海藻酸钙凝胶微球粒径的理论计算与实验

通过静电液滴发生器制备海藻酸钙凝胶微球,通过理论推导得到了微球粒径的计算公式.理论计算的结果表明,凝胶微球粒径的大小取决于静电压、电极距离、针头内径大小、注射器流速、海藻酸钠粘度和表面张力以及凝胶化体积收缩系数.理论计算结果与实验结果吻合得相当好.     

材料介观有序结构小角光散射图案的FFT算法

用快速傅里叶变换计算方法(FastFourierTransformation,FFT)直接获得高分子材料中介观有序结构小角激光光散射(SALS)图案,从而对实验获得的球晶和液晶液滴的SALS图案进行结构预测.作为实例,计算了几种典型液晶液滴构型的SALS图案.     

A Combinatorial Approach for Optimization of Oxygen Evolution Catalyst Loading on Mo‐doped BiVO4 Photoanodes

The incident photon to current efficiency (IPCE) of a photoactive surface strongly depends on the loading and thickness of the active materials. We present a combinatorial approach based on an optical scanning droplet cell for simultaneous deposition and systematic characterization of co‐catalysts for the oxygen evolution reaction (OER) on Mo‐doped BiVO₄ (Mo?BiVO₄) photoanodes electrochemically pre‐deposited on transparent conductive FTO substrates. The loading and photoelectrochemical characterization of 10 different OER co‐catalysts deposited by three different deposition techniques on FTO‐supported Mo?BiVO₄ were investigated aiming at determination of the suitable deposition parameters affording the highest enhancement of photoelectrochemical oxygen evolution for the different OER/Mo?BiVO₄ films. A comparison of the photoelectrochemical performance of films of various OER co‐catalyst deposited on FTO‐supported Mo?BiVO₄ by electrodeposition, photo‐assisted electrodeposition and photodeposition revealed the necessity of a material specific optimization with respect to co‐catalyst loading and deposition technique to achieve optimal IPCE for each co‐catalysts.     

High‐throughput droplet‐based microfluidics for directed evolution of enzymes

Natural enzymes have evolved over millions of years to allow for their effective operation within specific environments. However, it is significant to note that despite their wide structural and chemical diversity, relatively few natural enzymes have been successfully applied to industrial processes. To address this limitation, directed evolution (DE) (a method that mimics the process of natural selection to evolve proteins toward a user‐defined goal) coupled with droplet‐based microfluidics allows the detailed analysis of millions of enzyme variants on ultra‐short timescales, and thus the design of novel enzymes with bespoke properties. In this review, we aim at presenting the development of DE over the last years and highlighting the most important advancements in droplet‐based microfluidics, made in this context towards the high‐throughput demands of enzyme optimization. Specifically, an overview of the range of microfluidic unit operations available for the construction of DE platforms is provided, focusing on their suitability and benefits for cell‐based assays, as in the case of directed evolution experimentations.     

外压法推导开尔文公式的探究

液体的饱和蒸气压受外压的影响,根据外压对液体饱和蒸气压的影响公式可以推导出液滴、弯曲液面的开尔文公式。     

单液滴内空化气泡的生长及溃灭研究

超空化燃油射流使得喷雾中部分燃油分裂液滴内含有空化气泡;空化气泡的生长及溃灭对液滴的分裂与雾化具有重要影响. 基于VOF 方法首次对超空化条件下燃油液滴内空化气泡的生长及溃灭过程进行了数值模拟. 通过研究发现,单液滴内空化气泡的生长过程可以按控制机理划分为表面张力控制阶段、综合竞争阶段和惯性力控制阶段;在第I 阶段,空泡的生长主要受表面张力的控制作用,惯性力对空泡生长的促进作用及黏性力对空泡生长的抑制作用可以忽略;在第II 阶段,空泡的生长受表面张力、惯性力及黏性力三者的综合作用,空泡的生长速率是促进空泡生长的惯性力和抑制空泡生长的表面张力及黏性力相互竞争、共同作用的结果;在第III 阶段,空泡的生长主要受惯性力的控制作用,抑制空泡生长的表面张力及黏性力的作用基本可以忽略. 单液滴内空化气泡的溃灭过程由多个溃灭阶段和反弹阶段构成,类似于有阻尼弹簧振子的振动过程;根据每个溃灭周期结束时空泡半径随时间的变化历程,可以将空泡的溃灭分为快速溃灭期、缓慢溃灭期以及稳定期;溃灭初期空泡溃灭压力的变化非常剧烈,但空泡溃灭体积的变化则要相对平缓得多;空泡反弹压力随时间的变化与空泡反弹体积随时间的变化基本对应.      

冰滴在宇宙速度下与航天铝壳结构超高速撞击的分子动力学模拟(英文)

采用大规模分子动力学模拟,从原子层次探索了冰滴高速撞击航天铝壳结构的动态过程.冰滴的速度设置为典型的宇宙速度.在高速撞击时,部分动能转化为热能,使得撞击点附近迅速升温.随着撞击速度的提高,铝壳经历了弹性变形、塑性变形、冲击融化,最后被穿透的过程.在分子动力学模拟中,清楚地观测了碎片云的形成和动态行为.     

Numerical Investigation of the Time Scales of Single Droplet Burning

The effect of gas phase velocity fluctuations on single droplet burning is investigated numerically. The main objective of this study is to understand the effect of gas phase turbulence on nitric oxide formation in single droplet flames. Since the interaction of gas phase velocity fluctuations with droplet burning is of sequential character, a separate investigation of droplet momentum coupling and droplet burning is performed. Momentum coupling controls droplet relaxation against changes of the gas phase velocity along the droplet trajectory and, thereby, determines to what extend gas phase velocity fluctuations translate into droplet slip velocity fluctuations. This coupling effect acts as a high pass filter with a cutoff frequency determined by the droplet Reynolds number and diameter. In the simulation of single droplet burning detailed models for chemical reaction, diffusive species transport and evaporation are used. A significant effect of slip velocity fluctuations on the mean values of NO formation rate is observed. The effect of slip velocity fluctuations on the mean NO formation rate is frequency dependent. The frequency response of the droplet flame is similar to that of a low pass filter. The droplet flame time scale characterizing the response to slip velocity fluctuations is found to correlate with chemical time scales. This time scale is not affected by droplet diameter.     

Measuring particle size distribution using LED-illumination

A particle/droplet image analysis (PDIA) system employing LED-illumination was designed. Freezing the moving droplets using high speed camera instead of stroboscopic illumination, the system had no requirement to synchronize the backlight and the camera. It featured low cost, low power consumption and simple optical configuration in comparison to laser-based systems. Only focused droplets in images were counted. Given the sample size of the system was relatively small, an upper-limit lognormal distribution was used to fit the actual data to represent the spray patterns. The accuracy of the diameter measurement was verified using precisely manufactured balls. Comparisons with two laser-based systems were given and the system’s capacity to distinct spray patterns were demonstrated in nozzle classification experiments.