三嗪类化合物的合成及其产酸性能研究

合成了一系列的三嗪类光生酸剂1a—1e,确定了它们的结构,并对1e在乙腈溶剂中365和405nm光下的曝光分解产酸性能进行了初步的定量研究.结果表明,在测定浓度范围内分解量子产率和产酸量子产率基本上都不随浓度的变化而变化,在405nm光下比在365nm光下有更高的分解和产酸量子效率.有关这类化合物的光生酸性能与曝光波长的关系正在进一步研究中.     

Geometry Optimization of Thermoelectric Modules: Deviation of Optimum Power Output and Conversion Efficiency

Besides the material research in the field of thermoelectrics, the way from a material to a functional thermoelectric (TE) module comes alongside additional challenges. Thus, comprehension and optimization of the properties and the design of a TE module are important tasks. In this work, different geometry optimization strategies to reach maximum power output or maximum conversion efficiency are applied and the resulting performances of various modules and respective materials are analyzed. A Bi₂Te₃-based module, a half-Heusler-based module, and an oxide-based module are characterized via FEM simulations. By this, a deviation of optimum power output and optimum conversion efficiency in dependence of the diversity of thermoelectric materials is found. Additionally, for all modules, the respective fluxes of entropy and charge as well as the corresponding fluxes of thermal and electrical energy within the thermolegs are shown. The full understanding and enhancement of the performance of a TE module may be further improved.     

An improved evaluation of the neutron background in the PandaX-Ⅱ experiment

In dark matter direct detection experiments,neutron is a serious source of background,which can mimic the dark matter-nucleus scattering signals.In this paper,we present an improved evaluation of the neutron background in the PandaX-II dark matter experiment by a novel approach.Instead of fully relying on the Monte Carlo simulation,the overall neutron background is determined from the neutron-induced high energy signals in the data.In addition,the probability of producing a dark-matter-like background per neutron is evaluated with a complete Monte Carlo generator,where the correlated emission of neutron(s)andγ(s)in the(α,n)reactions and spontaneous fissions is taken into consideration.With this method,the neutron backgrounds in the Run 9(26-ton-day)and Run 10(28-ton-day)data sets of PandaX-II are estimated to be(0.66±0.24)and(0.47±0.25)events,respectively.     

汽轮发电机定子结构的动力分析和模型试验研究

本文用有限元方法分析了两种常见汽轮发电机定子结构模型的动力特性,建立了固有特性对集中质量、连接刚度及基础刚度的灵敏度分析方法,对这两种结构模型进行了振动实验研究,实验结果与有限元分析结果吻合较好.从避开共振的角度出发,对两种结构作了评价.本文的研究方法及实验结果对汽轮发电机结构设计、减振、隔振和降噪等方面的工作具有一定的参考价值和实际工程意义.     

“强光一号”加速器Z箍缩丝阵负载的零维模拟

作为丝阵Z箍缩实验的基础,丝阵负载的设计具有重要意义。主要介绍了Z箍缩丝阵负载设计的slug模型, 首先对该模型的原理进行了分析,然后对该模型进行编程,并利用美国Saturn加速器上的丝阵负载实验结果进行验证,计算结果表明了程序的可靠性。最后应用该模型及所编写程序对“强光一号”加速器上丝阵负载的Z箍缩实验进行了模拟,获得了偏差小于5%的模拟结果。     

Development of novel flexible black silicon

We report a new type of black silicon: flexible black silicon. A silicon-on-insulator (SOI) wafer is irradiated by automatically scanning a femtosecond laser and then split by etching out the SOI silica middle layer. Large-area, uniform micro spikes on the surface of a very thin flexible silicon layer are obtained. The black silicon shows good flexibility and optical properties. The absorption spectrum of the flexible black silicon is as high as 97% in the visible and insensitive to the change of the incident angle of the light, which makes it a potential good candidate as an absorber for the solar-thermo generator.     

纳秒级前沿PFN-MARX发生器充放电特性

为了改善脉冲形成网络(PFN)-Marx发生器的输出波形,得到前沿较短、纹波因数尽可能小的输出波形,对单级PFN的特性进了仿真研究,包括PFN中末端电容、末端电感、PFN的阻抗等因素对单级PFN的输出波形的影响;建立了PFN-Marx发生器的整体仿真模型,并对采用耦合电感作为隔离电感和采用分立电感作为隔离电感进行了仿真研究。研究表明：采用耦合电感作为隔离电感可以使各级PFN的充电波形更加一致,效果更好。搭建了一个小型的PFN-Marx发生器,并研究了PFN-Marx发生器中气体开关在不同气压下导通时输出波形的差异,结果表明,升高气压有利于减小PFN-Marx发生器输出波形的前沿持续时间。     

PPCP用固态脉冲电源的实验研究

 介绍了一种采用半导体开关与磁开关、可饱和脉冲变压器相结合技术的固态脉冲电源,此电源可用于脉冲放电等离子体烟气治理。在理论分析的基础上建立了实验模型,通过实验验证了此类电源的可行性,解决了8支晶闸管开关串联的动静态均压及开通同步性问题,并对可饱和脉冲变压器及磁开关的工作特性进行了分析计算。电源在阻性负载上得到峰值电压37.5 kV、前沿101 ns、脉宽1 μs的脉冲,重复频率300 Hz,输出功率10 kW。