Turbulent Structure of a Gas-Liquid Impinging Jet

The turbulent structure of a submerged axisymmetric impinging jet containing small gas bubbles is studied experimentally under conditions of periodic external excitation. On the basis of measuring the surface-friction pulsatory component in the jet impinging on an obstacle, the effect of the suppression of large-scale eddies at large gas volume fractions is registered. The conditions of resonant growth of coherent structures and the suppression of wide-band turbulence are determined for both the single-phase and the two-phase impinging jet. An analysis of the development of different pulsatory friction components in the impinging-jet gradient region is presented.     

两种流型下雾滴表面气溶胶粒子的扩散沉积

用浓度边界层理论分析了势流和Hadamard流情形下雾滴或云滴前向驻点处小粒子的扩散效应。结果表明：存在静电效应时，有限直径小粒子在雾滴表面的扩散通量与两个无量纲数参数有效；对于无外场作用时的点粒子情形，上述两种流型下的扩散沉积特征与粘性流结果亦不相同。     

An Image-Based Technique for Measuring Droplet Size Distribution: The Use of CNN Algorithm

A challenging task in measuring droplet size is the ability to perform in-situ droplet size distribution analysis on multiphase fluids in their native states in the undisturbed environment. In this study, an inline two-dimensional low cost–high accuracy technique is presented for continuous measurement of spherical or non-spherical droplets in emulsions using image processing. The characteristic of the droplets is evaluated and the describe drop size distributions in different ranges is determined. This droplet size determination algorithm is based on both cellular neural networks and linear matrix inequality. Our main work focuses on the performance of the proposed methodology for exploring the dynamical evolution of such droplet size distributions by in-situ measurement. Moreover, the results were compared with those obtained using laser diffraction analyzer technique. It was proved that this method can efficiently characterize the quality of dispersed phase by determining droplet size distribution.     

The Role of Internal Droplet Size on Emulsion Stability and the Extraction Performance of Kraft Lignin Removal from Pulping Wastewater in Emulsion Liquid Membrane Process

It has been discovered that the size of internal droplets in primary emulsion determines emulsion dispersion and stability in emulsion liquid membrane (ELM) process for removal of lignin from pulping wastewater. Generally, primary emulsion contains kerosene, Aliquat 336, sodium bicarbonate, as well as Span 80 as diluent, carrier, internal phase, and surfactant, respectively. Hence, this study had looked into the parameters, including concentration of surfactant, carrier, and stripping agent; emulsification speed and time; as well as agitation speed and time. As a result, the diameter of the smallest droplets (1.4 µm) was formed with maximum lignin extraction (95%), minimum swelling (5%) at 3% (w/v) surfactant concentration, 12,000 rpm of emulsification within 5 minutes, 0.01 M of Aliquat 336, 0.1 M of NaHCO_3, and 250 rpm of extraction within 10 minutes.     

Adaptive Chemical Networks under Non‐Equilibrium Conditions: The Evaporating Droplet

Non‐volatile solutes in an evaporating drop experience an out‐of‐equilibrium state due to non‐linear concentration effects and complex flow patterns. Here, we demonstrate a small molecule chemical reaction network that undergoes a rapid adaptation response to the out‐of‐equilibrium conditions inside the droplet leading to control over the molecular constitution and spatial arrangement of the deposition pattern. Adaptation results in a pronounced coffee stain effect and coupling to chemical concentration gradients within the drop is demonstrated. Amplification and suppression of network species are readily identifiable with confocal fluorescence microscopy. We anticipate that these observations will contribute to the design and exploration of out‐of‐equilibrium chemical systems, as well as be useful towards the development of point‐of‐care medical diagnostics and controlled deposition of small molecules through inkjet printing.     

Large-eddy simulation of impinging jets on smooth and rough surfaces

We performed large-eddy simulations (LES) of forced impinging jets over smooth and rough surfaces, containing large-scale, azimuthal vortices generated by the enhanced primary instability in the jet shear layer. The interaction between these vortices and the turbulence in the wall jet that is formed downstream of the impingement region determines their rate of decay. To explore the surface-roughness effects on the evolution of the vortices, sand-grain-like surfaces are generated using uniformly distributed but randomly oriented ellipsoids. The flow is compared to our previous LES of jets impinging on a smooth surface. In spite of the severe modification caused by the roughness on the near-wall flow, the vortex development is not significantly altered. Slightly faster decay of the primary vortices is observed in the rough-wall case compared to the smooth-wall one; the secondary vortex that detaches from the wall and is lifted up has larger vorticity. The highly disturbed near-wall flow is advected outward and affects the evolution of the primary vortex for a longer period during the vortex interaction. The robust turbulent generation mechanism in the outer shear layer, however, mitigates the changes in vortex behaviour. The momentum deficit and the enhancement of turbulence due to the surface roughness play a key role during this process.     

Investigation of various optical transitions in GaAs/Al0.3Ga0.7As double quantum ring grown by droplet epitaxy

This work examines the optical transitions of a GaAs double quantum ring (DQR) embedded in Al_0.3Ga_0.7As matrix by photoreflectance spectroscopy (PR). The GaAs DQR was grown by droplet epitaxy (DE). The optical properties of the DQR were investigated by excitation‐intensity and temperature‐dependent PR. The various optical transitions were observed in PR spectra, whereas the photoluminescence (PL) spectrum shows only the DQR and GaAs band emissions. The various optical transitions were identified for the GaAs near‐band‐edge transition, surface confined state (SCS), DQR confined state, wetting layer (WL), spin–orbital split (E_GaAs + Δ_o), and AlGaAs band transition. PR spectroscopy can identify various optical transitions that are invisible in PL. The PR results show that the GaAs/AlGaAs DQR has complex electronic structures due to the various interfaces resulting from DE.     

Nanostructure Explains the Behavior of Slippery Covalently Attached Liquid Surfaces

Slippery covalently-attached liquid surfaces (SCALS) with low contact angle hysteresis (CAH, <5°) and nanoscale thickness display impressive anti-adhesive properties, similar to lubricant-infused surfaces. Their efficacy is generally attributed to the liquid-like mobility of the constituent tethered chains. However, the precise physico-chemical properties that facilitate this mobility are unknown, hindering rational design. This work quantifies the chain length, grafting density, and microviscosity of a range of polydimethylsiloxane (PDMS) SCALS, elucidating the nanostructure responsible for their properties. Three prominent methods are used to produce SCALS, with characterization carried out via single-molecule force measurements, neutron reflectometry, and fluorescence correlation spectroscopy. CO₂ snow-jet cleaning was also shown to reduce the CAH of SCALS via a modification of their grafting density. SCALS behavior can be predicted by reduced grafting density, Σ, with the lowest water CAH achieved at Σ≈2. This study provides the first direct examination of SCALS grafting density, chain length, and microviscosity and supports the hypothesis that SCALS properties stem from a balance of layer uniformity and mobility.     

正癸烷纳米液滴润湿特性的分子动力学研究

流体液滴在固体表面的浸润性对其润滑性能至关重要.本文利用分子动力学方法研究了正癸烷纳米液滴在铜表面上的润湿特性.结果表明：在平坦光滑表面上,壁面的厚度和分子数目对润湿效果影响不大.随着壁面能量势阱参数εs 增大,接触角线性减小.随着温度升高,液滴的接触角减小.在沟槽粗糙表面上,随着粗糙度因子增大,对于疏液表面,接触角增大到一定值后基本保持不变,符合Cassie理论;中性和亲液表面接触角则会减小,为Wenzel润湿模式.当表面分数增大时,疏液与亲液表面接触角整体呈减小的趋势,对中性表面影响不大.当温度升高时,粗糙疏液表面接触角会增大,润湿效果更差,而粗糙中性和亲液表面液滴润湿性会更好.     

Analysis of volatile aldehyde biomarkers in human blood by derivatization and dispersive liquid–liquid microextraction based on solidification of floating organic droplet method by high performance liquid chromatography

A new dispersive liquid–liquid microextraction based on solidification of floating organic droplet method (DLLME-SFO) was developed for the determination of volatile aldehyde biomarkers (hexanal and heptanal) in human blood samples. In the derivatization and extraction procedure, 2,4-dinitrophenylhydrazine (DNPH) as derivatization reagent and formic acid as catalyzer were injected into the sample solution for derivatization with aldehydes, then the formed hydrazones was rapidly extracted by dispersive liquid–liquid microextraction with 1-dodecanol as extraction solvent. After centrifugation, the floated droplet was solidified in an ice bath and was easily removed for analysis. The effects of various experimental parameters on derivatization and extraction conditions were studied, such as the kind and volume of extraction solvent and dispersive solvent, the amount of derivatization reagent, derivatization temperature and time, extraction time and salt effect. The limit of detections (LODs) for hexanal and heptanal were 7.90 and 2.34 nmol L⁻¹, respectively. Good reproducibility and recovery of the method were also obtained. The proposed method is an alternative approach to the quantification of volatile aldehyde biomarkers in complex biological samples, being more rapid and simpler and providing higher sensitivity compared with the traditional dispersive liquid–liquid microextraction (DLLME) methods.