银微电极微分电位溶出分析法研究

本文首次报道了银微电极微分电位溶出分析法。用化学刻蚀法方便地制作了银微电极，用于ＤＰＳＡ具有背景值低，分辨率好、精密度及灵敏度高，在不搅拌，仅需一定酸度而酸度而无其它介质的条件下就能测试等优点，对人工试样及自来水样分析，结果令人满意。     

Network theory of the nonlinear behaviour of polymer melts. Simple shear flow

Summary The network model developed in a previous paper is applied to the simple shear flow of polymer melts. The constitutive equation obtained consists of two terms. One of them describes the stress due to the network strands which exist at the onset of the deformation, dissociate during the deformation and result in a single integral constitutive equation with a strain dependent damping function. The formulation of the damping function in invariant form seems to be almost impossible.The second normal stress differenceN ₂ of the model is not zero,but has negative values. According to our model this is a consequence of the deformation dependence of the disentanglement process. The theory is compared with experimental data for a LDPE melt. It is found that the model explains the main features of the shear flow behaviour of the LDPE melt investigated preciously.

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Zusammenfassung Das Netzwerk-Modell, das in einer vorangegangenen Arbeit entwickelt wurde, wird für die einfache Scherströmung von Polymerschelzen angewendet. Die abgeleitete rheologische Zustandsgleichung besteht aus zwei Gliedern. Das erste beschreibt die Spannung-Dehnung-Beziehung der Kettensegmente, die zu Beginn der Deformation existieren und während der Deformation aufgelöst werden. Es hat die Form der einfachen Integralbeziehung mit einer Gedächtnisfunktion. Es ist kaum möglich, die dabei erhaltene Gedächtnisfunktion als Funktion der Invarianten der der Tensoren darzustellen. Die zweite Normal-SpannungsdifferenzN ₂ des Modells ist nicht Null und hat einen negativen Wert. Dies ist nach unserem Modell eine Folge der Deformationsabhängigkeit des Entschlaufungsprozesses. Die Theorie wird mit dem experimentellen Daten für eine LDPE-Schmelze verglichen, wobei sich zeigt, daß das Modell die wesentlichen Merkmale des Scherverhaltens der LDPE-Schmelze gut erklärt.

     

停留—催化反应速差动力学法同时测定Fe,Mo

根据Ｆｅ（Ⅲ）、Ｍｏ（Ⅵ）对Ｈ２Ｏ２氧化邻氨基酚的催化反应速率不同，结合流动注射停留技术，建立了同时测定Ｆｅ（Ⅲ）、Ｍｏ（Ⅵ）的速差动力学分光光度法．测定铁和钼的线性范围分别为０．１～２．５μｇ／ｍＬ和０．５～１５μｇ／ｍＬ．除Ｗ（Ⅵ）的允许量较小外，其它离子不干扰测定．用本法测定了合成样液中铁和钼含量，结果满意．     

Enthalpies of mixing of binary and ternary mixtures containing diisopropylether,benzene and cyclohexane at 303.15 K

Enthalpies of mixing H have been measured for liquid binary mixtures of diisopropylether (DIPE)+benzene or cyclohexane and for liquid ternary mixtures diisopropylether+benzene+cyclohexane at 303.15 K and constant pressure using a C80 calorimeter. A Redlich-Kister type equation was used to correlate experimental results.     

Mixed strategy solutions forN-person quadratic games

Mixed strategy -equilibrium points are given forN-person games with cost functions consisting of quadratic, bilinear, and linear terms and strategy spaces consisting of closed balls in Hilbert spaces. The results are applied to linear-quadratic differential games with no information and quadratic integral constraints on the control functions.This work was supported by a Commonwealth of Australia, Postgraduate Research Award.     

A central limit theorem for age- and density-dependent population processes

Consider a population consisting of one type of individual living in a fixed region with area A. In [8], we constructed a stochastic population model in which the death rate is affected by the age of the individual and the birth rate is affected by the population density P_A(t), i.e., the population size divided by the area A of the given region. In [8], we proposed a continuous deterministic model which in general is a nonlinear Volterra type integral equation and proved that under appropriate conditions the sequence P_A(t) would converge to the solution P(t) of our integral equation in the sense that

$\text{lim}\text{→∞}\text{P}\text{sup}\text{0?s?t}\text{|P}{}_{\mathrm{A}}\text{(s) ? P(s)|>ε}\text{=0}\text{for every}\text{ε > 0}$

.In this paper, we obtain a “central limit theorem” for the random element √A(P_A(t)?P(t)). We prove that under appropriate conditions √A(P_A(t)?P(t)) will converge to a Gaussian process. (See Theorem 3.4 for the explicit formula of this Gaussian process.)     

Pyrolysis Analysis and Kinetics of Crude Oils

This research presents the results of an experimental study on the determination of pyrolysis behaviour and kinetics of six crude oils by differential scanning calorimetry (DSC) and thermogravimetry (TG/DTG). Crude oil pyrolysis indicated two main temperature ranges where loss of mass was observed. The first region between ambient to 400°C was distillation. The second region between 400 and 600°C was visbreaking and thermal cracking. Arrhenius-type kinetic model is used to determine the kinetic parameters of crude oils studied. It was observed that as crude oils gets heavier (°API decreases) cracking activation energy increases. Activation energy of cracking also show a general trend with asphaltene content. This revised version was published online in July 2006 with corrections to the Cover Date.     

Viscosity of aqueous solutions of polysaccharides and hydrophobically modified polysaccharides: Application of Fedors equation

Amphiphilic polysaccharides have been obtained by hydrophobic modification of a neutral bacterial polysaccharide, dextran. Various amounts and types of aliphatic hydrocarbon groups have been attached to dextran.The solution behaviour of unmodified dextran samples and amphiphilic dextran derivatives is characterized by viscometric measurements. The overall viscosity behaviour of unmodified polysaccharides is described up to C × [η] = 3, using the equation of Fedors [Fedors RF. Polymer 1979;20:225] which involves only a concentration parameter. The latter is shown to depend on the hydrodynamic volume of the macromolecules in solution.The equation of Fedors is shown to conveniently estimate the viscosity behaviour of amphiphilic dextran derivatives up to C × [η] = 1. The interdependence between Fedors parameter and other viscometric characteristics (intrinsic viscosity, Huggins coefficient) is evidenced. These results are extended to the data of other authors.     

Monolayer adsorption isotherms and a disordered medium model

A model of disordered medium is proposed to describe the monolayer adsorption isotherm on heterogeneous surfaces. The model is based on the premise that adsorption medium consists of separate regions in each of which there is a permanent local equilibrium constant, the character of the changes of which is determined by the disorder parameter of the medium. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 42, No. 3, pp. 189–193, May–June, 2006.     

Thermoanalytical characterization of polyphenylacetylene: III. Use of modulated differential scanning calorimetry (MDSC)

Four polyphenylacetylene samples, synthesized using different C₆H₅OH/Mo molar ratios, were investigated thermoanalytically by modulated temperature differential scanning calorimetry (MTDSC) in order to clarify a non-reversible exothermic event observed between 473 and 523 K on normal DSC. A stepwise, non-reversible change in heat capacity suggests the presence of internal reactions within the sample, that are followed by decomposition with loss of volatile products.