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31.
研究了应用于锂二次电池正极的新型高能量密度存贮材料Li(AlxCo1-x)O2 (x=01—05)的磁性.发现Al3+的掺杂可导致Co3+中d电子自旋态发生变化,即有部分d电子进入高自旋态.伴随Co3+中电子状态的改变,材料结构演化也发生了相应变化,表现为c/a比增大明显减缓,较好地解释了材料结构对Vegard定律的正偏离.这对材料的微观结构与性能设计具有重要意义.
关键词:
锂电池材料
Li(AlxCo1-x)O2
磁性
自旋态
结构演化 相似文献
32.
Andrzej Dabrowski Erich Robens Peter Klobes Klaus Meyer Przemyslaw Podkocielny 《Particle & Particle Systems Characterization》2003,20(5):311-322
Since a comprehensive survey published in 1999 [1] much work was done in standardizing measuring methods to characterize the surface geometry of dispersed and/or porous solids and to certify reference materials. The present paper is an extension of a short communication [2]. It gives a survey on existing standards and reports on new drafts and proposals. 相似文献
33.
34.
V. V. Struzhanov V. V. Bashurov 《Journal of Applied Mechanics and Technical Physics》2003,44(4):549-556
Some iterative methods for calculating self-balanced stresses under shrinkage of a ball inclusion enclosed in a spherical matrix of a physically nonlinear damageable material. The stability of this system was studied using methods of catastrophe theory. It has been established that the beginning of divergence of the proposed iterative processes coincides with the moment of transition of the system to an unstable position of equilibrium. 相似文献
35.
共轭下降法的全局收敛性 总被引:3,自引:0,他引:3
本文提出了一种Armijo型的线搜索,并在这种线搜索下讨论了共轭下降法的全局收敛性,且可得方法在每次迭代均产生一个下降搜索方向. 相似文献
36.
The state of the art iterative method for solving large linear systems is the conjugate gradient (CG) algorithm. Theoretical convergence analysis suggests that CG converges more rapidly than steepest descent. This paper argues that steepest descent may be an attractive alternative to CG when solving linear systems arising from the discretization of ill-posed problems. Specifically, it is shown that, for ill-posed problems, steepest descent has a more stable convergence behavior than CG, which may be explained by the fact that the filter factors for steepest descent behave much less erratically than those for CG. Moreover, it is shown that, with proper preconditioning, the convergence rate of steepest descent is competitive with that of CG.This revised version was published online in October 2005 with corrections to the Cover Date. 相似文献
37.
Nongelatin dichromated holographic film(NGD) is a new holographic recordingmaterial.Holograms recorded on this material have better environmental stability, higherdiffraction efficiency and stronger real time effect, etc..An experimental study to ascertainthe influence of two electron donors, namely,N,N-dimethylformamide(DMF) and dimethyl-sulfoxide(DMSO),on the real time diffraction efficiency(RTDE) of NGD holograms is car-ried out.The pressence of electron donors not only improves the sensitivity,but also enhancesthe real time effect greatly.RTDE of above 60% at±1 orders of NGD plane transimissiongrating is achieved by introducing electron donors. 相似文献
38.
MDF materials are chemically bonded ceramic materials free of the macrodefects typical of hydraulic cement-based materials. MDF materials arising through reactions of sulfo-aluminate-ferrite belitic (SAFB) clinkers and/or Portland cements (PC) with two types of water-soluble polymer (hydroxy-propylmethyl cellulose {HPMC}, polyphosphate glass {poly-P}) are discussed. Mixes of low energy SAFB clinkers with Portland cement, HPMC and, especially poly-P comprise promising cross-linked compositions additional to the better known MDF materials formed from high alumina cement with polyvinylalcohol/acetate. The principles of co-ordination of P and C atoms (of the polymer) with Al and Fe atoms (originating from the cement) are highlighted from spectroscopic information on next-nearest-neighbour interactions, along with the effects of second co-ordination spheres. Polymers modify the interface through functional bonding/grafting of polymer chains onto the surfaces of cement grains. Both the cross-linked atomic structure and the interface coincide well with the model of functional polymers and represent a new type of atomic-level structure in polymer-modified cements. Interpretation is based on previous magnetic resonance and thermal analysis studies. The compactness of Al(Fe)-O-P cross-links reduces transport through the interfaces, increasing the interfacial interactions and resisting the unfavourable uptake of moisture and carbonation. 相似文献
39.
An effect of Berry’s phase on the NQR spectrum of the rotating powder sample is described and applied for the determination of the electric field gradient asymmetry. The proposed method involves the analysis of the frequency singularities in the NQR powder patterns of the rotating samples. The Berry’s phases for the eigenstates, associated with an adiabatically changing quadrupole hamiltonian, are calculated for nuclei with a spin I = 3/2 and I = 1 as a function of the asymmetry parameter. 相似文献
40.
M. Iuga G. Steinle-Neumann J. Meinhardt 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,58(2):127-133
Athermal elasticity for some ceramic materials (α-Al2O3,
SiC (α and β phases), TiO2 (rutile and anatase),
hexagonal AlN and TiB2, cubic BN and CaF2, and monoclinic
ZrO2) have been investigated via density functional theory.
Energy-volume equation-of-state computations to obtain the zero pressure
equilibrium volume and bulk modulus as well as computations of the full
elastic constant tensor of these ceramics at the experimental zero pressure
volume have been performed. The present results for the single crystal
elasticity are in good agreement with experiments both for the aggregate
properties (bulk and shear modulus) and the elastic anisotropy. In contrast,
a considerable discrepancy for the zero pressure bulk modulus of some
ceramics evaluated from the energy-volume fit to the computational zero
pressure volume has been observed. 相似文献