Partial quantum recurrence in free and quasibound systems

The quantum motion of a periodically two-sided kicked free particle is studied under various boundary conditions. The quasienergies, quasistates and the energy of the system are determined exactly. It is found that the energy of the system recurs irrespective of boundary conditions whereas the wave function shows recurrence only for a completely bound particle.     

Characterization of high heating rate chars of biomass fuels

Data on biomass chars obtained under conditions similar to those of practical applications (high heating rate and low residence time) are required for co-combustion and gasification plants. A methodological procedure is developed and applied to two biomass fuels (cacao shells and olive cake) for producing high heating rate chars and characterizing their reactivity and morphology after the first steps of devolatilization. Different chars are produced in a drop tube reactor (rapid pyrolysis) by varying the nominal temperature and the residence time. Oxidation in air is performed to compare typical temperatures and kinetic parameters and evaluate the effect of the operating conditions on char reactivity. A detailed SEM analysis allows to assess the structural variations during the pyrolysis and detect the main phenomena (softening, swelling, melting, formation of bubbles). A quantitative morphological study is also performed to provide size and shape (important for biomasses) distributions of the parent fuel and the chars. These data are more significant than average values in advanced model to correctly simulate the fluid dynamic behaviour of each dimensional class of particles in large scale furnaces and gasifiers and predict a more reliable residence time of the particles.     

General route to the total synthesis of sempervirine analogues containing modified E rings, potential cytostatics

Sempervirine analogues 13a–c with different E rings have been obtained via inverse electron demand Diels–Alder reactions of 5-acetyl-3-(methylsulfanyl)-1,2,4-triazine with cyclic enamines (formation of D and E rings) followed by Fischer indole synthesis under microwave irradiation on solid support (formation of A and B rings) and subsequent annulation of indole derivatives 10a–c via a directed metallation route (formation of C rings).     

Correlation between the surface free energy of modified and non-modified glasses with controlled porosity and their sorption properties

Summary Contact angles for water and diiodomethane drops were measured on the surface of thermally and chemically (by Carbowax 20M bonding) modified porous glasses and on the surface of naphthalene, diphenyl and anthracene. Using the obtained results to a modified Young equation, dispersion and nondispersion components of the surface free energy of these glasses and organic substances were calculated. The work of adhesion (W_A) for benzene, naphthalene, diphenyl, anthracene, nitrobenzene was estimated and correlated with the capacity factors, (k′) of these substances. On the basis of experimental and calculated data it can be stated that the thermal treatment of porous glasses increases, their hydrophobicity but the Carbowax layer causes hydrophilicity. There is a linear relationship between k′ and W_A which can be helpful for predicting retention data of chromatographed substances on the base of surface free energy which can be calculated from contact angle measurements.     

辉光放电中处理聚四氟乙烯表面：Ⅱ,ESR研究PTFE膜自由基

在外部电极电容耦合式反应装置中,对聚四氟乙烯(PTFE)膜进行了辉光放电处理。通过电子自旋共振(ESR)谱研究了PTFE在处理过程中所产生的自由基,着重讨论了温度对ESR谱的影响。最后,以DPPH为内标,测定了处理后PTFE膜的自由基浓度,并考察了自由基在空气中的衰减情况。     

The effect of repulsive interactions on Bose-Einstein condensation

One-dimensional Bose gases that interact via a repulsive two-body interaction and show Bose-Einstein condensation at the free level are studied. It is shown that the introduction of this interaction, however small, destroys the condensate. It is also shown that the free energy of an interacting Bose gas does not depend on the boundary conditions(including attractive boundary conditions) in the van der Waals limit.     

Electrical resistivity of the alkaline earth metals Ca,Sr and Ba in the 50–300K temperature region

The computed values of the temperature dependent electrical resistivity is presented for the alkaline earth metals Ca, Sr and Ba. Numerical values of the mean free paths obtained using a finite mean free path approach is also reported. The structure factor has been evaluated using experimental values for the phonon spectra while local model potentials were used for the form factors. Our numerical results compare favourably with experiments.     

高聚物熔体的新状态方程

1引言随着国民经济的快速发展，作为新型的、具有特殊功能的高分子聚合物已成为在国民经济各部门中应用最为广泛的新型材料之一，如SAN、PP、PVC等高聚物．高聚物状态方程是研究这类新型材料性能及其加工过程，以及生产这些高聚物机械设备设计的重要依据，长期以来一直为广大高分子科技工作者十分重视的研究领域。但由于高聚物具有其特殊且又十分复杂的物质结构，与常规的气、液等物态有着很大的差异，尤其热物性与这些常规物质间存在着很大的不同，因此研究起来往往十分困难，至今为止国外的研究仍寥寥无几，国内在这方面的研究几乎尚…     

EXISTENCE OF STOCHASTIC EQUILIBRIUM WITH INCOMPLETE FINANCIAL MARKETS

This paper analyzes the aritrage-tree security markets and the general equilibrium ex-istence problem for a stochastic economy with incomplete financial markets. Information structure is given by an event tree. This paper restricts attention to puraly financial securities. It isassume that trading takes place in the sequence of spot markets and futures markets for securi-ties payable in units of account. Unlimited short-selling in securities is allowed. Financial markets may be incomplete, some consumption streams may be impossible to obtain by any tradingstrategy. Securities may be individually precluded from trade at arbitrary states and dates. Thesecurity price process is arbitrage-free the dividend process if and only if there exists a stochaticstate price (present value) process : the present value of the security prices at every vertex isthe present value of their dividend and capital values over the set of immediate successors ; thecurrent value of each security at every vertex is the present value of its future dividend streamover all succeeding vertices. The existence of such an equilibrium is proved under the followingcondition: continuous, weakly convex, strictly monotone and complete preferences, strictlypositive endowmenta and dividends processes.     

Reflections and Three-Dimensionality

If the dimension of a linear space is not greater than 3, then the characteristic polynomial of the Coxeter transformation associated with any symmetric matrix is invariant under the natural action of the symmetric group. If the dimensionality is greater than 3, then this statement does not hold. The set of all trees such that the spectrum of their associated Coxeter transformation contains negative one is three-dimensional.