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991.
以硅烷化后吸附粒径小于10 nm的金种子的玻璃片为基底,聚乙烯吡咯烷酮为还原剂,在荧光灯照射条件下还原氯金酸,制备出表面具有金纳米粒子聚集结构的基底。用原子力显微镜、扫描电镜、X射线衍射、吸收和荧光光谱研究了基底的性质。结果表明:随着光照时间增加至20 h,金种子长大为平均粒径140 nm的不规则状多晶粒子,且出现双层粒子堆叠。基底的吸收光谱上出现了由金粒子的表面等离子体激元偶极子耦合引发的强烈吸收峰,随着粒子粒径增大,耦合峰在600~800 nm波段内连续红移升高,表明耦合程度不断增强。在223 nm紫外光的激发下,基底的荧光光谱上在405 nm处出现发射峰,是由金粒子表面激发电子和空穴的复合辐射造成的,发光强度随着基底上粒子平均尺度增加而减弱。 相似文献
992.
ZHENG Yu-Ming FUCHS C. SRISAWAS Pornrad FAESSLER Amand YAN Yu-Peng KOBDAJ Chinorat XING Yong-Zhong 《理论物理通讯》2008,50(9):725-728
The sigma meson production in p + ^12C and p A- ^40Ca reactions at the incident energy Ep = 1.5 GeV is investigated within the Quantum Molecular Dynamics model. The simulation results indicate a distinctive A dependence of the sigma production, that is, the increase of A is followed by an increase of the production cross sections. We find that the σ meson production in proton-induced reactions is strongly medium-dependent, and the produced σ mesons decaying in a denser medium experience a stronger mass shift towards lower masses. This mass shift is an experimentally accessible observable in the final state pion pairs, which do not suffer from reabsorption by the surrounding nucleons. It is pointed out that the ratio of measured sigma cross sections as a function of the sigma invariant-mass from various reactions is a good probe to explore the existence of the σ meson in a dense nuclear environment. 相似文献
993.
Proton-detected scalar coupling based assignment strategies in MAS solid-state NMR spectroscopy applied to perdeuterated proteins 总被引:1,自引:0,他引:1
Assignment of proteins in MAS (magic angle spinning) solid-state NMR relies so far on correlations among heteronuclei. This strategy is based on well dispersed resonances in the 15N dimension. In many complex cases like membrane proteins or amyloid fibrils, an additional frequency dimension is desirable in order to spread the amide resonances. We show here that proton detected HNCO, HNCA, and HNCACB type experiments can successfully be implemented in the solid-state. Coherences are sufficiently long lived to allow pulse schemes of a duration greater than 70 ms before incrementation of the first indirect dimension. The achieved resolution is comparable to the resolution obtained in solution-state NMR experiments. We demonstrate the experiments using a triply labeled sample of the SH3 domain of chicken α-spectrin, which was re-crystallized in H2O/D2O using a ratio of 1/9. We employ paramagnetic relaxation enhancement (PRE) using EDTA chelated CuII to enable rapid data acquisition. 相似文献
994.
In this paper, the compositions in a laser absorption region can be
determined from the experiment of laser impulse coupling. When the
ambient pressure varies from 9325 to 33325Pa, the compositions are
vapour and plasma; while from 35325 to 101325Pa, they are ambient air
and plasma. By analysing the relation between the degree of
compression and the ambient pressure, the compositions can be
determined and the variation of plasma can be explained. 相似文献
995.
Zhongzhi Zhang Shuigeng Zhou Lichao Chen Jihong Guan 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,64(2):277-283
Real networks can be classified into two categories: fractal networks and non-fractal networks. Here we introduce a unifying
model for the two types of networks. Our model network is governed by a parameter q. We obtain the topological properties of the network including the degree distribution, average path length, diameter, fractal
dimensions, and betweenness centrality distribution, which are controlled by parameter q. Interestingly, we show that by adjusting q, the networks undergo a transition from fractal to non-fractal scalings, and exhibit a crossover from ‘large’ to small worlds
at the same time. Our research may shed some light on understanding the evolution and relationships of fractal and non-fractal
networks. 相似文献
996.
We show that the number of photons in a strongly coupled exciton–photon system is asymmetric with the detuning of the modes when, in the spontaneous emission regime, the two modes are entangled. As changing the detuning is easy in semiconductor microcavities–where on the other hand the nature of the strong-coupling in terms of single-particle effects is not yet resolved–we propose this effect as a test of the quantum character of microcavity polaritons. 相似文献
997.
The dynamics of information traffic over scale-free networks has been investigated systematically. A series of routing strategies
of data packets have been proposed, including the local routing strategy, the next-nearest-neighbour routing strategy, and
the mixed routing strategy based on local static and dynamic information. The capacity of the network can be quantified by
the phase transition from free flow state to congestion state. The optimal parameter values of each model leading to the highest
efficiency of scale-free networked traffic systems have been found. Moreover, we have found hysteretic loop in networked traffic
systems with finite packets delivering ability. Such hysteretic loop indicates the existence of the bi-stable state in the
traffic dynamics over scale-free networks.
相似文献
998.
Zhongzhi Zhang Shuigeng Zhou Zhan Su Tao Zou Jihong Guan 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,65(1):141-147
In this paper, we define a stochastic Sierpinski gasket, on the basis of which we construct a network called random Sierpinski
network (RSN). We investigate analytically or numerically the statistical characteristics of RSN. The obtained results reveal
that the properties of RSN is particularly rich, it is simultaneously scale-free, small-world, uncorrelated, modular, and
maximal planar. All obtained analytical predictions are successfully contrasted with extensive numerical simulations. Our
network representation method could be applied to study the complexity of some real systems in biological and information
fields. 相似文献
999.
Coupling a single-mode laser diode with 200 mW to a single-mode fiber (SMF) through an orthonormal aspherical cylindrical lens and a GRIN lens for the intersatellite optical communication system is proposed and demonstrated. We experimentally studied how the coupling efficiency changes with the SMF's position displacement and axial angle variation, and obtained 80 mW output power at the end of the SMF, which shows that the coupling units have satisfied the designed request. 相似文献
1000.
以血红蛋白模拟过氧化物酶,在不同pH溶液中,测定并比较了催化反应中间体-Ⅱ的ks,t1/2和催化活性等。结果表明,中间体-Ⅱ的ks,t1/2和催化活性均与缓冲液的pH密切相关,其稳定性在pH5.0时最小,而此时的催化反应速度最高。 相似文献