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991.
ThehydrogenatomtransferreactionNH H-N H,isanimportantreactioninradicalreactionsandthegas-phrasethermatdecompositionofammonia.Therewereseveralstudiesonthisreactioninexperiment]andtheory='3.Inthispaper,wehaveemployedtheunifiedstatisticaltheory'(UST)tos... 相似文献
992.
993.
M. M. A. Imran D. Bhandari N. S. Saxena 《Journal of Thermal Analysis and Calorimetry》2001,65(1):257-274
Results of phase transformations, enthalpy released and specific heat of Ge22Se78–xBix(x=0, 4 and 8) chalcogenide glasses, using differential scanning calorimetry (DSC), under non-isothermal condition have been reported and discussed. The glass transition temperature, T
g, is found to increase with an average coordination number and heating rates. Following Gibbs—Dimarzio equation, the calculated values of T
g (i.e. 462.7, 469.7 and 484.4 K) and the experimental values (i.e. 463.1, 467.3 and 484.5 K) increase with Bi concentration. Both values of T
g, at a heating rate of 5 K min–1, are found to be in good agreement. The glass transition activation energy increases i.e. 102±2, 109±3 and 115±8 kJ mol–1 with Bi concentration. The demand for thermal stability has been ensured through the temperature difference T
c–T
g and the enthalpy released during the crystallization process. Below T
g, specific heat has been observed to be temperature independent but highly compositional dependent. The growth kinetic has been investigated using the Kissinger, Ozawa, Matusita and modified JMA equations. Results indicate that the crystallization ability is enhanced, the activation energy of crystallization increases with increasing the Bi content and the crystal growth of these glasses occur in 3 dimensions.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
994.
湖北网湖^137Cs、^210Pb计年与沉积速率研究 总被引:2,自引:0,他引:2
采用放射性核素^137Cs和^210Pb计年法测定百年来湖北网湖沉积物的年代,据此计算出网湖的沉积速率.结果表明:2种计年方法测得的沉积速率基本一致,以1954年和1963年为时标,^137Cs测得的沉积速率分别为0.594cm·a^-1和0.557cm·a^-1。^210Pb计年法CIC模式计算得到网湖平均沉积速率为0.56cm·a^-1.CRS模式得到百年来网湖沉积速率变化较大,20世纪50年代以前,平均沉积速率为0.2cm·a^-1左右;50年代至80年代中期,平均沉积速率上了一个台阶,约为0.4cm·a^-1;80年代中期以后平均沉积速率攀升至约0.6cm·a^-1,网湖沉积速率变化与湖区自然环境的改变和人类活动的影响密切相关. 相似文献
995.
Rouhollah Gheisari 《International journal of quantum chemistry》2009,109(5):1070-1073
Several resonances in the molecular spectrum of the exotic dtμ* ion are obtained. We present a theoretical formulation for its energy levels together with the numerical calculations for the nuclear fusion rates. The calculations are performed with the coupled rearrangement channel method, but with a set of functions alternative to others. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2009 相似文献
996.
索赔次数为复合Poisson-Geometric过程的常利率风险模型的罚金函数 总被引:3,自引:0,他引:3
讨论了常利率下索赔次数为复合Poisson-Geometric过程的风险模型的罚金函数,得到了罚金函数的期望所满足的积分方程,并由所得到的积分方程推出了破产概率所满足的积分方程,初始盈余为0时,得到了罚金函数的期望及破产概率的精确解. 相似文献
997.
Sieck L. Wayne Heron John T. Green David S. 《Plasma Chemistry and Plasma Processing》2000,20(2):235-258
Reliable kinetic and thermodynamic data are required to model the evolution of electric discharge or electron-beam decomposition chemistry of gases in humid air streams. In this first segment of a continuing series, we provide a core database describing the initially dominant ion-neutral molecule reactions in humid air plasmas. Recommended reaction rate data and extrapolation tools are presented in a manner to facilitate prediction of reactivities and reaction channels as a function of temperature, pressure, and applied electric field. 相似文献
998.
During the past several years infrared thermography has evolved into a powerful investigative means of thermo-fluid-dynamic analysis to measure convective heat fluxes as well as to investigate the surface flow field behaviour over complicated body shapes. The basic concepts that govern this innovative measurement technique together with some particular aspects linked to its use are herein reviewed. Different operating methods together with their implementations are also discussed. Finally, the capability of infrared thermography to deal with several simple, or complex, fluid flow configurations is analysed. 相似文献
999.
Seema Thakral A. K. Madan 《Journal of inclusion phenomena and macrocyclic chemistry》2008,60(3-4):203-209
In the present study, urea, a well-known adductor for linear compounds was successfully utilized for inclusion of glipizide—a
highly substituted cyclic organic compound through a modified technique. Formation of glipizide co-inclusion compounds in
urea was confirmed by FTIR, DSC and XRD. The minimum proportion of rapidly adductible endocyte (RAE) required for adduction
of glipizide in urea was estimated by a modified Zimmerschied calorimetric method. Urea–GLP–RAE inclusion compounds containing
varying proportions of guests were prepared and their thermal behaviour studied by DSC. The co-inclusion compounds were found
to exhibit good content uniformity. Through the formation of co-inclusion compounds of urea, it was possible to achieve steep
improvement in the dissolution efficiency of glipizide, which is a BCS class II drug. 相似文献
1000.
Ting Cheng 《Journal of Differential Equations》2008,244(4):766-802
The blow-up rate estimate for the solution to a semilinear parabolic equation ut=Δu+V(x)|u|p−1u in Ω×(0,T) with 0-Dirichlet boundary condition is obtained. As an application, it is shown that the asymptotic behavior of blow-up time and blow-up set of the problem with nonnegative initial data u(x,0)=Mφ(x) as M goes to infinity, which have been found in [C. Cortazar, M. Elgueta, J.D. Rossi, The blow-up problem for a semilinear parabolic equation with a potential, preprint, arXiv: math.AP/0607055, July 2006], is improved under some reasonable and weaker conditions compared with [C. Cortazar, M. Elgueta, J.D. Rossi, The blow-up problem for a semilinear parabolic equation with a potential, preprint, arXiv: math.AP/0607055, July 2006]. 相似文献