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81.
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Kang‐Zhen Xu Ji‐Rong Song Feng‐Qi Zhao Shu‐Yun Heng Li Ding Yao‐Yu Wang Rong‐Zu Hu 《中国化学会会志》2009,56(3):524-531
A novel high energy material, 1‐amino‐1‐methylamino‐2,2‐dinitroethlyene (AMFOX‐7), was synthesized by the reaction of 1,1‐diamino‐2,2‐dinitroethylene (FOX‐7) and methylamine aqueous solution in N‐methyl pyrrolidone at 80°C. The thermal behavior and non‐isothermal decomposition kinetics of AMFOX‐7 were studied with DSC and TG/DTG methods. The kinetic equation of thermal decomposition reaction can be expressed as: $ {\rm d\alpha /d}T = \frac{{10^{21.03}}}{{\rm \beta}}\frac{3}{2}\left({1 - {\rm \alpha}} \right)\left[{- 1{\rm n}\left({{\rm 1} - {\rm \alpha}} \right)} \right]^{\frac{1}{3}} \exp \left({- 2.292 \times 10^5 {\rm /}RT} \right) A novel high energy material, 1‐amino‐1‐methylamino‐2,2‐dinitroethlyene (AMFOX‐7), was synthesized by the reaction of 1,1‐diamino‐2,2‐dinitroethylene (FOX‐7) and methylamine aqueous solution in N‐methyl pyrrolidone at 80°C. The thermal behavior and non‐isothermal decomposition kinetics of AMFOX‐7 were studied with DSC and TG/DTG methods. The kinetic equation of thermal decomposition reaction can be expressed as: $ {\rm d\alpha /d}T = \frac{{10^{21.03}}}{{\rm \beta}}\frac{3}{2}\left({1 - {\rm \alpha}} \right)\left[{- 1{\rm n}\left({{\rm 1} - {\rm \alpha}} \right)} \right]^{\frac{1}{3}} \exp \left({- 2.292 \times 10^5 {\rm /}RT} \right) $. The critical temperature of thermal explosion of AMFOX‐7 is 244.89°C. The specific heat capacity of AMFOX‐7 was determined with micro‐DSC method and theoretical calculation method, and the standard molar specific heat capacity is 199.39 J·mol?1·K?1 at 298.15 K. Adiabatic time‐to‐explosion of AMFOX‐7 was also calculated to be 215.41 s. AMFOX‐7 has higher thermal stability than FOX‐7. 相似文献
83.
利用弹道冲击摆锤系统对分层梯度蜂窝夹芯板在爆炸荷载下的动力响应进行了实验研究,分析了梯度蜂窝夹芯板在爆炸荷载作用下的变形失效模式,并与传统非梯度蜂窝夹芯板的抗爆性能做了对比。通过一维应力波理论,分析了应力波在梯度芯层中的传播规律。应力波透射系数在梯度试件中比非梯度芯层中小,而且相对密度递减的芯层组合有最小的应力波透射系数。综合考虑结构变形失效模式,后面板挠度,芯层压缩量以及应力波传播特点得到:分层梯度蜂窝夹芯板的抗爆性能明显优于传统的非梯度夹芯板,在所研究的荷载范围内,芯层相对密度从大到小排列试件的抗爆性能相对较好。 相似文献
84.
本文探讨了超微血管成像(SMI)和超声造影(CEUS)对乳腺癌病灶内微血流及超微血管的评价,及其联合检查对乳腺癌的诊断价值。选取2017年6月~2019年3月我院收治的经手术病理证实的乳腺癌患者106例(106个肿块)作为研究对象,所有患者术前均完成彩色多普勒血流显像(CDFI)、CEUS及SMI检查。比较SMI、CEUS对乳腺癌的诊断准确率及对病灶内血流信号、穿支血管的显示情况。结果显示,106例乳腺癌(106个肿块)中,SMI和CEUS对乳腺癌的诊断准确率分别为79.25%、83.96%,两者比较差异无统计学意义(P>0.05);SMI联合CEUS检查对乳腺癌的诊断准确率为96.23%,明显高于单一SMI或CEUS的诊断准确率(P<0.05)。在血流信号显示上,SMI检出不丰富血流信号、丰富血流信号分别为64个、42个;CEUS表现为低增强64个、等增强及高增强为42个;SMI和CEUS评价乳腺癌病灶内微血管及血流供应情况具有较好的一致性(P<0.05)。在穿支血管显示上,SMI检出44个、CDFI检出34个,SMI能够清晰检出CDFI不能检出的穿支血管10个。表明SMI和CEUS诊断乳腺癌病灶内微血管及血流供应情况具有较好的一致性,对乳腺癌均有较高的诊断价值,二者联合检查有助于提高乳腺癌的诊断准确率。 相似文献
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86.
具有初始缺陷的内胆会对复合材料气瓶的服役性能造成严重危害,本文基于响应面法,提出了一种复合材料气瓶含初始缺陷内胆屈曲的可靠性分析方法。建立了铝合金6061内胆的T700/环氧复合材料气瓶的三维有限元模型,实现了复合材料气瓶内胆的收缩屈曲分析。基于响应面方法,构造了复合材料气瓶极限状态方程,并假设结构中的随机变量服从高斯分布,开展了考虑几何尺寸和凹陷尺寸变化的气瓶结构可靠性分析,结果表明,在气瓶内胆加工过程中,直筒段厚度的离散性会严重影响气瓶结构的可靠性;直筒段半径、直筒段长度、封头段半径和封头段厚度在通用加工误差内对气瓶结构的可靠性影响较小;对本文定型气瓶,当内胆表面的凹陷半径超过10 mm,且深度超过2 mm时,气瓶结构的可靠性会严重降低。 相似文献
87.
88.
89.
Nara O 《Analytica chimica acta》2011,(1):91-102
I describe an interchangeable twin vessel (J, N) automatic glass recrystallizer that eliminates the time-consuming recovery and recycling of crystals for repeated recrystallization. The sample goes in the dissolution vessel J containing a magnetic stir-bar K; J is clamped to the upper joint H of recrystallizer body D. Empty crystallization vessel N is clamped to the lower joint M. Pure solvent is delivered to the dissolution vessel and the crystallization vessel via the head of the condenser A. Crystallization vessel is heated (P). The dissolution reservoir is stirred and heated by the solvent vapor (F). Continuous outflow of filtrate E out of J keeps N at a stable boiling temperature. This results in efficient dissolution, evaporation and separation of pure crystals Q. Pure solvent in the dissolution reservoir is recovered by suction. Empty dissolution and crystallization vessels are detached. Stirrer magnet is transferred to the crystallization vessel and the role of the vessels are then reversed. Evacuating mother liquor out of the upper twin vessel, the apparatus unit is ready for the next automatic recrystallization by refilling twin vessels with pure solvent. We show successive automatic recrystallization of acetaminophen from diethyl ether obtaining acetaminophen of higher melting temperatures than USP and JP reference standards by 8× automatic recrystallization, 96% yield at each stage. Also, I demonstrate a novel approach to the determination of absolute purity by combining the successive automatic recrystallization with differential scanning calorimetry (DSC) measurement requiring no reference standards. This involves the measurement of the criterial melting temperature T0 corresponding to the 100% pure material and quantitative ΔT in DSC based on the van’t Hoff law of melting point depression. The purity of six commercial acetaminophen samples and reference standards and an eight times recrystallized product evaluated were 98.8 mol%, 97.9 mol%, 99.1 mol%, 98.3 mol%, 98.4 mol%, 98.5 mol% and 99.3 mol% respectively. 相似文献
90.
V. N. Manuilov T. Idehara M. Kamada T. Hayashi La Agusu T. Kanemaki K. Yatsui Wiehua Jiang 《International Journal of Infrared and Millimeter Waves》2006,27(9):1183-1193
High power Large Orbit Gyrotron (LOG) [1] is now under development at FIR FU. First version of this device was recently manufactured
and then assembled with power supply ETIGO-IV [2]. Results of preliminary tests of electron-optic system are presented. The
conditions when stableflat form of current pulse realized are discussed. Analytical estimations of cathode-anode distance
to achieve small influence of cathode plasma during high voltage (HV) pulse are performed.
Two new electron gun versions with decreased influence of the cathode plasma on its impedance and pulse form are suggested
and optimized. New optimal magnetic field distributions are found. First gun has quiasi-flat cathode configuration near the
anode diaphragm and provides operating current about 60 A. Second one uses blade cathode with operating current about 30 A.
Beam quality for both guns is suitable for LOG operation. 相似文献