全文获取类型
收费全文 | 1720篇 |
免费 | 64篇 |
国内免费 | 33篇 |
专业分类
化学 | 884篇 |
晶体学 | 1篇 |
力学 | 506篇 |
综合类 | 72篇 |
数学 | 62篇 |
物理学 | 292篇 |
出版年
2024年 | 8篇 |
2023年 | 41篇 |
2022年 | 66篇 |
2021年 | 63篇 |
2020年 | 52篇 |
2019年 | 45篇 |
2018年 | 51篇 |
2017年 | 83篇 |
2016年 | 58篇 |
2015年 | 50篇 |
2014年 | 59篇 |
2013年 | 194篇 |
2012年 | 81篇 |
2011年 | 62篇 |
2010年 | 60篇 |
2009年 | 72篇 |
2008年 | 74篇 |
2007年 | 71篇 |
2006年 | 98篇 |
2005年 | 63篇 |
2004年 | 62篇 |
2003年 | 46篇 |
2002年 | 56篇 |
2001年 | 39篇 |
2000年 | 34篇 |
1999年 | 27篇 |
1998年 | 25篇 |
1997年 | 23篇 |
1996年 | 24篇 |
1995年 | 21篇 |
1994年 | 22篇 |
1993年 | 20篇 |
1992年 | 11篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 2篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有1817条查询结果,搜索用时 15 毫秒
71.
氢化物发生-原子荧光光谱法是土壤环境中锑检测所广泛使用的方法.土壤的消解前处理分别采用王水微波消解(半消解)、混酸全消解(硝酸+高氯酸+氢氟酸)方式.研究结果表明王水微波消解对锑的检测效果较好,标准土壤9次测定值的相对标准偏差为3.6%,实际样品的回收率为96%-102%.而采用混酸全消解的方式测定值偏低,实际样品的回收率为78%~86%,而且精密度超过5%,这是由于在赶酸过程中样品易被蒸干而造成痕量锑元素的损失. 相似文献
72.
Digrazia Philip M. Blackburn James W. Bienkowski Paul R. Hilton Barry Reed Gregory D. King J. M. Henry Sayler Gary S. 《Applied biochemistry and biotechnology》1990,(1):237-252
An experimental and mathematical method is developed for the microbial systems analysis of polyaromatic hydrocarbon (PAH)-degrading
mixed cultures in PAH-contaminated “town gas” soil systems. Frequency response is the primary experimental and data analysis
tool used to probe the structure of these complicated systems. The objective is to provide a fundamental protocol for evaluating
the performance of specific mixed microbial cultures on specific soil systems by elucidating the salient system variables
and their interactions. Two well-described reactor systems, a constant volume stirred tank reactor (CSTR) and a plug flow
differential volume reactor, are used in order to remove performance effects that are related to reactor type as opposed to
system structure. These two reactor systems are well-defined systems that can be described mathematically and represent the
two extremes of one potentially important system variable, macroscopic mass transfer. The experimental and mathematical structure
of the protocol is described, experimental data is presented, and data analysis is demonstrated for the stripping, sorption,
and biodegradation of napththalene. 相似文献
73.
Anisotropy of magnetic susceptibility is used in the present study to reveal thedepositional fabric on the original (windblown) loess and secondary (redeposited) loess. The two kinds of sediments mentioned above can be distinguished in terms of their susceptibility anisotropy, e.g. anisotropy degree, magnetic foliation and lineation parameters. On this basis the magnetic fabric of the Pliocene red soil underlaying the loess is studied, and compared with the results of a typical residue-deposited red clay in South China. Considering its geological features, the red soil in Xifeng is regarded probably as aeolian in origin also. 相似文献
74.
MITIC Snezana ZIVANOVIC Valentina OBRADOVIC Mirjana TOSIC Snezana PAVLOVIC Aleksandra 《中国化学》2007,25(4):531-534
The kinetic method for the determination of phosphate microamounts was described. The developed method is based on catalytic effect of phosphate on sodium pyrogallol-5-sulphonate (PS) by dissolved oxygen. The reaction was followed spectrophotometrically by measuring the rate of change in the values of the absorbance of the oxidation product at 437 nm. The optimum reaction conditions are PS (0.44×10^-3 mol·L^-1) and HClO4 (3.6×10^-6 mol·L^-1) at 25 ℃. Following this procedure, phosphate can be determined with a linear calibration graph up to 0.23 μg·mL^-1. The interference effect of several species was also investigated and it was found that the most common cations and anions did not interfere with the determination. The developed procedure was successfully applied to the determination of phosphate in natural waters and soil. 相似文献
75.
An alternative to traditional hydrocarbon bioremediation is to pump air through unsaturated soils to create aerobic conditions
and induce biodegradation. This study examines the effects of moisture and nutrient augmentation on biodegradation of petroleum
hydrocarbons in aerated soils. Findings indicate that forced aeration, coupled with additions of nutrients and moisture, stimulate
hydrocarbon-degrading microorganisms and present a feasible approach to bioremediation management. 相似文献
76.
Three procedures, matrix matching, plasma optimisation and single-point standard-addition, have been evaluated to ascertain the best procedure for simultaneous multi-element analysis of industrial soils by ICP-AES with CCD detection. A standard reference material, CRM143 from the Bureau Communautaire de Réference (BCR), has been analysed for Cd, Cr, Cu, Mn, Ni and Pb using the three different matrix interference correction procedures. All three procedures give comparable results which are in good agreement with the BCR values, except for Cr. The single-point standard addition procedure was chosen, on the basis of economy and ease of implementation, to correct for matrix interferences in the determination of Cd, Co, Cr, Cu, Mn, Mo, Ni, Pb, Sn and V in soil samples collected from an industrial site in England. Concentrations of some of the elements were found to vary greatly with sampling depth. For example, the concentration of Mn, determined using the atomic line at 279.920 nm, increased from 426 ± 3 g/g at a depth of 18–28 cm to 5996 ± 144 g/g at 60–85 cm. 相似文献
77.
探讨了土壤中重金属检测能力验证的质量控制措施,为确保能力验证结果的准确性及不断提高实验室的检测技术水平提供参考. 相似文献
78.
Ali Khumaeni Masahiko Tani Kazuyoshi Kurihara Kiichiro Kagawa Hideaki Niki 《Analytical letters》2017,50(12):1992-1999
A novel method of laser-induced plasma spectroscopy utilizing a pulsed transversely excited atmospheric CO2 laser has been developed for the high-sensitivity determination of heavy metals in soil. A coarse metal powder was used to trap the soil and to assist with plasma generation. When the CO2 laser (10.6?µm, 1.5?J, 200?ns) was irradiated on the metal and soil powder, a high-temperature and long-lifetime luminous plasma was induced. Fine particles of soil were dissociated and were excited in the plasma region. The method was used for the rapid determination of Cr, Pb, and Hg in loam. The limits of detection for Cr, Pb, and Hg were approximately 0.8, 15, and 0.7?mg/kg, respectively. 相似文献
79.
80.
采用超声提取的方式,以离子色谱法测定土壤易溶盐中的氯离子和硫酸根离子。对实验条件进行了优化,色谱柱为NJ–SA–4A柱(250 mm×2 mm),保护柱为SI–92G柱(50 mm×4 mm),淋洗液为1.8 mmol/L Na_2CO_3–1.7mmol/L NaHCO_3,流量为1.0 m L/min;在40℃下,对土壤样品提取10 min。Cl~–和SO_4~(2–)在检测范围内均线性良好,线性相关系数为0.999 8,加标回收率分别为95.0%~99.0%,96.0%~101.0%,测定结果的相对标准偏差分别为1.4%,1.0%(n=4)。与传统的方法相比,该法试剂用量少,操作简单,可用于土壤易溶盐样品的测定。 相似文献