Oldroyd-B黏弹性液滴弹跳行为的改进SPH模拟

基于光滑粒子流体动力学SPH(Smoothed Particle Hydrodynamics)方法对Oldroyd-B黏弹性液滴撞击固壁面产生的弹跳行为进行了模拟与分析。首先,为了解决SPH模拟黏弹性自由表面流出现的张力不稳定性问题,联合粒子迁移技术提出了一种改进SPH方法。然后,对Oldroyd-B黏弹性液滴撞击固壁面产生的铺展行为进行了改进SPH模拟,与文献结果的比较验证了方法的有效性。最后,通过降低Reynolds数捕捉到了液滴的弹跳行为;并在此基础上,分析了液滴黏度比、Weissenberg数和Reynolds数对液滴弹跳行为的影响。结果表明,改进SPH方法可有效地模拟黏弹性自由表面流问题;液滴黏度比、Weissenberg数和Reynolds数对液滴最大回弹高度均有显著的影响。     

Effect of droplet size on the dielectric properties of PDLC films

Polymer dispersed liquid crystal (PDLC) films (5CB/PMMA, 60/40) of different droplet size were prepared by a solvent-induced phase separation method under different N₂ flow speeds. The effects of droplet size on the thermal transitions of the LC and various dielectric properties such as dielectric constant, conductance, dielectric loss, and the electric field induced in a droplet were examined. The configuration of the LC in the film with smaller droplets can be identified by comparing the dielectric constant of the film with the one predicted by Boettcher's mixture formula. In addition, the effect of droplet size on the electro-optical response of the PDLC film was investigated. Variations of the conductance and the dielectric constant of the film were analyzed under various AC frequencies, with the purpose of elucidating the polarization mechanism of the LC molecules in the droplet. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35 : 1373–1381, 1997     

NUMERICAL PREDICTION OF SEMI-CONFINED JET IMPINGEMENT AND COMPARISON WITH EXPERIMENTAL DATA

The standard k–ε eddy viscosity model of turbulence in conjunction with the logarithmic law of the wall has been applied to the prediction of a fully developed turbulent axisymmetric jet impinging within a semi-confined space. A single geometry with a Reynolds number of 20,000 and a nozzle-to-plate spacing of two diameters has been considered with inlet boundary conditions based on measured profiles of velocity and turbulence. Velocity, turbulence and heat transfer data have been obtained using laser–Doppler anemometry and liquid crystal thermography respectively. In the developing wall jet, numerical results of heat transfer compare to within 20% of experiment where isotropy prevails and the trends in turbulent kinetic energy are predicted. However, stagnation point heat transfer is overpredicted by about 300%, which is attributed directly to the turbulence model and inapplicability of the wall function.     

Electrohydrodynamic behaviors of droplet under a uniform direct current electric field

The electrohydrodynamic behaviors and evolution processes of silicone oil droplet in castor oil under uniform direct current(DC)electric field are visually observed based on a high-speed microscopic platform.Subsequently,the effects of different working conditions,such as electric field strength,droplet size,etc.,on droplet behaviors are roundly discussed.It can be found that there are four droplet behavior modes,including Taylor deformation,typical oblique rotation,periodic oscillation,and fracture,which change with the increase of electric field strength.It is also demonstrated that the degree of flat ellipse deformation gets larger under a stronger electric field.Moreover,both of the stronger electric field and smaller droplet size lead to an increase in the rotation angle of the droplet.     

滴状模式下液桥形成及断裂的电流体动力学特性研究

对电场作用下微通道荷电液滴脱落过程中液桥形成及断裂的显微演变特征进行了可视化实验研究.借助时空分辨率较高的高速摄像技术精确捕捉了电场作用下液桥形成及断裂的界面演化过程,研究了液桥的界面结构变化及其断裂的动力学显微演变行为,获得了时间特征数、电邦德数及半月面形成角对液桥长度及断裂顺序的作用规律.实验结果显示,液桥断裂长度取决于黏度与表面张力之比,而受荷电弛豫时间的影响甚微,低电压工况下各实验介质液桥相对长度的变化并不明显,而在较高电压工况下相对液桥长度的增长速度加快.随着电邦德数的不断增加,液桥长度的变化在较高邦德数下更为明显且存在突变区,此时伴随着雾化模式的转变,表明液桥的突变恰恰是雾化模式过渡的信号.不同物性介质的射流过渡行为由于液桥上下游形成角的变化而存在较大差异.对于无水乙醇介质,电邦德数的增加使滴状模式首先过渡到纺锤模式,而对于生物柴油,滴状模式后会首先出现脉动模式而非纺锤模式.      

SiC表面圆环槽边缘效应实验研究

基于固体边缘效应,对碳化硅(SiC)表面激光加工圆环形沟槽的润湿特性进行实验研究,通过分析去离子水在圆环槽上的润湿性能及其在边缘处的铺展行为,获得了环槽深度与环槽宽度对液滴在边缘处最大表观接触角的影响规律.结果表明,SiC圆环槽阻碍液滴铺展,光滑基体表面上接触角为70°,激光加工圆环槽深度为290μm,宽度为1 mm时...     

Unexpected Antioxidant Efficiency of Chlorogenic Acid Phenolipids in Fish Oil-in-Water Nanoemulsions: An Example of How Relatively Low Interfacial Concentrations Can Make Antioxidants to Be Inefficient

Selecting effective antioxidants is challenging since their efficiency in inhibiting lipid oxidation depends on the rate constants of the chemical reactions involved and their concentration at the reaction site, i.e., at the interfacial region. Accumulation of antioxidants at the interface of emulsions is key to modulate their efficiency in inhibiting lipid oxidation but its control was not well understood, especially in emulsions. It can be optimized by modifying the physicochemical properties of antioxidants or the environmental conditions. In this work, we analyze the effects of surfactant concentration, droplet size, and oil to water ratio on the effective interfacial concentration of a set of chlorogenic acid (CGA) esters in fish oil-in-water (O/W) emulsions and nanoemulsions and on their antioxidant efficiency. A well-established pseudophase kinetic model is used to determine in the intact emulsified systems the effective concentrations of the antioxidants (AOs). The relative oxidative stability of the emulsions is assessed by monitoring the formation of primary oxidation products with time. Results show that the concentration of all AOs at the interfacial region is much higher (20–90 fold) than the stoichiometric one but is much lower than those of other phenolipid series such as caffeic or hydroxytyrosol derivatives. The main parameter controlling the interfacial concentration of antioxidants is the surfactant volume fraction, Φ_I, followed by the O/W ratio. Changes in the droplet sizes (emulsions and nanoemulsions) have no influence on the interfacial concentrations. Despite the high radical scavenging capacity of CGA derivatives and their being concentrated at the interfacial region, the investigated AOs do not show a significant effect in inhibiting lipid oxidation in contrast with what is observed using other series of homologous antioxidants with similar reactivity. Results are tentatively interpreted in terms of the relatively low interfacial concentrations of the antioxidants, which may not be high enough to make the rate of the inhibition reaction faster than the rate of radical propagation.     

Numerical simulation of the deformation and breakup of a two-core compound droplet in an axisymmetric T-junction channel

The rheological behaviors of a compound droplet in a confined geometry are of importance in many industrial and natural processes. However, a detailed numerical simulation of the finite deformation and its transition to the breakup of the multi-core compound droplet in an axisymmetric T-junction channel is still lacking. The present study is to fill this gap through the numerical simulations of a two-core compound droplet that deforms and breaks up in this channel configuration. The numerical results are obtained by the axisymmetric front-tracking method. Our new finding is that the compound droplet in the channel can experience the finite deformation or the breakup depending on the flow condition or the configuration of the channel. In the finite deformation mode (i.e. non-breakup mode), the droplet rapidly reaches the maximum deformation before approaching the perpendicular rigid wall. The most deformation occurs with the outer droplet, and the inner droplet closer to the wall is less deformed than the other inner core droplet. In the breakup mode, three breakup patterns are recognized: (i) breakup type I occurring when breaking up only the outer droplet; (ii) breakup type 2 occurring when breaking up only the inner droplets; (iii) breakup type 3 occurring when breaking up both inner and outer droplets. The transition from the non-breakup mode to the breakup mode is available when increasing the Reynolds number Re (from 0.16 to 40.0), the capillary number Ca (from 0.04 to 4.0), the size R_o of the outer droplet and the middle-to-outer fluid viscosity ratio μ₂₁, or decreasing the size R_i of the inner droplets, the radial size C₂ of the channel (normalized by the channel axial size C₁) and the interfacial tension ratio of the inner to the outer droplets. The transition diagrams based on some of these parameters are also proposed to provide a more complete picture of the two-core compound droplet behaving in the axisymmetric T-junction channel..     

液滴在润湿梯度表面运动的分子动力学模拟

本文进行了液滴在不同润湿梯度表面运动的分子动力学模拟,通过改变Lennard-Jones(LJ)势参数来实现表面的不同润湿性。模拟结果表明在润湿梯度差为10°的界面上,疏水表面的液滴运动更快,达到最终界面所需时间最短,并且液滴运动方向距离最远。当润湿梯度差为20°和30°时,液滴在疏水表面工况的运动速度与从疏水跨越到亲水的工况之间的差距越来越小,并且液滴在从疏水跨越到亲水的工况达到了最远的运动距离。同时,润湿梯度差的增加也引起了液滴运动速度的增大。