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101.
102.
温度和剂油比对汽油催化裂化脱硫的影响 总被引:5,自引:0,他引:5
Increasingly stringent regulations on environmental protection make gasoline desulfurization be a major concern for the present refineries. Accordingly, we proposed an original idea of sulfur reduction by catalytic cracking of FCC gasoline and simultaneously converting most sulfur of sulfides to H 2S. Some progress has been made in exploitation of the catalysts. In this paper, the effect of temperature and catalyst/oil ratio on the FCC gasoline desulfurization over two catalyst samples via catalytic cracking was discussed. The optimum temperature range is 400~420 ℃ for sulfur removal with relatively low cracking loss of gasoline. The highest sulfur removal percentage of 70% can be achieved with a liquid yield of more than 96%. The catalyst samples have higher desulfurization activity and selectivity for the sulfide cracking. In addition, both the gasoline yield and the sulfur content of the desulfurized gasoline decrease with the catalyst/oil ratio. 相似文献
103.
104.
QIN FangLi LI Qian ZHAN HongLei JIN WuJun LIU HongLan ZHAO Kun 《中国科学:物理学 力学 天文学(英文版)》2014,57(7):1404-1406
Terahertz time-domain spectroscopy(THz-TDS)was used for the quantitative detection of sulfur content in gasoline.Models of chemo metrics methods and partial least squares(PLS)were built to measure THz-TDS and the sulfur content.All of the samples were divided into two parts.One part was used for calibration and the other one for validation.In order to evaluate the quality of the models,the correlation coefficient(R)and root-mean-square errors(RMSE)of calibration and validation models were calculated.The value of R and RMSE were close to 1 and 0 within acceptable levels,respectively,indicating that the combination of THz-TDS and PLS is a potential method for further quantitative detection. 相似文献
105.
The identification of gasoline adulteration by organic solvents is not an easy task, because compounds that constitute the solvents are already in gasoline composition. In this work, the combination of Hydrogen Nuclear Magnetic Resonance (1H NMR) spectroscopic fingerprintings with pattern-recognition multivariate Soft Independent Modeling of Class Analogy (SIMCA) chemometric analysis provides an original and alternative approach to screening Brazilian commercial gasoline quality in a Monitoring Program for Quality Control of Automotive Fuels. SIMCA was performed on spectroscopic fingerprints to classify the quality of representative commercial gasoline samples selected by Hierarchical Cluster Analysis (HCA) and collected over a 6-month period from different gas stations in the São Paulo state, Brazil. Following optimized the 1H NMR-SIMCA algorithm, it was possible to correctly classify 92.0% of commercial gasoline samples, which is considered acceptable. The chemometric method is recommended for routine applications in Quality-Control Monitoring Programs, since its measurements are fast and can be easily automated. Also, police laboratories could employ this method for rapid screening analysis to discourage adulteration practices. 相似文献
106.
Xiaofang Zhang Xiaohua Qi Mingqiang Zou Jingwei Wu 《Journal of Raman spectroscopy : JRS》2012,43(10):1487-1491
Identification of the gasoline purity is important for quality control and detection of gasoline adulteration. Principal component analysis and Raman spectroscopy were used to authenticate gasoline adulterated with methyl tert‐butyl ether (MTBE) and benzene. Gasoline could be clearly distinguished from gasoline adulterated with MTBE and benzene by a plot of the first principal component (x‐axis) against the second principal component (y‐axis). And the radial basis function neural network was used for quantitative prediction of the volume percentages of MTBE and benzene in gasoline based on Raman Spectra. The correlation coefficient (r) and mean absolute percentage error between predictive values and spiked values were 0.9907 and 0.9934 and 15.73 and 8.19%, respectively. Moreover, the Raman spectra of the samples were obtained with a portable Raman spectrometer. Therefore, the method is simple, effective, fast, does not require sample pre‐processing, and is promising for rapid gasoline detection. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
107.
针对汽油机稀燃条件下循环变动大,燃料燃烧不充分的问题,本文在一台加装了电控氢气喷射系统的四缸汽油机上就混氢对改善汽油机稀燃条件下燃烧与排放性能的作用进行了试验研究。在发动机1400r/min,进气道绝对压力为61.5 kPa的条件下,就1%与3%两种进气混氢体积分数对稀燃汽油机燃烧与排放特性的影响进行了研究。试验结果表明,稀燃时发动机制动热效率随混氢分数增加而提高;滞燃期与速燃期随混氢分数增加而缩短;发动机稀燃极限所对应的过量空气系数由原机的1.45提高至混氢1%与3%时的1.55和1.96。混氢后发动机HC与CO排放降低,但NO_x排放有所升高。 相似文献
108.
109.
建立有机进样-电感耦合等离子体质谱法(ICP-MS)测定汽油中锰、铁、铅含量的分析方法。以乙醇为稀释剂,选择水性无机元素标准溶液为标准物质,采用标准加入法并加入内标校正、补偿基体干扰效应后直接稀释进样分析,用碰撞模式消除多原子离子质谱干扰。锰、铁、铅的含量在0.00~20.00 μg/kg范围内具有良好的线性关系,相关系数均大于0.999,检出限分别为0.20,0.50,0.05 μg/kg。按标准加入法进行回收试验,加标回收率分别为81.9%~95.5%,85.4%~103.1%,97.4%~101.4%,测定结果的相对标准偏差均小于6%(n=6)。该方法快速、准确,灵敏度高,操作简便,试剂用量小,能满足实际汽油样品中微量锰、铁、铅含量的分析要求。 相似文献
110.
Fatemah M. Al-Douseri Yunqing Chen X.-C. Zhang 《International Journal of Infrared and Millimeter Waves》2006,27(4):481-503
We present the results of terahertz (THz) sensing of gasoline products. The frequency-dependent absorption coefficients, refractive
indices, and complex dielectric constants of gasoline and xylene isomers were extracted in the spectral range from 0.5–3.0
THz. The THz spectra of gasoline (#87, #89, #93) and related BTEX (benzene, toluene, ethylbenzene, and xylene) compounds were
studied by using Fourier transform infrared spectroscopy (FTIR) in the 1.5–20 THz (50–660 cm−1). The xylene isomers, which are used as antiknock agent in gasoline were determined quantitatively in gasoline in the THz
range. Our investigations show the potential of THz technology for the petroleum industrial applications. 相似文献