclear quantum nature of the proton are also shown. Furthermore, we have applied principal component analysis to HMC and PIHMC simulations to analyze the nuclear quantum effect on intermolecular motions. We found that the ratio of Buckle mode (lowest vibrational mode from normal mode analysis) decreases due to the nuclear quantum effect, whereas that of Propeller mode (second lowest vibrational mode) increases. In addition, nonplanar structures of base pairs were found to become stable due to the nuclear quantum effect from two‐dimensional free energy landscape along Buckle and Propeller modes. © 2013 Wiley Periodicals, Inc. 相似文献
950.
You Wei 《Journal of Dispersion Science and Technology》2013,34(12):1785-1794