Paramagnetic Properties and Moderately RapidConformational Dynamics in the Cobalt(II) Calix[4]arene Complex by NMR

¹H NMR measurements are reported for the CD₂Cl₂/CDCl₃ solutions of the Co(II) calix[4]arenetetraphosphineoxide complex (I). Temperature dependences of the ¹H NMR spectra of I have been analyzed using the line shape analysis, taking into account the temperature variation of paramagnetic chemical shifts, within the frame of the dynamic NMR method. Conformational dynamics of the 2:1 Co(II) calix[4]arene complexes was conditioned by the pinched cone ↔pinched cone interconversion of I (with activation Gibbs energy ΔG^≠(298K) = 40 ± 3 kJ/mol. Due to substantial temperature dependence of paramagnetic shifts, complex I can be used as model compound for designing an NMR thermosensor reagent for local temperature monitoring.     

Effect of H impurity on misfit dislocation in Ni-based single-crystal superalloy： molecular dynamic simulations

The effect of H impurity on the misfit dislocation in Ni-based single-crystal superalloy is investigated using the molecular dynamic simulation.It includes the site preferences of H impurity in single crystals Ni and Ni 3 Al,the interaction between H impurity and the misfit dislocation and the effect of H impurity on the moving misfit dislocation.The calculated energies and simulation results show that the misfit dislocation attracts H impurity which is located at the γ/γˊinterface and Ni₃ Al and H impurity on the glide plane can obstruct the glide of misfit dislocation,which is beneficial to improving the mechanical properties of Ni based superalloys.     

继电器动态过程中动态参数的测试方法

本文介绍了一种测试继电器在动态过程中动态参数测试的方法。采用此方法能直接测量和观察继电器动态过程中的线圈电压、电流 ,同时可测出继电器的动作时间 ,还可了解其接点在接触过程是否有振动现象存在。所以 ,此方法是一种多用途的继电器动态参数测量方法     

Thermodynamic studies of some 1,2,4-triazole derivatives in DMF and THF solutions at 308.15 K

Some new 1,2,4-triazole derivatives have been synthesized and characterized by TLC, IR, NMR and mass spectra. Densities, viscosities and ultrasonic velocities of these compounds have been measured over the wide composition range at 308.15?K in dimethyl formamide (DMF) and tetrahydro furan (THF). From these data, various acoustical and thermodynamic parameters (C.V. Suryanarayana, J. Kuppuswamy. J. Acoust. Soc. Ind., 4, 75 (1976); H. Erying, M.S. John, Significance of Liquid Structures, Wiley, New York (1969); G.K. Johri, R.C. Misra. Acustica, 56, 66 (1989)) were evaluated. Some of these parameters are isentropic compressibility (κ_s), intermolecular free length (L _f), relaxation strength (r), relative association (R _A), Rao's molar constant (R _m), van der Waal's constant (b), molar compressibility (W), internal pressure (π), free volume (V _f), solvation number (S _n) etc. The behavior of solutions of these compounds in DMF and THF are explained from the evaluated parameters.     

一种动态实时的遥感专题应用系统定制框架

遥感专题应用系统广泛用于遥感影像的加载、分析、专题提取、出图等.为实现遥感专题应用系统动态、实时和可扩展的定制化开发,设计了一套基于组件的遥感专题应用系统定制框架：定义了组件划分方式,将专题系统划分为功能类组件和容器类组件,建立了组件属性和组件间的关系;采用XML文件描述遥感专题应用系统中的组件,并提供从XML到遥感专题应用系统的解析方法;设计了遥感专题应用系统定制平台,提出一种动态实时的软件设计方法,可以“所见即所得”地定制遥感专题应用系统,并将其保存为XML文件.采用该定制平台定制的多个专题系统已应用于相关部门.该框架为快速高效定制遥感专题应用系统提供了一种新的开发设计模式,降低了遥感数据在多行业应用的技术门槛,减少重复性开发工作.     

荒漠生态系统中的非线性动力学问题

本文给出了动物群体与荒漠绿洲脆弱带的周期、准周期、无周期振汤等事例。它们指明，种群密度的波都遵从非线性动力学规律，数值计算所得规律与经验规律对比后，其结果基本相符。     

冻融循环周次对陶粒混凝土动态力学性能影响的实验研究

为了研究冻融循环周次对陶粒混凝土动态力学性能的影响, 对含有页岩陶粒体积分数为0%、15%、30%、45%的陶粒混凝土试样分别进行0、10、20、30和40次的冻融循环后SHPB动态压缩实验. 实验表明: 陶粒混凝土的动态力学性能随着冻融循环周次增加而弱化, 动态压缩强度随着应变率的增加而增大, 并给出了冻融循环周次对陶粒混凝土动态压缩强度的变化规律.     

非保守动力学系统的Noether定理的一个证明

本文直接从动力学系统的Lagrange函数在无穷小变换下的变换性质出发,得到了完整非保守和非完整非保守的Noether定理。本文的方法具有优越性。     

时标上二阶广义Emden-Fowler型动态方程的振荡性

研究了时标上的一类具有阻尼项的二阶广义Emden-Fowler型泛函动态方程的振荡性,利用时标上的微积分理论和广义的Riccati变换及不等式技巧,建立了该方程振荡的若干判别准则, 推广且改进了一些已有的结果,并用具体实例来说明本文的主要结论。     

腰椎间盘纤维环膨隆症站立位动态脊髓造影的临床意义

目的:在MRI或CT检查的腰腿痛病人中,通过站立位动态脊髓造影,了解椎间盘纤维环在腰椎中立、过屈、过伸三位置下的变化,并探讨其临床意义,筛选出具有手术指征的LDH病人,决定手术方式.方法:对86例LDH患者,行站立或平卧中立、过屈、过伸脊髓造影,对比分析两组动态变化.鉴别出LDB,选择性行有限椎板减压,或保留其椎间盘.结果:脊髓造影侧位像“拿破仑帽”状影,站立三位置均明显大于平卧位,差异非常显著(P＜0.01),在动态变化中平卧位者改成由中至屈曲位时,硬膜囊受压影较站立位者明显缩小,差异非常显著(P＜0.01),站立由中至伸时,压迫影较平卧位增大,差异显著(P＜0.05).其中28例,行有限椎板切除或保留其椎间盘,效果优良.结论:站立位会使LDB加重、临床症状加重,因站立过伸位使腰椎管狭窄病人症状加重.而平卧位造影时因重力负荷减轻,(拿破仑帽)影像不明显或消失,而出现假阴性.